Topology Reconfiguration of Anion-Pillared Metal-Organic Framework from Flexibility to Rigidity for Enhanced Acetylene Separation.

Flexible metal-organic framework (MOF) adsorbents commonly encounter limitations in removing trace impurities below gate-opening threshold pressures. Topology reconfiguration can fundamentally eliminate intrinsic structural flexibility, yet remains a formidable challenge and is rarely achieved in practical applications. Herein, a solvent-mediated approach is presented to regulate the flexible CuSnF-dpds-sql (dpds = 4,4''-dipyridyldisulfide) with sql topology into rigid CuSnF-dpds-cds with cds topology.

Molecular sieving of iso-butene from C olefins with simultaneous high 1,3-butadiene and n-butene uptakes.

Iso-butene (iso-CH) is an important raw material in chemical industry, whereas its efficient separation remains challenging due to similar molecular properties of C olefins. The ideal adsorbent should possess simultaneous high uptakes for 1,3-butadiene (CH) and n-butene (n-CH) counterparts, endowing high efficiency for iso-CH separation in adsorption columns. Herein, a sulfate-pillared adsorbent, SOFOUR-DPDS-Ni (DPDS = 4,4'-dipyridyldisulfide), is reported for the efficient iso-CH separation from binary and ternary C olefin mixtures.

Improved soil moisture, nutrients, and economic benefits using plastic mulchs in balsa-based agroforestry systems.

The manufacture of wind turbine blades generally uses balsa wood as the base materials, and it is crucial to explore new regions for cultivating balsa trees to achieve carbon neutrality in the future. Xishuangbanna may be China's only area with a tropical climate suitable for the large-scale planting of balsa trees. The present study investigated the key soil elements influencing the growth of balsa plantations and the effects of different cultivation practices on soil environments and economic benefits in Xishuangbanna, China.

Comparison of NOD-like and Toll-like receptors gene expression levels in blood monocytes of colon cancer patients.

Colon cancer is one of the most common cancers affecting many people worldwide. This disease can be treated if diagnosed in the early stages. Therefore, with the hypothesis that the level of expression of inflammatory genes in peripheral blood monocytes of patients with colon cancer is different from that of healthy people, this research was done to find out the role of inflammation in the development of colon cancer by relying on its immunopathological profile to help diagnose it in the early stages.

Lymph node metastasis related gene BICC1 promotes tumor progression by promoting EMT and immune infiltration in pancreatic cancer.

Background: Pancreatic cancer (PC) is one of the most aggressive abdominal malignancies with a poor prognosis and it is urgent to find effective biomarkers for prediction. Although BICC1 expression is related to the survival, no evidence for its role in PC development has been found.

Methods: We used RNA-seq data to screen for molecular markers highly associated with lymph node metastasis.

A UAV Maneuver Decision-Making Algorithm for Autonomous Airdrop Based on Deep Reinforcement Learning.

How to operate an unmanned aerial vehicle (UAV) safely and efficiently in an interactive environment is challenging. A large amount of research has been devoted to improve the intelligence of a UAV while performing a mission, where finding an optimal maneuver decision-making policy of the UAV has become one of the key issues when we attempt to enable the UAV autonomy. In this paper, we propose a maneuver decision-making algorithm based on deep reinforcement learning, which generates efficient maneuvers for a UAV agent to execute the airdrop mission autonomously in an interactive environment.

Substrate-Free Multilayer Graphene Electronic Skin for Intelligent Diagnosis.

Current wearable sensors are fabricated with substrates, which limits the comfort, flexibility, stretchability, and induces interface mismatch. In addition, the substrate prevents the evaporation of sweat and is harmful to skin health. In this work, we have enabled the substrate-free laser scribed graphene (SFG) electronic skin (e-skin) with multifunctions.

Limonoids from the Leaves and Twigs of Walsura yunnanensis.

Nine new cedrelone limonoids, namely, walsuranolide B (1), 11β-hydroxy-23-O-methylwalsuranolide (2), yunnanolide A (3), yunnanol A (4), 11β-hydroxyisowalsuranolide (5), 11β-hydroxy-1,2-dihydroisowalsuranolide (6), 1α,11β-dihydroxy-1,2-dihydroisowalsuranolide (7), 11β-hydroxy-1α-methoxy-1,2-dihydroisowalsuranolide (8), and yunnanolide B (9), together with a new cycloartane triterpenoid, (24S*,25R*)-cycloartane-3β,24,25,26-tetrol (10), were isolated from the leaves and twigs of Walsura yunnanensis. Their structures were elucidated on the basis of spectroscopic analysis and by comparison with literature data. Compounds 3 and 5 exhibited potent cytotoxicity against five human tumor cell lines with IC50 values in the range 2.

Bioinspired green composite lotus fibers.

Owing to the growing global environmental problems, demands for environmentally friendly, fully biodegradable sustainable composites have substantially increased across various industries. Inspired by the composite structure of cocoon silk, we fabricated a fully green composite fiber (GCF) that is based on the lotus fiber (LF) and a biodegradable polymer, namely poly(vinyl alcohol) (PVA). After the formation of cross-linkages between the LF and PVA, the mechanical properties of this bioinspired GCF had substantially improved.

[Application of SNPstream for medical genetics research].

Objective: To introduce the principle, procedure, efficacy and application of SNPstream genotyping technology.

Methods: Genotyping results of 152 SNPs were used to analyze the feasibility, call rate and accuracy of SNPstream technology.

Results: For the 152 selected SNPs, 122 SNPs can be genotyped with SNPstream, for which 116 SNPs were successfully genotyped.