The tensile properties of fiber metal laminates were examined at temperatures ranging from 30 °C to 180 °C in this paper through the integration of numerical simulation techniques, experimental measurements, and digital image correlation techniques. The laminates were initially modeled using finite elements, and the failure behavior of porous basalt-fiber-reinforced aluminum alloy plates was numerically simulated. Consequently, metal fiber laminate stress-strain responses were varied by numerous tensile experiments conducted at varying temperatures.
View Article and Find Full Text PDFSpectrochim Acta A Mol Biomol Spectrosc
February 2025
Eu-activated materials have garnered significant attention due to their outstanding optical characteristics. In this work, the sol-gel method was successfully used to prepare BiMoO phosphors doped with different amounts of Eu. The generated samples were identified as orthorhombic BiMoO with a scheelite-like structure by X-ray diffraction analysis of the crystal structure.
View Article and Find Full Text PDFFor the first time, nanotubes of YGaO:Cr (referred to as YGO:Cr) and YGaO:Cr/Yb (referred to as YGO:Cr/Yb) were produced via a single-needle electrospinning method. The nanotubes of YGO:Cr and YGO:Cr/Yb have outer diameters between 190 and 210 nm, whereas the inner diameter ranges between 70 and 80 nm, and the wall thickness ranges from 50 to 60 nm. The temperature sensitivity of YGO:0.
View Article and Find Full Text PDFGlioblastoma (GBM), a prevalent and aggressive brain tumor, poses significant treatment challenges due to its rapid progression and the difficulty in achieving complete surgical resection. The current treatment regime, primarily surgery followed by radiotherapy and chemotherapy, offers limited success, with a five-year survival rate of less than 10 %. For addressing the challenges faced in the treatment of GBM, an approach using a biopolymer implant constructed with dynamic reversible covalent bonds, was designed to achieve controlled and constant-rate release of chemotherapy drug (Temozolomide, TMZ), immune adjuvant (Resiquimod, R848) and checkpoint inhibitor (5-carboxy-8-hydroxyquinoline, IOX1).
View Article and Find Full Text PDFSpectrochim Acta A Mol Biomol Spectrosc
December 2024
The development of white phosphors that can be activated in near-ultraviolet light is highly important in the field of LED lighting. In this work, a series of color-tunable Y(TiHf)O:Eu phosphors were prepared by adjusting the HfO and Eu concentrations. In particular, white Y(TiHf)O:Eu phosphors were successfully synthesized and emitted a broad band covering the entire visible light region upon excitation with 340 nm UV light.
View Article and Find Full Text PDFThe influence of cooling history for the ZnGaGeO/Cr phosphors prepared by solid state reaction on the spectral properties was discovered, and an anticounterfeiting scheme based on the identification with smartphone was proposed and experimentally demonstrated using the studied phosphors. A combination of color-tunable visible fluorescence emission and near-infrared (NIR) afterglow emission in ZnGaGeO/ mol % Cr( = 0, 0.05, 1, 2, 3, and 4) phosphors to achieve multimode anticounterfeiting was reported.
View Article and Find Full Text PDFA series of Tb-doped SrYTaO double perovskite phosphors (SYT:Tb) were synthesized using a conventional solid-state reaction method. A strong green emission was observed in the SYT:Tb phosphors, and the optimal doping concentration of Tb was confirmed to be 5 mol%. The electric dipole-dipole interaction was ascribed to be the main mechanism for the luminescence concentration quenching.
View Article and Find Full Text PDFRaising photoelectric conversion efficiency and enhancing heat management are two critical concerns for silicon-based solar cells. In this work, efficient Yb infrared emissions from both quantum cutting and upconversion were demonstrated by adjusting Er and Yb concentrations, and thermo-manage-applicable temperature sensing based on the luminescence intensity ratio of two super-low thermal quenching levels was discovered in an Er/Yb co-doped tungstate system. The quantum cutting mechanism was clearly decrypted as a two-step energy transfer process from Er to Yb.
View Article and Find Full Text PDFSpectrochim Acta A Mol Biomol Spectrosc
March 2024
Anti-counterfeiting labels based on luminescence materials are a newly emerging technique for protecting legal goods and intellectual property. In the anti-counterfeiting field to prevent forgery and cloning, luminescence materials with properties different from the commercialized and traditional ones are in urgent need. In this work, multicolor-emitting Er single-doped and Er/Yb co-doped ZnGeO phosphors combining static and dynamic identifications were developed in order to achieve advanced anti-counterfeiting application.
View Article and Find Full Text PDFFluorescent CDs tend to undergo solid-state aggregation quenching in powder form. This is caused by the stacking of π-π conjugate structures and excessive resonant energy transfer. Moreover, various forms of N play an important role in white CDs suitable for LED applications.
View Article and Find Full Text PDFM-NC catalysts were prepared by a combination of the electrospinning method and thermal treatment. For the first time, the contribution of N-species to the ORR (oxygen reduction reaction) of the M-NC was analysed using XPS (X-ray photoelectron spectroscopy). The obtained relations were verified by VASP (Vienna Ab-initio Simulation Package).
View Article and Find Full Text PDFThe infiltrative growth and malignant biological behavior of glioma make it one of the most challenging malignant tumors in the brain, and how to maximize the extent of resection (EOR) while minimizing the impact on normal brain tissue is the pursuit of neurosurgeons. The current intraoperative visualization assistance techniques applied in clinical practice suffer from low specificity, slow detection speed and low accuracy, while Raman spectroscopy (RS) is a novel spectroscopy technique gradually developed and applied to clinical practice in recent years, which has the advantages of being non-destructive, rapid and accurate at the same time, allowing excellent intraoperative identification of gliomas. In the present work, the latest research on Raman spectroscopy in glioma is summarized to explore the prospect of Raman spectroscopy in glioma surgery.
View Article and Find Full Text PDFEnergy harvesting (EH) is a potential solution to enhance the node sustainability and prolong the network lifetime of cognitive radio sensor networks (CRSNs). However, CRSNs nodes can only harvest energy from the direct link with energy sources, and severe path loss results in low energy utilization ratio. To solve the above problem, intelligent reflecting surface (IRS) is introduced, and a shared reflection coefficient matrix-based EH scheme is proposed for IRS-aided CRSNs in this paper.
View Article and Find Full Text PDFSpectrochim Acta A Mol Biomol Spectrosc
March 2023
The content of Cu in lubricating oil and lubricant temperature are important indicators predicting mechanical failure. Therefore, developing a nontoxic fluorescence probe is necessary to detect Cu and temperature in lubricating oil. The lead-free inorganic double perovskite nanocrystals (NCs) CsAgInCl are potential candidates.
View Article and Find Full Text PDFSpectrochim Acta A Mol Biomol Spectrosc
January 2023
In this study, intense red and extremely weak green up-conversion (UC) luminescence was obtained in BaGdO: x mol% Yb/y mol% Er phosphors under the excitations of 980 nm and 1550 nm. The corresponding maximum integrated intensity ratios of the red to green UC emissions are 50.3 and 158.
View Article and Find Full Text PDF"Thermal expansion and cold contraction" are common occurrences in nature. Resulting from "thermal expansion and cold contraction" reaction, strain effect is created, which affects the oxygen reduction reaction (ORR) activities of fuel cell catalysts. Nevertheless, the "thermal expansion and cold contraction" effects of catalysts have rarely been investigated.
View Article and Find Full Text PDFThere is growing evidence supporting the implications of exosomes-shuttled microRNAs (miRs) in the phenotypes of glioblastoma stem cells (GSCs), whilst the role of exosomal miR-27b-3p remains to be established. Herein, the aim of this study was to investigate the effect of M2 tumor-associated macrophage (TAM)-derived exosomal miR-27b-3p on the function of GSCs. Clinical glioblastoma (GBM) specimens were obtained and GSCs and M2-TAMs were isolated by fluorescence-activated cell sorting (FACS), and exosomes were separated from M2-TAMs.
View Article and Find Full Text PDFPurpose: Primary sporadic intradural malignant peripheral nerve sheath tumor (MPNST) in the spinal canal is a type of rare neoplasm with challenging diagnosis and therapy. The overall prognosis of this tumor is markedly different from that of the usual spinal intradural tumors. The purpose of this systematic review is to reduce the misdiagnosis and enhance the prognosis of the disease by reviewing the literature.
View Article and Find Full Text PDFGlioblastoma (GBM) cell-derived extracellular vesicles (EVs) have been demonstrated to modulate tumor microenvironment. In the present study, we attempted to discuss the role of hsa-microRNA-27a-3p (miR-27a-3p) delivered by GBM-EVs in M2 macrophage polarization. The isolated GBM-EVs were co-cultured with macrophages.
View Article and Find Full Text PDFBroadband tunable solid-state lasers continue to present challenges to scientists today. The gain medium is significant for realizing broadband tunable solid-state lasers. In this investigation, the optical gain performance for Tm and Cu single-doped and co-doped germanate glasses with broadband emissions was studied via an amplified spontaneous emission (ASE) technique.
View Article and Find Full Text PDFGliomas are the most common primary malignant tumors of the central nervous system, and their conventional treatment involves maximal safe surgical resection combined with radiotherapy and temozolomide chemotherapy; however, this treatment does not meet the requirements of patients in terms of survival and quality of life. Graphene oxide (GO) has excellent physical and chemical properties and plays an important role in the treatment of gliomas mainly through four applications, viz. direct killing, drug delivery, immunotherapy, and phototherapy.
View Article and Find Full Text PDFNon-small cell lung cancer (NSCLC) is one of the most common malignant tumors and has high morbidity and mortality rates. Central nervous system (CNS) metastasis is one of the most frequent complications in patients with NSCLC and seriously affects the quality of life (QOL) and overall survival (OS) of patients, with a median OS of untreated patients of only 1-3 months. There are various treatment methods for NSCLC CNS metastasis, including surgery, chemotherapy, radiotherapy, targeted therapy, and immunotherapy, which do not meet the requirements of patients in terms of improving OS and QOL.
View Article and Find Full Text PDFSpectrochim Acta A Mol Biomol Spectrosc
January 2022
A turn on upconversion fluorescence probe based on the combination of ~32 nm NaYF: Yb/Tm nanoparticles and MnO nanosheets has been established for rapid, sensitive detection of Fe ions levels in aqueous solutions and serum. X-ray diffraction (XRD), transmission electron microscopy (TEM), absorption and emission spectra have been used to characterize the crystal structure, morphology and optical properties of the samples. MnO nanosheets on the surface of UCNPs act as a fluorescence quencher, resulting in the quenching of the blue fluorescence (with excitation/emission maximum of 980/476 nm) via fluorescence resonance energy transfer from upconversion nanoparticles to MnO nanosheets.
View Article and Find Full Text PDFBackground: In this study, we determine the potential roles and uncover the regulatory mechanisms of circCCDC66 in regulating cell growth and cell metastasis of glioma.
Methods: qRT-PCR was used to detect the expressions of circCCDC66 in gliomas and tissues. The biological function of circCCDC66 in glioma cell lines was elucidated by functional experiments.
Spectrochim Acta A Mol Biomol Spectrosc
November 2021
GdNbTiO: Sm phosphors with various Sm concentrations were prepared via a high temperature solid-state reaction method. The crystal structure of the samples was characterized by means of X-ray diffraction (XRD) and the as-prepared samples were confirmed to be orthorhombic phase GdNbTiO. Photoluminescence properties were investigated by measuring the concentration- and temperature-dependent photoluminescence spectra.
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