As one of the best candidates for hydrogen oxidation reaction (HOR), ruthenium (Ru) has attracted significant attention for anion exchange membrane fuel cells (AEMFCs), although it suffers from sluggish kinetics under alkaline conditions due to its strong hydroxide affinity. In this work, we develop ternary hollow nanocages with Pt epitaxy on RuCu (Pt-RuCu NCs) as efficient HOR catalysts for application in AEMFCs. Experimental characterizations and theoretical calculations confirm that the synergy in optimized Pt-RuCu NCs significantly modifies the electronic structure and coordination environment of Ru, thereby balancing the binding strengths of H* and OH* species, which leads to a markedly enhanced HOR performance.
View Article and Find Full Text PDFThe intrinsic performance of an electrocatalyst can be reinforced by constructing appropriate epitaxial interfaces, where the modulated electronic states and adsorption/desorption behaviors are conductive to enhancing electrocatalytic activity. Herein, nickel-nickelous hydroxide epitaxial interface supported on nickel foam (Ni-Ni(OH)/NF) with epitaxial growth of nickel nanoparticles on the surface of nickelous hydroxide nanoribbons is devised for alkaline hydrogen evolution reaction (HER). Notably, the Ni-Ni(OH)/NF reveals excellent electrocatalytic activity of alkaline HER (158 mV @ 100 mA cm), along with robust stability (90 % activity retention after 150 h continuous test at 200 mA cm).
View Article and Find Full Text PDFCurrently, there is limited research on the in situ forming process of thermoplastic prepreg tape winding, and the unclear impact of process parameters on mechanical properties during manufacturing is becoming increasingly prominent. The study aimed to investigate the influence of process parameters on the mechanical properties of thermoplastic composite materials (CFRP) using laser-assisted CF/PPS winding forming technology. The melting point and decomposition temperature of CF/PPS materials were determined using DSC and TGA instruments, and based on the operating parameters of the laser-assisted winding equipment, the process parameter range for this fabrication technology was designed.
View Article and Find Full Text PDFMetallic lithium is the most competitive anode material for next-generation high-energy batteries. Nevertheless, the extensive volume expansion and uncontrolled Li dendrite growth of lithium metal not only cause potential safety hazards but also lead to low Coulombic efficiency and inferior cycling lifespan for Li metal batteries. Herein, a multifunctional dendrite-free composite anode (Li/SnS) is proposed through an in situ melt-infusion strategy.
View Article and Find Full Text PDFCarbon materials have great potential for applications in energy, biology, and environment due to their excellent chemical and physical properties. Their preparation by carbonization methods encounters limitations and the carbon loss during pyrolysis in the form of gaseous molecules results in low yield of carbon materials. Herein a low-energy (600 °C) and high-yield (82 wt.
View Article and Find Full Text PDFEnhancing the flame retardancy of epoxy (EP) resins typically entailed a trade-off with other physical properties. Herein, hyperbranched poly(amidoamine) (HPAA) and phytic acid (PA) were used to functionalize graphene oxide (GO) via electrostatic self-assembly in water to prepare a phosphorus-nitrogen functionalized graphene oxide nanosheet (PN-GOs), which could be utilized as high efficient flame-retardant additive of epoxy resin without sacrificing other properties. The PN-GOs demonstrated improved dispersion and compatibility within the EP matrix, which resulted in significant concurrent enhancements in both the mechanical performance and flame-retardant properties of the PN-GOs/EP nanocomposites over virgin EP.
View Article and Find Full Text PDFAnion exchange membrane fuel cells are a potentially cost-effective energy conversion technology, however, the electrocatalyst for the anodic hydrogen oxidation reaction (HOR) suffers from sluggish kinetics under alkaline conditions. Herein, we report that Ru-based nanosheets with amorphous-crystalline heterointerfaces of Ru and Ti-doped RuO (a/c-Ru/Ti-RuO) can serve as a highly efficient HOR catalyst with a mass activity of 4.16 A mg, which is 19.
View Article and Find Full Text PDFHO photosynthesis has attracted great interest in harvesting and converting solar energy to chemical energy. Nevertheless, the high-efficiency process of HO photosynthesis is driven by the low HO productivity due to the recombination of photogenerated electron-hole pairs, especially in the absence of a sacrificial agent. In this work, we demonstrate that ultrathin ZnInS nanosheets with S vacancies (S-ZIS) can serve as highly efficient catalysts for HO photosynthesis via O/HO redox.
View Article and Find Full Text PDFThe key to the innovation of sodium-ion batteries (SIBs) is to find efficient sodium-storage electrode. Here, metal Mo doping of NiSe is proposed by modified electrospinning strategy followed by in situ conversion process. The Mo-NiSe anchoring on hollow carbon nanofibers (HCNFs) would make full use of the multi-channel HCNFs in the inner layer and the active sites of Mo-NiSe in the outer layer, which plays an important role in buffering the volume stress of Na (de)insertion and reducing the adsorption energy barrier of Na.
View Article and Find Full Text PDFMolybdenum disulfide (MoS) has garnered attention as a promising anode material for sodium-ion batteries due to its high theoretical capacity and unique lamellar texture. Nevertheless, unmodified MoS suffers from inferior electrical conductivity, poor reaction reversibility, and suboptimal cycle life upon repeated sodiation/desodiation. In this study, a novel carbon-free V-heteroatom doping MoS composite (abbr.
View Article and Find Full Text PDFFor the continued use of sodium-ion batteries (SIBs), which require matching anode materials, it is crucial to create high energy density energy storage devices. Here, hollow nanoboxes shaped carbon supported sulfur-doped MoSe nanosheets (S-MoSe@NC) are fabricated by in situ growth and heterodoping strategy. This ensures that the MoSe nanosheets are tightly anchored to the nanoboxes carbon, and the structure can effectively buffer the volume stress caused by sodium ion (de)intercalation, as well as providing abundant ion/electron migration transportations.
View Article and Find Full Text PDFMicrowave absorbers with high efficiency and mechanical robustness are urgently desired to cope with more complex and harsh application scenarios. However, manipulating the trade-off between microwave absorption performance and mechanical properties is seldom realized in microwave absorbers. Here, a chemistry-tailored charge dynamic engineering strategy is proposed for sparking hetero-interfacial polarization and thus coordinating microwave attenuation ability with the interfacial bonding, endowing polymer-based composites with microwave absorption efficiency and mechanical toughness.
View Article and Find Full Text PDFThe development of high-quality anode materials is critical for the advancement of sodium-ion batteries (SIBs). MoSe is a candidate anode for SIBs, while its inherent limitations, such as the agglomeration of nanosheets, poor electron conductance and mechanical strain due to volume changes during cycling, which can lead to decreased performance and durability in SIBs. To overcome the challenges, a novel aliovalent doping and structural engineering was taken to prepare reduced graphene oxide (rGO) functionalized and phosphorus-doped MoSe flake (P-MoSe@rGO) via in situ growth technique.
View Article and Find Full Text PDFThe progress of sodium-ion batteries is currently confronted with a noteworthy obstacle, specifically the paucity of electrode materials that can store large quantities of Na in a reversible fashion while maintaining competitiveness. Herein, ultrafast and long-life sodium storage of metal selenides is rationally demonstrated by employing micron-sized nanosheets (Cu-CoSe@NC) through electron accumulation engineering. The nanosheet structure proves to be effective in reducing the transport distance of sodium ions.
View Article and Find Full Text PDFCurrently, the main obstacle to the widespread utilization of metal chalcogenides (MS ) as anode for potassium-ion batteries (PIBs) is their poor rate capability and inferior cycling stability as a result of the undesirable electrical conductivity and severe pulverization of the nanostructure during large K-ions intercalation-extraction processes. Herein, an ultrafast and long-life potassium storage of metal chalcogenide is rationally demonstrated by employing Fe Ni S solid-solution (FNS/C) through molecular structure engineering. Benefiting from improved electroactivity and intense interactions within the unique solid solution phase, the electrical conductivity and structure durability of Fe Ni S are vastly improved.
View Article and Find Full Text PDFAn interfacial covalent bonding strategy is proposed for the synthesis of the MXene-stabilized SbSe nanotube hybrid. As an anode material, the prepared SbSe@NC/MXene exhibits an enhanced sodium-ion battery performance in half/full batteries in terms of a high specific and cycling stability.
View Article and Find Full Text PDFHigh-entropy alloys (HEAs) have been attracting extensive research interests in designing advanced nanomaterials, while their precise control is still in the infancy stage. Herein, we have reported a well-defined PtBiPbNiCo hexagonal nanoplates (HEA HPs) as high-performance electrocatalysts. Structure analysis decodes that the HEA HP is constructed with PtBiPb medium-entropy core and PtBiNiCo high-entropy shell.
View Article and Find Full Text PDFThe shortage of high-capacity anode materials with long cycling stability is the main roadblock to the development of sodium-ion batteries (SIBs). The advantages of transition metal selenides are high theoretical capacity, safety and ease of design, which gradually make them potential substitute materials for the anodes of a new generation of SIBs. However, the low intrinsic conductivity of transition metal selenides and the serious powderization during charge and discharge processes restrict their rate performance and cycling stability in SIBs.
View Article and Find Full Text PDFCrystal phase engineering is an important strategy for designing noble-metal-based catalysts with optimized activity and stability. From the thermodynamic point of view, it remains a great challenge to synthesize unconventional phases of noble metals. Here, a new class of Pd-based nanostructure with unconventional rhombohedral Pd Sb phase is successfully synthesized.
View Article and Find Full Text PDFDeveloping microwave absorption (MA) materials with ultrahigh efficiency and facile preparation method remains a challenge. Herein, a superior 1D@2D@1D hierarchical structure integrated with multi-heterointerfaces via self-assembly and an autocatalytic pyrolysis is designed to fully unlock the microwave attenuation potential of materials, realizing ultra-efficient MA performance. By precisely regulating the morphology of the metal organic framework precursor toward improved impedance matching and intelligently integrating multi-heterointerfaces to boosted dielectric polarization, the specific return loss value of composites can be effectively tuned and optimized to -1002 dB at a very thin thickness of 1.
View Article and Find Full Text PDFDeveloping high-rate and durable anode materials for sodium-ion batteries (SIBs) is still a challenge because of the larger ion radius of sodium compared with the lithium ion during charge-discharge processes. Herein, NiTe coupled with N-doped carbon (NiTe/NC) hexagonal nanosheets has been fabricated through a solvothermal and subsequent carbonisation strategy. This unique hexagonal nanosheet structure offers abundant active sites and contact area to the electrolyte, which could shorten the Na diffusion path.
View Article and Find Full Text PDFOwing to their large theoretical capacity and relatively high electronic conductivity, transition metal selenides have been investigated as potential anodes for energy storage applications. On the other hand, the quick capacity decline induced by volume expansion during cycling and unconnected conducting network of the transition metal selenide-based electrode severely limit their employment in sodium-ion batteries (SIBs). Herein, a simple solvent ultrasonic technique and pyrolysis selenation process were used to make a porous N-doped carbon nanosheet-supported FeSe/CoSe electrode.
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