Liquid marbles (LMs) are microliter-scale droplets coated with hydrophobic solid particles. The particle size and hydrophobicity of the surface coating determine their properties, such as transparency, expandability, and resistance to evaporation and coalescence, one or more of which can be critical to their application as microreactors. This study reports the use of a mixture of two different hydrophobic powders for fabrication of LMs for colorimetric assays: trichloro(1,1,2,2-perfluorooctyl) silane-linked silica gel (modified silica gel (MSG), particle size: 40-75 μm) and hexamethyldisilazane-linked fumed silica (modified fumed silica (MFS), average aggregate length: 200-300 nm).
View Article and Find Full Text PDFThe increasing prevalence of pharmaceutical contaminants in aquatic ecosystems poses profound challenges for both environmental sustainability and public health. Addressing this pressing issue requires the development of innovative, cost-effective, and efficient remediation approaches. Here we report the synthesis of WO/diatomite composites and their photocatalytic degradation in conjunction with potassium peroxymonosulfate (PMS) activation.
View Article and Find Full Text PDFTailoring the microstructure of magnetic microparticles is of vital importance for their applications. Spiky magnetic particles, such as those made from sunflower pollens, have shown promise in single cell treatment and biofilm removal. Synthetic methods that can replicate or extend the functionality of such spiky particles would be advantageous for their widespread utilization.
View Article and Find Full Text PDFThe eradication of drug-resistant microbial biofilms remains an unresolved global health challenge. Small-scale robotics are providing innovative therapeutic and diagnostic approaches with high precision and efficacy. These approaches are rapidly moving from proof-of-concept studies to translational biomedical applications using ex vivo, animal, and clinical models.
View Article and Find Full Text PDFSlippery liquid-infused porous surfaces (SLIPS) show remarkable liquid repellency, making them useful for many coating applications. The outstanding repellency of SLIPS comes from a lubricant layer stabilized within and at the surface of a porous template. The stability of this lubricant layer is key for SLIPS to exhibit their unique functionality.
View Article and Find Full Text PDFBeilstein J Nanotechnol
January 2022
Semiconducting SnO photocatalyst nanomaterials are extensively used in energy and environmental research because of their outstanding physical and chemical properties. In recent years, nitrogen oxide (NO ) pollutants have received particular attention from the scientific community. The photocatalytic NO oxidation will be an important contribution to mitigate climate change in the future.
View Article and Find Full Text PDFPhotocatalysis has been studied and considered as a green and practical approach in addressing environmental pollution. However, factors that affect photocatalytic performance have not been systematically studied. In this work, we have presented a comprehensive roadmap for characterizing, interpreting, and reporting semiconductors' electrical and optical properties through routinely used techniques such as diffuse reflectance spectroscopy, electrochemical techniques (Mott-Schottky plots), photoluminescence, X-ray photoelectron spectroscopy, and ultraviolet photoelectron spectroscopy in the context of photocatalysis.
View Article and Find Full Text PDFPolymer-infiltrated nanoparticle films (PINFs) are a new class of nanocomposites that offer synergistic properties and functionality derived from unusually high fractions of nanomaterials. Recently, two versatile techniques,capillary rise infiltration (CaRI) and solvent-driven infiltration of polymer (SIP), have been introduced that exploit capillary forces in films of densely packed nanoparticles. In CaRI, a highly loaded PINF is produced by thermally induced wicking of polymer melt into the nanoparticle packing pores.
View Article and Find Full Text PDFNanocomposite films (NCFs) with vertically aligned nanowires (NWs) provide several useful properties owing to their unique morphology. One of the key challenges in producing such an NCF is retaining the vertical alignment of NWs during NCF fabrication. Although current methods such as layer-by-layer assembly and solution-based processes with field-induced alignment of NWs have been successfully demonstrated, these approaches require multiple steps thus are time-consuming, and only suitable for lab-scale production, consequently limiting their widespread applicability.
View Article and Find Full Text PDFHere, we synthesized copper(i) oxide and titanium dioxide nanotubes (TNTs) heterojunctions (HJs) by a photoreduction method using a low-power UV lamp without involving any additional steps, such as chemical reduction, surfactant, or protection agents. Transmission electron microscopy, X-ray diffraction, Raman scattering, X-ray photoelectron spectroscopy, diffuse reflectance spectra, and photoluminescence spectroscopy were carried out to verify the formation of a HJ between the CuO nanoparticles (CuO NPs) and TNTs. The efficiency and the rate of methylene blue photo-degradation over the CuO/TNTs HJ were found to be nearly double and triple compared to the isolated TNTs.
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