Photo-responsive nanoporous liquid crystal polymer films for selective dye adsorption.

Photo-responsive nanoporous polymer films (AZOF-R(NC6)) have been developed by a template method based on a hydrogen-bonding supramolecular liquid crystal (LC) and a light-sensitive azobenzene LC crosslinker in this work. Anionic nanopores were obtained after the removal of template NC6 using KOH solution. The AZOF-R(NC6) demonstrates charge-selective dye adsorption and the maximum adsorption capacity for Rh6G is 504.

In Situ Generated Dual-Template Method for Fe/N/S Co-Doped Hierarchically Porous Honeycomb Carbon for High-Performance Oxygen Reduction.

Heteroatoms doping is able to produce catalytic sites in carbon materials for oxygen reduction reaction (ORR); while hierarchically porous structure is necessary for efficient exposure and accessibility of the usually limited catalytic sites in such activated carbon catalysts. This work reports an in situ generated dual-template method to synthesize the Fe/N/S co-doped hierarchically porous carbon (FeNS/HPC), with NaCl crystallites formed during the precursor lyophilization process as the primary template to generate ∼500 nm macropores with ultrathin graphene-like carbon-layer walls, and FeO nanoparticles formed during the high-temperature carbonization process as the secondary template to produce mesopores on the walls of macropores. As well as the coexistence of graphitic-N, pyridinic-N, and thiophene-S which are beneficial to ORR, the as prepared FeNS/HPC possesses a highly graphitized and interconnected hierarchical porous structure, giving a specific surface area as high as 938 m g.