The study looks into how SrPBr and SrNCl double perovskite materials can be used as absorbers in perovskite solar cells (PSCs). Computational SrPBr and SrNCl simulations were employed to assess the performance of each absorber together with electron transport layers (ETL), with a particular emphasis on optimizing ETL thickness to improve charge transport and synchronize current outputs. The simulations yielded valuable insights into the electronic and optical characteristics of the individual absorbers.
View Article and Find Full Text PDFPorous clay heterostructures are a hybrid precursor between the pillaring process and organoclays. In this study, the organoclay was substituted by an aluminium intercalated species clay or pillared alumina clays. A porous clay heterostructure was successfully achieved from an aluminium intercalated species clay, due to the easy exchange of the aluminium species by the cosurfactant and silica species.
View Article and Find Full Text PDFSolar cells are fabricated based on two new dyes. Dye acts as an additive to thin layer interface. The effect of the -conjugated rigidity of the thiophene rings on the photovoltaic characteristics has been investigated.
View Article and Find Full Text PDFZirconium porous clay heterostructures (Zr-PCH) were synthesized using intercalated clay minerals by zirconium species with different contents of zirconium. The presence of zirconium and silica species was confirmed by X-ray diffraction, X-ray fluorescence, and magic-angle spinning nuclear magnetic resonance. The insertion of zirconium improved the thermal stability, the specific surface area with a maximum of 950 m/g, and the acidity concentration of 0.
View Article and Find Full Text PDFThe significance of the Fowler-Nordheim-type plots lies in the possibility of extracting useful and reliable physical parameters of the field electron emitters. This is achieved by the parameter's extraction methods. We report on the application of two parameters extraction methods on field emission data from bundles of carbon fibers (CFs) grouped in nickel tubes and operated inside a typical field emission microscope setup.
View Article and Find Full Text PDFThe removal of Basic Blue-41 dye molecules was carried out by using two doped porous clay heterostructures by aluminum (Al) or zirconium (Zr) species. The proposed method of synthesis showed its efficiency, starting from Al or Zr intercalated hydrolyzed species, prior to its reaction with dodecylamine (C amine) and tetraethyl orthosilicate (TEOS) as a silica source. The intercalated precursors and their porous clay heterostructures (PCH) derivatives were characterized by different techniques.
View Article and Find Full Text PDFA dye-sensitized solar cell was constructed on the basis of encapsulating the ruthenium polypyridyl photosensitizer Z907 in the macrocycle cucurbit[7]uril (CB7). The work focuses on the photophysical properties of the new host-guest complexes in acetonitrile and water (volume ratio 1:9) and on the top of nanocrystalline titanium dioxide (TiO) electrode prior to the addition of poly(3-hexylthiophene) polymer and gold electrode. Complexation to CB7 in aqueous solutions has decreased the emission intensity and excited-state lifetime for metal-to-ligand charge transfer (MLCT) state at 650 nm by twofold because of collisional quenching, which opens a non-radiative deactivation channel.
View Article and Find Full Text PDFThe performance of a dye-sensitized solar cell (DSSC) that is based on the host-guest encapsulation of 5-[4-diphenylamino)phenyl]thiophene-2-cyanoacrylic acid (L1) inside β-cyclodextrin hosts has been tested. The formation of the complex in the solid state and when adsorbed on TiO(2) was characterized using steady and picosecond time-resolved emission techniques, as well as time dependent DFT calculations. The molecular-level insulation has led to a small enhancement in the energy-conversion performance of the fabricated DSSC with the best results being an increase in the open circuit voltage (Voc) from 0.
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