In Situ XANES Studies on Extracted Copper from Scrap Cu/ITO Thin Film in an Ionic Liquid Containing Iodine/Iodide.

Copper is coated on indium-tin-oxide (ITO) thin film to improve its electrical resistivity. In order to recycle the scrap Cu/ITO thin film, an ionic liquid (1-butyl-3-methyl imidazolium hexafluorophosphate ([C4mim][PF6])) containing iodine/iodide (IL-I) was used to extract copper at 303, 343, 413, 374, and 543 K. The extraction efficiency of copper from the scrap Cu/ITO thin film was >99% with IL-I.

Ionic Liquid Extraction Behavior of Cr(VI) Absorbed on Humic Acid-Vermiculite.

Cr(VI) can be released into soil as a result of mining, electroplating, and smelting operations. Due to the high toxicity of Cr(VI), its removal is necessary in order to protect ecosystems. Vermiculite is applied in situations where there is a high degree of metal pollution, as it is helpful during the remediation process due to its high cation exchange capacity.

Application of metallic nanoparticle-biochars with ionic liquids for thermal transfer fluids.

Ionic liquids (ILs (1-butyl-3-methylimidazolium chloride ([Cmim][Cl]) and 1-butyl-3-methylimidazolium tetrafluoroborate ([Cmim][BF]))) were used as heat transfer fluids for solar thermal collectors. The additive of ILs was biochar containing copper and silver nanoparticles (Cu-Ag/biochar) to improve the adsorption of solar irradiation and thermal conductivities. After impregnation and reduction processes, nanoparticles such as Cu, CuO, Cu(OH), Ag, and AgO were found in the biochar by X-ray powder diffraction (XRD) spectroscopy.

Speciation of chromium compounds from humic acid-zeolite Y to an ionic liquid during extraction.

By synchrotron X-ray absorption spectroscopy, chemical structures of hexavalent chromium (Cr(VI))/trivalent chromium (Cr(III)) adsorbed on humic acid (HA)-zeolite Y and extracted in an ionic liquid (1-butyl-3-methylimidazolium tetrafluoroborate ([Cmim][BF])) have been studied. By combining the competitive adsorption results and reduction of Cr(VI)-HA with the carboxyl groups of HA, Cr(III)-HA (58%) was shown to be the major compound in HA-zeolite Y using synchrotron X-ray absorption near-edge structure (XANES) spectroscopy. In an ionic liquid phase, the reduction of Cr(VI)-HA to Cr(III)-HA and the desorption of Cr(III) from HA were caused by [Cmim][BF].

Extraction of nanosize copper pollutants with an ionic liquid.

Speciation and possible reaction paths of nanosize copper pollutants extracted with a RTIL (room-temperature ionic liquid ([C4mim][PF6], 1-butyl-3-methylimidazolium hexafluorophosphate)) have been studied in the present work. Experimentally, in a very short contact time (2 min), 80-95% of nanosize CuO as well as other forms of copper (such as nanosize Cu, Cu2+, or Cu(II)(ads) (in the channels of MCM-41)) in the samples could be extracted into the RTIL. The main copper species extracted in the RTIL as observed by XANES (X-ray absorption near edge structure) were Cu(II).