Two-dimensional (2D) metallic transition metal dichalcogenides (TMDCs) have attracted extensive interest in various fields owing to their unique electronic properties. However, studies on their transport properties and the modulation of these properties based on their band structure are limited. Herein, we studied the transport phenomena in 2D metallic 2H-NbSe using experimental and theoretical approaches.
View Article and Find Full Text PDFNovel two-dimensional semiconductor crystals can exhibit diverse physical properties beyond their inherent semiconducting attributes, making their pursuit paramount. Memristive properties, as exemplars of these attributes, are predominantly manifested in wide-bandgap materials. However, simultaneously harnessing semiconductor properties alongside memristive characteristics to produce memtransistors is challenging.
View Article and Find Full Text PDF2D transition metal dichalcogenides (TMDCs) have revealed great promise for realizing electronics at the nanoscale. Despite significant interests that have emerged for their thermoelectric applications due to their predicted high thermoelectric figure of merit, suitable doping methods to improve and optimize the thermoelectric power factor of TMDCs have not been studied extensively. In this respect, molecular charge-transfer doping is utilized effectively in TMDC-based nanoelectronic devices due to its facile and controllable nature owing to a diverse range of molecular designs available for modulating the degree of charge transfer.
View Article and Find Full Text PDFWith the recent reillumination of the hydrogen economy around the world, the demand for H sensors is expected to increase rapidly. Due to safety issues caused by the highly flammable and explosive character of hydrogen gas (H ), it is imperative to develop the sensors that can quickly and sensitively detect H leaks. For the development of H sensors, Pd-based materials have been extensively used due to the high affinity of Pd metal for H .
View Article and Find Full Text PDFPhotolithography is the prevalent microfabrication technology. It needs to meet resolution and yield demands at a cost that makes it economically viable. However, conventional far-field photolithography has reached the diffraction limit, which imposes complex optics and short-wavelength beam source to achieve high resolution at the expense of cost efficiency.
View Article and Find Full Text PDFElectronic band engineering is a promising approach to enhance the thermopower of thermoelectric materials. In transition-metal dichalcogenides (TMDCs), this has so far only been achieved using their inherent semiconducting nature. Here, we report the thickness-modulated band engineering of nanosheets based on semimetallic platinum diselenide (PtSe) resulting in a thermopower enhancement of more than 50 times than that of the bulk.
View Article and Find Full Text PDFACS Appl Mater Interfaces
January 2019
Wetting of the liquid metal on the solid electrolyte of a liquid metal battery controls the operating temperature and performance of the battery. Liquid sodium electrodes are particularly attractive because of their low cost, natural abundance, and geological distribution. However, they wet poorly on a solid electrolyte near its melting temperature, limiting their widespread suitability for low-temperature batteries to be used for large-scale energy storage systems.
View Article and Find Full Text PDFThe electrical conductivity and Seebeck coefficient of RuO nanosheets are enhanced by metal nanoparticle doping using Ag-acetate solutions. In this study, RuO monolayer and bilayer nanosheets exfoliated from layered alkali metal ruthenates are transferred to Si substrates for device fabrication, and the temperature dependence of their conductivity and Seebeck coefficients is investigated. For pristine RuO nanosheets, the sign of the Seebeck coefficient changes with temperature from 350-450 K.
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