Efficient Thin Polymer Coating as a Selective Thermal Emitter for Passive Daytime Radiative Cooling.

Radiative cooling to subambient temperatures can be efficiently achieved through spectrally selective emission, which until now has only been realized by using complex nanoengineered structures. Here, a simple dip-coated planar polymer emitter derived from polysilazane, which exhibits strong selective emissivity in the atmospheric transparency window of 8-13 μm, is demonstrated. The 5 μm thin silicon oxycarbonitride coating has an emissivity of 0.