Publications by authors named "Hisao Nakagawa"
Article Synopsis
- The reaction between [2.2]paracyclophane and silver(I) heptafluorobutyrate led to the creation of four unique metal-organic complexes with 2D structures: three complexes contain guest molecules (pyrene, phenanthrene, fluorene), and one is an intercalation compound with benzene.
- These complexes feature silver heptafluorobutyrate forming infinite chains, while [2.2]paracyclophane connects them, resulting in different coordination modes depending on the complex.
- Notably, these complexes allow for reversible guest exchanges, meaning they can swap out the guest molecules for others while preserving their original structure.
Article Synopsis
- The reaction of [2.2]paracyclophane (pcp) with silver(I) acetate compounds resulted in the formation of three new intercalation polymers, each with unique guest molecules.
- Structural analysis via single crystal X-ray diffraction revealed that these polymers have two-dimensional layered frameworks characterized by cation-pi interactions and a novel coordination mode for pcp.
- The complexes were able to reversibly interchange between guest-eliminated and guest-reincorporated states, as demonstrated through various analytical methods including (1)H NMR and thermogravimetric analysis.
