The microbiologically influenced corrosion inhibition (MICI) of Q235 carbon steel by Shewanella putrefaciens and mediated calcium deposition were investigated by regulating microbial mineralization. In a calcium-rich medium, S. putrefaciens rapidly created a protective calcium carbonate layer on the steel surface, which blocked Cl diffusion.
View Article and Find Full Text PDFThe microbiologically influenced corrosion of 201 stainless steel by was investigated via modulating the concentration of fumarate (electron acceptor) in the medium and constructing mutant strains induced by Δ. The ICP-MS and electrochemical tests showed that the presence of enhanced the degradation of the passive film; the lack of an electron acceptor further aggravated the effect and mainly affected the early stage of MIC. The electrochemical tests and atomic force microscopy characterization revealed that the ability of Δ to transfer electrons to the passive film was significantly reduced in the absence of the c-type cytochrome related to EET progress, leading to the lower corrosion rate of the steel.
View Article and Find Full Text PDFis widely found in industrial water and seawater. Microbiologically influenced corrosion (MIC) caused by is a serious threat and damage to the safe service of steel materials. In this study, the MIC behavior of FeCoNiCrMn high-entropy alloy (HEA) by biofilm was investigated in the simulated marine medium.
View Article and Find Full Text PDFAntifoulants are the most vital substances in antifouling coatings to prevent marine organisms from colonizing the undersea substrate surfaces. In addition to antibacterial performance, inhibition of biofilm formation is an important criterion for antifouling coatings. In this study, we synthesized pH-responsive matrine@chitosan-D-proline (Mat@CS-Pro) nanocapsules of about 280 nm with antibacterial properties and biofilm dispersibility.
View Article and Find Full Text PDFThe microbiologically influenced corrosion of pure iron was investigated in the presence of Shewanella oneidensis MR-1 with various levels of exogenous riboflavin (RF) serving as electron shuttles for extracellular electron transfer (EET). With more RF available, a larger and denser phosphate layer was formed on the surface of pure iron by the bacteria. The results of electrochemical impedance spectroscopy, linear polarization resistance and potentiodynamic polarization tests showed that the product layer provided good corrosion protection to the pure iron.
View Article and Find Full Text PDFIn this study, the influence of exogenous pyocyanin (PYO) on the microbiologically influenced corrosion (MIC) of 304 stainless steel by Pseudomonas aeruginosa was investigated. Under sterile condition, the additional PYO in the culture medium had no effect on the corrosion of 304 stainless steel. In contrast, P.
View Article and Find Full Text PDFMicrobial activities can change the properties of biofilm/metal interfaces to accelerate or decelerate the corrosion of metals in a given environment. Microbiologically influenced corrosion inhibition (MICI) is the inhibition of corrosion that is directly or indirectly induced by microbial action. Compared with conventional methods for protection from corrosion, MICI is environmentally friendly and an emerging approach for the prevention and treatment of (bio)corrosion.
View Article and Find Full Text PDFBy anodization and thermal oxidation at 600 °C, an oxide layer on Ti with excellent corrosion resistance in strong acid solutions was prepared. The structural properties of TiO films before and after thermal oxidation were investigated with methods of Scanning electron microscope (SEM), X-ray photoelectron spectroscopy (XPS) and X-ray diffraction (XRD). The electrochemical characterization was recorded via electrochemical impedance spectroscopy, potentiodynamic polarization and Mott-Schottky methods.
View Article and Find Full Text PDFThe influence of NaCl concentration on microbiologically influenced corrosion (MIC) of Q235 carbon steel by the halophilic archaeon Natronorubrum tibetense was investigated by immersion tests and electrochemical measurements. An increase in NaCl concentration from 0 g/mL to 0.1 g/mL promoted the anodic dissolution of carbon steel and accelerated its corrosion, but MIC did not occur.
View Article and Find Full Text PDFThe process of microbiologically influenced corrosion (MIC) in soils has received widespread attention. Herein, long-term outdoor soil burial experiments were conducted to elucidate the community composition and functional interaction of soil microorganisms associated with metal corrosion. The results indicated that iron-oxidizing (e.
View Article and Find Full Text PDFIn this study, the influence of thermoacidophilic archaeon Metallosphaera cuprina on the corrosion of 304 stainless steel was investigated. 304 stainless steel in M. cuprina-inoculated culture medium exhibited more marked pitting corrosion behavior than that seen in sterile culture medium.
View Article and Find Full Text PDFIn this work, microbiologically influenced corrosion (MIC) of 304 stainless steel (SS) caused by Bacillus cereus was investigated by electrochemical measurements and surface analyses in simulated Beijing soil solution under aerobic condition. The nitrate-reducing bacterium (NRB), B. cereus, was isolated from Beijing soil and identified using 16S rDNA.
View Article and Find Full Text PDFThe influence of dissolved oxygen concentration (DOC) on the microbiologically influenced corrosion (MIC) of Q235 carbon steel in the culture medium of halophilic archaeon was investigated. The increase of DOC from 0.0 to 3.
View Article and Find Full Text PDFIn this study, a new self-healing shape memory polymer (SMP) coating was prepared to protect the aluminum alloy 2024-T3 from corrosion by the incorporation of dual-function microspheres containing polycaprolactone and the corrosion inhibitor 8-hydroxyquinoline (8HQ). The self-healing properties of the coatings were investigated via scanning electron microscopy, electrochemical impedance spectroscopy, and scanning electrochemical microscopy following the application of different healing conditions. The results demonstrated that the coating possessed a triple-action self-healing ability enabled by the cooperation of the 8HQ inhibitor, the SMP coating matrix, and the melted microspheres.
View Article and Find Full Text PDFMater Sci Eng C Mater Biol Appl
November 2017
In this study, a multilayer antibacterial film was assembled onto 316L stainless steel via mussel-inspired depositions of polydopamine (PDA) and silver (Ag) nanoparticles followed by post-modification with 1H, 1H, 2H, 2H-perfluorodecanethiol. The resulting surface exhibited excellent superhydrophobicity with hierarchical micro/nanostructures that were constructed by both PDA and Ag nanoparticles. The crystal structure and chemical composition of these surfaces were investigated using X-ray photoelectron spectroscopy (XPS) analysis.
View Article and Find Full Text PDFThe corrosion behavior of X80 steel in the presence of coupled coating defects was simulated and studied under the interference of alternating current (AC) in an alkaline environment. The results from electrochemical measurements showed that the electrode potential of the coating defect with the smaller exposed area was lower than that with the larger area, which indicated that the steel with the smaller coating defect was more prone to corrosion. The result of weight loss tests also showed that the smaller coating defect had induced a higher corrosion rate.
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