River regulation and climate change reduce river flows to major Australian floodplain wetland.

Freshwater ecosystems, including rivers and floodplain wetlands, face severe stress from unsustainable water resources development, with climate change exerting further pressure. This study compares the relative effects of river regulation and projected climate change on river flows to the semi-arid Lowbidgee Floodplain (3250 km), the largest wetland ecosystem on the heavily regulated Murrumbidgee River, Australia's second longest river, within the Murray-Darling Basin. We modelled annual natural streamflow in the lower Murrumbidgee River before major dam constructions and water diversions (1890-1927), linking river flows to runoff from the upper Murrumbidgee catchment.

Divergent determinants on interannual variability of terrestrial water cycle across the globe.

Intensifying variability in precipitation under a changing climate is projected to amplify fluctuation in terrestrial hydrological cycle, leading to more severe water-related disasters. The connections between interannual variability of hydrological components and factors influencing these connections have not been clearly defined yet. Based on terrestrial water budget from Climate Data Record, we identify dominant factors influencing partitioning interannual variability of precipitation (P) into that of evapotranspiration (E), runoff (Q), and water storage deviation (ΔS) across the globe by employing geographical detector model (GDM).

Chromium Picolinate Regulates Bone Metabolism and Prevents Bone Loss in Diabetic Rats.

Diabetic osteoporosis (DOP) is an abnormal metabolic disease caused by long-term hyperglycemia. In this study, a model rat of streptozotocin (STZ)-induced diabetes was established, and chromium picolinate (5 mg·kg) was given; the changes in blood glucose and body weight were detected before and after administration; and bone mineral density (BMD), bone morphology, bone turnover markers, inflammatory cytokines, and oxidative stress indicators were observed in each group. We found that after chromium picolinate (CP) intervention for 8 weeks, the blood glucose level was decreased; the BMD, the bone histomorphology parameters, and the pathological structure were improved; the expression of bone resorption-related proteins was downregulated; and the expression of bone formation-related proteins was upregulated.

Protective Effect of Black Rice Cyanidin-3-Glucoside on Testicular Damage in STZ-Induced Type 1 Diabetic Rats.

Diabetic testicular damage is quite a common and significant complication in diabetic men, which could result in infertility. The natural fertility rate of type 1 diabetes men is only 50% because of testicular damage. This research first aimed to explore the intervention effect of C3G on testicular tissue damage induced by diabetes.

Chromium Picolinate Protects against Testicular Damage in STZ-Induced Diabetic Rats via Anti-Inflammation, Anti-Oxidation, Inhibiting Apoptosis, and Regulating the TGF-β1/Smad Pathway.

Chromium picolinate (CP) is an organic compound that has long been used to treat diabetes. Our previous studies found CP could relieve diabetic nephropathy. Thus, we speculate that it might have a positive effect on diabetic testicular injury.

Investigation of Parallel and Orthogonal MIMO Antennas with Two-Notched Structures for Ultra-Wideband Application.

Ultra-wideband (UWB) technology is widely used in many communication scenarios. However, narrowband systems can easily interfere with the UWB system, which generates multipath fading. In order to solve these interferences and meet the design requirements of high isolation of multiple-input multiple-output (MIMO) antennas, two MIMO antennas with double-notch structures are designed.

Spatial patterns of climate change and associated climate hazards in Northwest China.

Northwest China (NWC) is experiencing noticeable climate change accompanied with increasing impacts of climate hazards induced by changes in climate extremes. Towards developing climate adaptation strategies to mitigate the negative climatic impacts on both the ecosystem and socioeconomic system of the region, this study investigates systematically the spatial patterns of climate change and the associated climate hazards across NWC based on high resolution reanalysis climate dataset for the period 1979 to 2018. We find that NWC overall is under a warming and wetting transition in climate with change rate of temperature and precipitation around 0.

Broadband Flexible Microstrip Antenna Array with Conformal Load-Bearing Structure.

To enhance the load-bearing mechanical properties and broadband electromagnetic characteristics of the conformal antenna, a broadband microstrip antenna array with a conformal load-bearing structure is proposed in this paper, which consists of three flexible substrate layers and two honeycomb core layers stacked on each other. By combining the antenna and honeycomb core layer in a structural perspective, the antenna array is implemented in the composition function of surface conformability and load-bearing. Additionally, the sidelobe level of the antenna is suppressed based on the reflection surface loaded.

Ice phenology dataset reconstructed from remote sensing and modelling for lakes over the Tibetan Plateau.

The Tibetan Plateau (TP) is a region sensitive to global climate change and has been experiencing substantial environmental changes in the past decades. Lake ice phenology (LIP) is a perceptible indicator reflecting changes of lake thermodynamics in response to global warming. Lake ice phenology over the Tibetan Plateau is however rarely observed and recorded.

The stereoselective conversion of epimerized alkoxyl phosphine-borane to -stereogenic tertiary phosphine cleavage of P-O bond.

The P-O bond of epimerized alkoxyl phosphine-borane was cleaved by naphthalene-lithium, to form two diastereomers of P-anions in a ratio of 86 : 14, which was then converted to secondary phosphine-borane acidification, and to tertiary phosphines with alkyl halides with enhanced 96 : 4 dr. The isolated tertiary phosphine containing hydroxyl (in >99 : 1 dr) was converted to multi-stereogenic tertiary phosphines -alkylation with alkylene dihalides.

Recent Advances in Copper-Catalyzed C-N Bond Formation Involving N-Centered Radicals.

C-N bonds are pervasive throughout organic-based materials, natural products, pharmaceutical compounds, and agricultural chemicals. Considering the widespread importance of C-N bonds, the development of greener and more convenient ways to form C-N bonds, especially in late-stage synthesis, has become one of the hottest research goals in synthetic chemistry. Copper-catalyzed radical reactions involving N-centered radicals have emerged as a sustainable and promising approach to build C-N bonds.

Selective divergent radical cyclization of 1,6-dienes with alkyl nitriles.

An efficient, selective, and step economical radical cyclization of 1,6-dienes with alkyl nitriles initiated by α-C(sp)-H functionalization under the Sc(OTf) and AgCO system is described here. The selective divergent cyclization relies on the substitution effect at the α-position of the acrylamide moiety and nitriles, which is terminated by hydrogen abstraction, direct cyclization with the aryl ring, or further cyclization with the CN bond and hydrolysis, respectively.

Recent progress in the radical α-C(sp)-H functionalization of ketones.

The direct use structurally simple ketones as α-ketone radical sources for α-C(sp)-H functionalization is a sustainable and powerful approach for constructing complex and multifunctional chemical scaffolds with diverse applications. The reactions of α-ketone radicals with alkenes, alkynes, enynes, imides, and imidazo[1,2-a]pyridines have broadened the structural diversity and complexity of ketones. Through chosen illustrative examples, we outline the recent progress in the development of methods that enable the radical α-C(sp)-H functionalization of ketones, with an emphasis on radical initiation systems and possible mechanisms of the transformations.

The construction of benzimidazo[2,1-]isoquinolin-6(5)-ones from -methacryloyl-2-phenylbenzoimidazoles through radical strategies.

Benzimidazo[2,1-]isoquinolin-6(5)-one constitutes a structurally unique class of tetracyclic N-heterocycles that are found throughout a myriad of biologically active natural products, pharmaceutical compounds, and functional materials. Various synthetic routes for the preparation of benzimidazo[2,1-]isoquinolin-6(5)-ones have been reported. In particular, the use of -methacryloyl-2-phenylbenzoimidazoles to construct benzimidazo[2,1-]isoquinolin-6(5)-ones through various radical strategies have attracted widespread attention due to the versatility and simple preparation of raw materials, as well as the step-economy and mild reaction conditions.

Radical Cyclization of 1,n-Enynes and 1,n-Dienes for the Synthesis of 2-Pyrrolidone.

2-Pyrrolidones have aroused enormous interest as a useful structural moiety in drug discovery; however, not only does their syntheses suffer from low selectivity and yield, but also it requires high catalyst loadings. The radical cyclization of 1,n-enynes and 1,n-dienes has demonstrated to be an attractive method for the synthesis of 2-pyrrolidones due to its mild reaction conditions, fewer steps, higher atom economy, excellent functional group compatibility, and high regioselectivity. Furthermore, radical receptors with unsaturated bonds (i.

Visible-Light-Catalyzed N-Radical-Enabled Cyclization of Alkenes for the Synthesis of Five-Membered N-Heterocycles.

Five-membered N-heterocycles play an important role in organic synthesis and material chemistry, as they are widespread through pharmaceutical molecules and natural products. Chemists have developed many synthetic strategies for constructing five-membered N-heterocycles from N-centered radicals, but the availability of mild and green methods for these transformations is still limited. The cyclization of visible-light-generated N-centered radicals with alkenes has emerged as a powerful tool to enable these chemical transformations in recent years.

ZnO-CoO/N-C Cage Derived from the Hollow Zn/Co ZIF for Enhanced Degradation of Bisphenol A with Persulfate.

The zeolitic imidazolate framework (ZIF)-67 microcrystal was employed as a precursor to synthesize the hollow ZIF-8/ZIF-67 composite the epitaxial growth of ZIF-8 on ZIF-67, self-sacrifice, and excavation of ZIF-67. The hollow ZIF-8/ZIF-67 composite was successfully transformed to the ZnO-CoO/N-C cage by thermal treatment, which was further used as the catalyst for the oxidative degradation of bisphenol A (BPA) in the presence of potassium persulfate (PS). In comparison with the CoO/N-C and CoO obtained from pure ZIF-67 and cobalt nitrate, the ZnO-CoO/N-C cage demonstrated a more than four fold-higher activity and robust reusability.

Sulfonyl radical triggered selective iodosulfonylation and bicyclization of 1,6-dienes.

A novel sulfonyl radical triggered selective iodosulfonylation and bicyclization of 1,6-dienes has been described for the first time. High selectivity and efficiency, mild reaction conditions, excellent functional group compatibility, and broad substrate scope are the attractive features of this synthetic protocol, which provides a unique platform for precise radical cyclization.

Enhanced Photodetection Performance of Photodetectors Based on Indium-Doped Tin Disulfide Few Layers.

Two dimensional (2D) tin disulfide (SnS) has attracted growing interest as a promising high performance photodetector with superior performance such as fast response time, high responsivity, and good stability. However, SnS-based photodetectors still face great challenges, and the photodetection performance needs to be improved for practical applications. Herein, indium-doped SnS (In-SnS) few layers were exfoliated from CVT-grown single crystals, which were synthesized by chemical vapor transport.

Recent advances in acyl radical enabled reactions between aldehydes and alkenes.

Radical-mediated functionalization of alkenes has been emerging as an elegant and straightforward protocol to increase molecule complexity. Moreover, the abstraction of a hydrogen atom from aldehydes to afford acyl radicals has evolved as a rising star due to its high atom-economy and the ready availability of aldehydes. Considering the great influence and synthetic potential of acyl radical enabled reactions between aldehydes and alkenes, we provide a summary of the state of the art in this field with a specific emphasis on the working models and corresponding mechanisms.

An Integrated Mission Planning Framework for Sensor Allocation and Path Planning of Heterogeneous Multi-UAV Systems.

Mission planning is the guidance for a UAV team to perform missions, which plays the most critical role in military and civil applications. For complex tasks, it requires heterogeneous cooperative multi-UAVs to satisfy several mission requirements. Meanwhile, airborne sensor allocation and path planning are the critical components of heterogeneous multi-UAVs system mission planning problems, which affect the mission profit to a large extent.

Ultrathin Amorphous/Crystalline Heterophase Rh and Rh Alloy Nanosheets as Tandem Catalysts for Direct Indole Synthesis.

Heterogeneous noble-metal-based catalysis plays an essential role in the production of fine chemicals. Rh-based catalysts are one of the most active candidates for indole synthesis. However, it is still highly desired to develop heterogeneous Rh-based catalysts with high activity and selectivity.

Oxidize Amines to Nitrile Oxides: One Type of Amine Oxidation and Its Application to Directly Construct Isoxazoles and Isoxazolines.

A facile oxidative heterocyclization of commercially available amines and -butyl nitrite with alkynes or alkenes leading to isoxazoles or isoxazolines is described. The unprecedented strategy of the oxidation of an amine directly to a nitrile oxide was used in this cyclization process. This reaction is highly efficient, regiospecific, operationally simple, mild, and tolerant of a variety of functional groups.