A new approach in this present study, isolated bacteria from refinery sludge were used in a laboratory-scale bio-scrubber, connecting with two parallel airlift bioreactors to eliminate harmful and toxic fumes of BTX. One of the main features of this bio-scrubber is using porous mineral pumice fillers (Lava Rock) inside poly-urethane foam (PUF) module tower, connecting with agitator bio-phasic continuously stirred tank bio-reactor (CSTbR) to increase retention time and contact surface. The bio-scrubber and airlift plug flow bio-reactor (PFbR) were used in parallel with cooling flow to be more efficient in preservation of the corresponding heater and endothermic from removal reactions.
View Article and Find Full Text PDFHerein, two novel porous polymer matrix nanocomposites were synthesized and used as adsorbents for heavy metal uptake. Methacrylate-modified large mesoporous silica FDU-12 was incorporated in poly(methyl methacrylate) matrix through an in-situ polymerization approach. For another, amine-modified FDU-12 was composited with Nylon 6,6 via a facile solution blending protocol.
View Article and Find Full Text PDFIn this study, porous methacrylate-modified FDU-12/poly(methyl methacrylate) and amine-modified FDU-12/Nylon 6 nanocomposites were synthesized via a facile solution casting protocol. The physicochemical properties of the prepared materials were studied using various characterization techniques including Fourier transform-infrared spectroscopy, field emission-scanning electron microscopy, transmission electron microscopy, and nitrogen adsorption/desorption. After characterization of the materials, the prepared nanocomposites were applied as novel adsorbents for the removal of Pb(II) from aqueous media.
View Article and Find Full Text PDFThermal decomposition of oil palm fruit press fiber (FPF) into a liquid product (LP) was achieved using subcritical water treatment in the presence of sodium hydroxide in a high pressure batch reactor. This study uses experimental design and process optimisation tools to maximise the LP yield using response surface methodology (RSM) with central composite rotatable design (CCRD). The independent variables were temperature, residence time, particle size, specimen loading, and additive loading.
View Article and Find Full Text PDFThermal decomposition of oil palm fruit press fiber (FPF) with sub/supercritical methanol, ethanol, acetone, and 1,4-dioxane treatments were investigated using a high-pressure autoclave reactor. When FPF was decomposed with methanol, ethanol, and acetone from 483 to 603 K, the highest degree of conversion obtained were 81.5%, 77.
View Article and Find Full Text PDFDecomposition of oil palm fruit press fiber (FPF) to various liquid products in subcritical water was investigated using a high-pressure autoclave reactor with and without the presence of catalyst. When the reaction was carried in the absence of catalyst, the conversion of solid to liquid products increased from 54.9% at 483 K to 75.
View Article and Find Full Text PDF