The Synergistic Effect of Graphene Oxide in Epoxy Resin on Photocured Coating Films with Anticorrosion and Antibacterial Properties.

In this work, graphene oxide (GO) and epoxy-functionalized graphene oxide (GOSi) are chosen as additives and incorporated into epoxy resin (EP) for nanocomposite photo-coating films (GO/EP and GOSi/EP series). Compared to GO/EP, the GOSi/EP nanocomposite demonstrates strong binding and excellent dispersibility, highlighting covalent bonding between GOSi and the epoxy coating. Furthermore, GOSi/EP-based films demonstrated superior thermal stability and adhesion performance on galvanized steel plates.

UV-crosslinking of chitosan/spent coffee ground composites for enhanced durability and multifunctionality.

Spent coffee grounds (SCGs) have numerous applications and are often blended with polymers to create composites. However, SCGs are physically trapped within the polymer matrix, lacking strong chemical bonding. Therefore, this study has developed a new method for UV crosslinking composites using phenyl azide to address the issue of SCG leakage and limited durability of the composites.

Dual-Coating of Fluorinated Polydimethylsiloxane/Fluorinated SiO Nanoparticles for Superhydrophobic and High-Efficiency Bacteriostatic Surface.

A simple two-step spray method is used to prepare superhydrophobic and bacteriostatic surfaces, involving dual-coating with polydimethylsiloxane-normal-fluorine (PDMS-NF) or branched-fluorine (PDMS-BF) in combination with fluorinated silica nanoparticles (FSiO -NPs) using a spray technique. This approach has the potential to create surfaces with both water-repellent and antimicrobial properties, which could be useful in a variety of applications. It is noteworthy that the dual-coating on cotton fabric exhibited an impressive dual-scale roughness and achieved superhydrophobicity with a water contact angle of 158° and a hysteresis of less than 3°.

Self-Assembly of Shark Scale-Patterned Tunable Superhydrophobic/Antifouling Structures with Visual Color Response.

The stacked riblet-like shark scales, also known as dermal denticles, allow them to control the boundary layer flow over the skin and to reduce interactions with any biomaterial attached, which guide the design of antifouling coatings. Interestingly, shark scales are with a wide variation in geometry both across species and body locations, thereby displaying diversified antifouling capabilities. Inspired by the multifarious denticles, a stretchable shark scale-patterned silica hollow sphere colloidal crystal/polyperfluoroether acrylate-polyurethane acrylate composite film is engineered through a scalable self-assembly approach.

Developing Transparent and Conductive PolyHEMA Gels Using Deep Eutectic Solvents.

Poly(2-hydroxyethyl methacrylate) (polyHEMA) hydrogels are commonly used in biomaterials such as contact lenses. However, water evaporation from these hydrogels can cause discomfort to wearers, and the bulk polymerization method used to synthesize them often results in heterogeneous microstructures, reducing their optical properties and elasticity. In this study, we synthesized polyHEMA gels using a deep eutectic solvent (DES) instead of water and compared their properties to traditional hydrogels.

Biomimetic surfaces: Insights on the role of surface topography and wetting properties in bacterial attachment and biofilm formation.

The study explores the impact of biomimetic surfaces on bacterial attachment and biofilm formation. Specifically, it investigates the effects of topographic scale and wetting behavior on the attachment and growth of Staphylococcus aureus and Escherichia coli on four different biomimetic surfaces: rose petals, Paragrass leaves, shark skin, and goose feathers. Using soft lithography, epoxy replicas with surface topographies similar to those of the natural surfaces were created.

Effect of Codeposition of Polydopamine with Polyethylenimine or Poly(ethylene glycol) Coatings on Silver Nanoparticle Synthesis.

This study investigated the effects of polydopamine (PDA), PDA/polyethylenimine (PEI), and PDA/poly(ethylene glycol) (PEG) deposition on silver nanoparticle (AgNP) formation. PEI or PEG with different molecular weights was mixed with dopamine at different concentrations to obtain various PDA/PEI or PDA/PEG codepositions. These codepositions were soaked in silver nitrate solution to observe AgNPs generated on the surface and then to examine the catalytic activity of AgNPs for the reduction of 4-nitrophenol to 4-aminophenol.

A Rapidly and Highly Self-Healing Poly(Sulfobetaine Methacrylate) Hydrogel with Stretching Properties, Adhesive Properties, and Biocompatibility.

This study focuses on the preparation of stretchable zwitterionic poly(sulfobetaine methacrylate) (PSBMA) hydrogels. To address the weak mechanical properties of chemically crosslinked PSBMA hydrogels, a physical crosslinking method utilizing hydrophobic interactions to crosslink hydrogels to approach tough properties is developed. Here, sodium dodecyl sulfate (SDS)-based micelle is used as a physical crosslinker to prepare physically crosslinked PSBMA (PSBMA ) hydrogels, and ethylene glycol dimethylacrylate (EGDMA) is used to prepare a control group of chemically crosslinked PSBMA (PSBMA ) hydrogels.

Polycarboxybetaine-Based Hydrogels for the Capture and Release of Circulating Tumor Cells.

Circulating tumor cells (CTCs) are indicators for the detection, diagnosis, and monitoring of cancers and offer biological information for the development of personalized medicine. Techniques for the specific capture and non-destructive release of CTCs from millions of blood cells remain highly desirable. Here, we present a CTC capture-and-release system using a disulfide-containing poly(carboxybetaine methacrylate) (pCB) hydrogel.

Enhancing the antibacterial property of chitosan through synergistic alkylation and chlorination.

Chitosan exhibits moderate antimicrobial properties. Here, we enhanced the antimicrobial properties of chitosan through alkylation and chlorination and evaluated the effect of alkylation on chitosan's hydrophobicity, bacterial attachment, chlorination, biocidal property, and stability. First, chitosan films were prepared through casting and were then immersed in a hexanal solution of different concentrations.

A hemostatic keratin/alginate hydrogel scaffold with methylene blue mediated antimicrobial photodynamic therapy.

Uncontrollable bleeding and infection are two of the most common causes of trauma-related death. Yet, developing safe materials with high hemostatic and antibacterial effectiveness remains a challenge. Keratin-based biomaterials have been reported to exhibit the functions of enhancing platelet binding and activating and facilitating fibrinogen polymerization.

Upconversion Nanoparticles Encapsulated with Molecularly Imprinted Amphiphilic Copolymer as a Fluorescent Probe for Specific Biorecognition.

A fluorescent probe for specific biorecognition was prepared by a facile method in which amphiphilic random copolymers were encapsulated with hydrophobic upconversion nanoparticles (UCNPs). This method quickly converted the hydrophobic UCNPs to hydrophilic UNCPs. Moreover, the self-folding ability of the amphiphilic copolymers allowed the formation of molecular imprinting polymers with template-shaped cavities.

Incidence of plastic ingestion by the shortfin mako, Isurus oxyrinchus, off the northeast coast of Taiwan.

This present study documents the incidence of plastic digestion by shortfin mako shark (Isurus oxyrinchus), caught by the Taiwanese small-scale tuna longline fishery in the Northwest Pacific Ocean (between the northeast coast of Taiwan and Japan). In 20 stomachs of shortfin mako, nearly 10% of samples contained at least one piece of plastic debris. The ingested plastic debris was found in the forms of films (5.

Rapid Biocidal Activity of -Halamine-Functionalized Polydopamine and Polyethylene Imine Coatings.

Microorganisms easily adhere to the surface of substrates and further form biofilms, which present problems in various fields. Therefore, the development of surfaces with antimicrobial adhesion or viability is a promising approach. In this study, we were committed to develop a rapid sterilizing coating.

Biomimetic Mineralization of Tannic Acid-Supplemented HEMA/SBMA Nanocomposite Hydrogels.

This study developed a tannic acid (TA)-supplemented 2-hydroxyethyl methacrylate-co-sulfobetaine methacrylate (HEMA-co-SBMA) nanocomposite hydrogel with mineralization and antibacterial functions. Initially, hybrid hydrogels were synthesized by incorporating SBMA into the HEMA network and the influence of SBMA on the chemical structure, water content, mechanical properties, and antibacterial characteristics of the hybrid HEMA/SBMA hydrogels was examined. Then, nanoclay (Laponite XLG) was introduced into the hybrid HEMA/SBMA hydrogels and the effects evaluated of the nanoclay on the chemical structure, water content, and mechanical properties of these supplemented hydrogels.

Well-Dispersed Silver Nanoparticles on Cellulose Filter Paper for Bacterial Removal.

In this study, a polydopamine (PDA) and polyethyleneimine (PEI)-assisted approach was developed to generate well-distributed PDA/PEI/silver (PDA/PEI/Ag) nanocomplexes on the surfaces of commercial cellulose filter papers to achieve substantial bacterial reduction under gravity-driven filtration. PDA can bind to cellulose paper and act as a reducer to produce silver nanoparticles (AgNPs), while PEI can react with oxidative dopamine and act as a dispersant to avoid the aggregation of AgNPs. The successful immobilization of PDA/PEI/Ag nanocomplexes was confirmed by scanning electron microscopy (SEM), X-ray diffraction (XRD), and Fourier transform infrared spectroscopy (FTIR).

Accessing Multiple Paternity in the Shortfin Mako Shark ().

Multiple paternity has been demonstrated in a variety of sharks with different reproductive modes (, viviparous, ovoviviparous, adelphophagy, oviparous), although the number of sires per litter varies considerably among species. To date, such analyses have focused mainly on coastal and nearshore shark species due to the difficulty in sampling oceanic sharks. In the present study, we observed multiple paternity in the oceanic shark from seven polymorphic microsatellite loci and three litters collected from Nanfangao Fishing Port.

Synthesis, Optical Properties, and Sensing Applications of LaF:Yb/Er/Ho/Tm Upconversion Nanoparticles.

Herein, we successfully synthesized a series of LaF:Yb/Er/Ho/Tm upconversion nanoparticles (UCNPs) and LaF:Yb, Er@LaF:Yb core/shell UCNPs by modifying the amount of NaOH and the reaction time. Hexagonal LaF nanocrystals with uniform particle sizes and bright UC emissions were obtained. The crystal structures of the lanthanide-doped LaF UCNPs were investigated using wide-angle X-ray diffraction.

Interaction of LiYF:Yb/Er/Ho/Tm@LiYF:Yb upconversion nanoparticles, molecularly imprinted polymers, and templates.

In this work, LiYF:Yb /Er /Tm /Ho @LiYF:Yb upconverting nanoparticles (UCNP) were used as luminescent materials for the preparation of molecular imprinting polymer nanocomposites. Three luminescent molecularly imprinted polymer (MIP) nanocomposites were prepared by polymerization. The relationship between the functional monomers, templates, and upconversion nanoparticles was investigated.

Superhydrophilic Coating with Antibacterial and Oil-Repellent Properties via NaIO-Triggered Polydopamine/Sulfobetaine Methacrylate Polymerization.

Superhydrophilic coatings have been widely used for the surface modification of membranes or biomedical devices owing to their excellent antifouling properties. However, simplifying the modification processes of such materials remains challenging. In this study, we developed a simple and rapid one-step co-deposition process using an oxidant trigger to fabricate superhydrophilic surfaces based on dopamine chemistry with sulfobetaine methacrylate (SBMA).

Inhibition of biofilm formation by rough shark skin-patterned surfaces.

In this study, we investigate the microscale structure of shark skin denticles at abdomen (A) and fin (F) locations, analyze the roughness and wetting properties related to their microstructures, and evaluate the effect of the surface properties on early bacterial attachment and biofilm formation. Microstructural analysis by scanning electron microscopy and confocal laser scanning microscopy confirmed the length (A: 165-180 μm vs. F: 145-165 μm), width (A: 86-100 μm vs.

Polysaccharidic spent coffee grounds for silver nanoparticle immobilization as a green and highly efficient biocide.

Spent coffee grounds (SCGs) contain abundant polysaccharides and several components with bioactivities. Despite many bio-functionalities, their bioactivities are not always satisfactory. Modifications of SCGs may overcome this issue.

Preparation, material properties and antimicrobial efficacy of silicone hydrogel by modulating silicone and hydrophilic monomer.

The present work proposes to investigate two series of silicone hydrogel materials for their characterization, water content, surface wettability, transmittance, mechanical property, oxygen permeability (Dk), and bacterial attachment as potential contact lens materials and discuss the relationships between water affinity and optical, mechanical, oxygen permeable and biological properties. One of the series of silicone hydrogels is presented on the basis of 3-(methacryloyloxy)propyltris(trimethylsiloxy)silane (TRIS), 3-(3-methacryloxy-2-hydroxypropoxy)propylbis(trimethylsiloxy)methylsilane (BIS) and 2-hydroxyethyl methacrylate (HEMA) with different silicone monomers/HEMA ratios. The other is presented on the basis of TRIS, BIS, HEMA and N,N-dimethylacrylamide (DMA) with different DMA/HEMA ratios.

Studies of PET nonwovens modified by novel antimicrobials configured with both -halamine and dual quaternary ammonium with different alkyl chain length.

This work describes the synthesis of novel antimicrobial agents consisting of -halamine and dual quaternary ammonium with different alkyl chain lengths and their antimicrobial applications for PET nonwovens. The antimicrobial agents were grafted onto PET nonwovens esterification with a crosslinker, 1,2,3,4-butanetetracarboxylic acid (BTCA). The cyclic amide structure in the antimicrobial agents could be easily converted to -halamine after immersion in a diluted chlorine bleach solution.

Immobilization of functional polymers on poly(4-benzoyl-pxylylene-co-p-xylylene) films via photochemical conjugation for modulation of cell adhesion.

Surface modification with functional materials, such as anti-fouling or thermal responsive polymers, on biomedical devices benefits their clinical performance. Simple and versatile technologies, which could be applied to a wide variety of substrates, are still highly desirable. Chemical vapor deposition (CVD) of 4-benzoyl-[2,2]paracyclophane (Benzoyl-PPX) layers attracts much attention because the photoreactive platform could be deposited onto almost every substrate for the conjugation of functional molecules.