Publications by authors named "Hmayak B Sargsyan"
Article Synopsis
- The synthesis of tomato pinworm sex pheromones (E)- and (Z)-tridec-4-en-1-yl acetates was achieved using a C10+C3 strategy, with the iodinated dec-1-yn serving as a substrate.
- The key steps included the production of the C10-component through electrophilic iodination of dec-1-yne and the C3-component via a Grignard reaction on a bromopropoxy compound.
- Field tests conducted in 2024 confirmed the presence of Keiferia lycopersicella, the tomato pinworm, in several regions of Armenia, marking its first recorded finding in the country.
The present study focuses on the iodination of pyrazoles mediated by cadmium (II) acetate. The objects of research were compounds with pyrazole rings substituted by N-propargyl, C, N-alkyl groups. Depending on the molar ratios of the reagents effective ways of obtaining mono- and triiodo-substituted products with the participation of the propargylic fragment in DMSO were elucidated.
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