In this study, electrochemical sensors for the enantioselective recognition of d and l phenylalanine were prepared using a molecular imprinting technique in which the electro-polymerization of pyrrole was carried out by Chronopotentiometry(CP) with the target molecules being present on a Ag screen printed electrode's (SPE) surface. The sensing performance was evaluated by multi-potential steps at 0 and 2V(vs. Ag/AgCl) held for 1s and 2s, respectively, for 20 cycles (with the two enantiomers being present at the same concentration).
View Article and Find Full Text PDFIn this study, copolymers based on 1,3-bis(carbazol-9-yl)benzene (BCz) and three 3,4-ethylenedioxythiophene derivatives (3,4-ethylenedioxythiophene (EDOT), 3,4-(2,2-dimethylpropylenedioxy)thiophene (ProDOT-Me₂), and 3,4-ethylenedithiathiophene (EDTT)) were electrochemically synthesized and their electrochemical and electrochromic properties were characterized. The anodic copolymer P(BCz--ProDOT) with BCz/ProDOT-Me₂ = 1/1 feed molar ratio showed high optical contrast (Δ%) and coloring efficiency (η), measured as 52.5% and 153.
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