Experimental study of DNAPL displacement by a new densified polymer solution and upscaling problems of aqueous polymer flow in porous media.

The remediation of DNAPL-contaminated soil with lower-density fluids is ineffective due to the over-riding of displacing fluid. The densification of biopolymers is experimentally studied to develop a solution with the same density as a pollutant. Polymer solutions and contaminants are characterized through rheometer.

Influence of water saturation and soil properties on the removal of organic pollutants using microwave heating.

Properties of fluids and media, such as soil moisture, may play a significant role in the absorption of microwave and heat distribution during the remediation of soil contaminated with volatile and semi-volatile compounds. Previous studies have been performed on soil samples placed inside a microwave oven cavity in a reactor far from the waveguide outlet or directly inside the metal waveguides. These conditions are far from in situ applications where the unsaturated soil is directly exposed to microwaves through the antenna slots.

Numerical simulations of high viscosity DNAPL recovery in highly permeable porous media under isothermal and non-isothermal conditions.

We developed a decimetric size model based on coupling generalized Darcy's law and heat-transfer equations to model viscous dense non-aqueous phase liquid (DNAPL) pumping through highly permeable porous media under non-isothermal conditions. The presence of fingering and non-wetting phase ganglia was modeled through an unsteady capillary diffusion coefficient and an arbitrary heterogeneous permeability field. The model was validated using existing experimental data of a simple case, an oil injection in a 2D tank packed with glass beads.

Influence of the injection of densified polymer suspension on the efficiency of DNAPL displacement in contaminated saturated soils.

Nowadays the remediation of DNAPL contaminated zones near groundwater has gained great prominence in environmental fields due to the high importance of water resources. In this work, we suggest injecting a densified polymer suspension by adding barite particles to displace DNAPL. To evaluate the efficiency of the densification of polymer suspensions on the displacement of DNAPL, various densities of barite-polymer suspension; lower, equal, and higher than the density of DNAPL were prepared and their rheological behavior was analyzed.

DNAPL flow and complex electrical resistivity evolution in saturated porous media: A coupled numerical simulation.

Induced Polarization (IP) is a non-intrusive geophysical method to monitor Dense Non-Aqueous Phase Liquid (DNAPL) contamination and remediation processes underground. In this study, an advanced numerical code simulating DNAPL flow and complex electrical resistivity is presented. The model was validated against existing IP results and image measurements that were carried out previously in a series of 2D tank experiment.

Experimental study of foam propagation and stability in highly permeable porous media under lateral water flow: Diverting groundwater for application to soil remediation.

Foam propagation and stability in highly permeable porous media, encountered in soil pollution applications, are still challenging. Here, we investigated the application of foam for blocking the aquifer to divert the flow from a contaminated zone and, therefore, ease the remediation treatments. The main aim was to better understand the critical parameters when the foam is injected into a highly permeable aquifer with high groundwater flow velocity (up to 10 m/day).

A critical review of the influence of groundwater level fluctuations and temperature on LNAPL contaminations in the context of climate change.

The intergovernmental panel on climate change (IPCC) predicts significant changes in precipitation patterns, an increase in temperature, and groundwater level variations by 2100. These changes are expected to alter light non-aqueous phase liquid (LNAPL) impacts since groundwater level fluctuations and temperature are known to influence both the mobility and release of LNAPL compounds to air and groundwater. Knowledge of these potential effects is currently dispersed in the literature, hindering a clear vision of the processes at play.

Experimental study of thermally enhanced recovery of high-viscosity DNAPL in saturated porous media under non-isothermal conditions.

Thermal enhancement is known to be an efficient way to decrease the residual saturation of some common dense non-aqueous phase liquids (DNAPLs) after pumping. However, the effect of transient heat transfer during the recovery of a high-viscosity contaminant, such as coal tar, in highly permeable porous media is still unknown. A 2D tank experimental setup allowing monitoring of temperature and saturation fields during DNAPL pumping has been developed.

Targeted delivery of hydrogen for the bioremediation of aquifers contaminated by dissolved chlorinated compounds.

Dihydrogen (H) gas injection is a promising option to enhance the reductive biodehalogenation of contaminants in groundwater. However, it is challenging to ensure its targeted delivery at the right places in plumes, and for the long times required for bioremediation. In this paper, the ability of surfactant foam to retain H in the saturated zone and to enhance its release in the dissolved form was compared to traditional biosparging.

Study of the effect of wind speed on evaporation from soil through integrated modeling of the atmospheric boundary layer and shallow subsurface.

In an effort to develop methods based on integrating the subsurface to the atmospheric boundary layer to estimate evaporation, we developed a model based on the coupling of Navier-Stokes free flow and Darcy flow in porous medium. The model was tested using experimental data to study the effect of wind speed on evaporation. The model consists of the coupled equations of mass conservation for two-phase flow in porous medium with single-phase flow in the free-flow domain under nonisothermal, nonequilibrium phase change conditions.