Publications by authors named "Hirschfeld P"

In weakly coupled BCS superconductors, only electrons within a tiny energy window around the Fermi energy, E, form Cooper pairs. This may not be the case in strong coupling superconductors such as cuprates, FeSe, SrTiO or cold atom condensates where the pairing scale, E, becomes comparable or even larger than E. In cuprates, for example, a plausible candidate for the pseudogap state at low doping is a fluctuating pair density wave, but no microscopic model has yet been found which supports such a state.

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Visualizing atomic-orbital degrees of freedom is a frontier challenge in scanned microscopy. Some types of orbital order are virtually imperceptible to normal scattering techniques because they do not reduce the overall crystal lattice symmetry. A good example is d/d (π,π) orbital order in tetragonal lattices.

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High-pressure electrical resistivity measurements reveal that the mechanical deformation of ultra-hard WB during compression induces superconductivity above 50 GPa with a maximum superconducting critical temperature, Tof 17 K at 91 GPa. Upon further compression up to 187 GPa, the Tgradually decreases. Theoretical calculations show that electron-phonon mediated superconductivity originates from the formation of metastable stacking faults and twin boundaries that exhibit a local structure resembling MgB (hP3, space group 191, prototype AlB).

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For multiband superconductors, the orbital multiplicity yields orbital differentiation in normal-state properties and can lead to orbital-selective spin-fluctuation Cooper pairing. The orbital-selective phenomenon has become increasingly pivotal in clarifying the pairing "enigma", particularly for multiband high-temperature superconductors. Meanwhile, in one-unit-cell (1-UC) FeSe/SrTiO, since the standard electron-hole Fermi pocket nesting scenario is inapplicable, the actual pairing mechanism is subject to intense debate.

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Superconductivity is a remarkably widespread phenomenon that is observed in most metals cooled to very low temperatures. The ubiquity of such conventional superconductors, and the wide range of associated critical temperatures, is readily understood in terms of the well-known Bardeen-Cooper-Schrieffer theory. Occasionally, however, unconventional superconductors are found, such as the iron-based materials, which extend and defy this understanding in unexpected ways.

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An unidentified quantum fluid designated the pseudogap (PG) phase is produced by electron-density depletion in the CuO antiferromagnetic insulator. Current theories suggest that the PG phase may be a pair density wave (PDW) state characterized by a spatially modulating density of electron pairs. Such a state should exhibit a periodically modulating energy gap [Formula: see text] in real-space, and a characteristic quasiparticle scattering interference (QPI) signature [Formula: see text] in wavevector space.

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Designing materials with advanced functionalities is the main focus of contemporary solid-state physics and chemistry. Research efforts worldwide are funneled into a few high-end goals, one of the oldest, and most fascinating of which is the search for an ambient temperature superconductor (A-SC). The reason is clear: superconductivity at ambient conditions implies being able to handle, measure and access a single, coherent, macroscopic quantum mechanical state without the limitations associated with cryogenics and pressurization.

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A15 NbSi is, until now, the only 'high' temperature superconductor produced at high pressure (∼110 GPa) that has been successfully brought back to room pressure conditions in a metastable condition. Based on the current great interest in trying to create metastable-at-room-pressure high temperature superconductors produced at high pressure, we have restudied explosively compressed A15 NbSi and its production from tetragonal NbSi. First, diamond anvil cell pressure measurements up to 88 GPa were performed on explosively compressed A15 NbSi material to traceas a function of pressure.

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The defining characteristic of hole-doped cuprates is -wave high temperature superconductivity. However, intense theoretical interest is now focused on whether a pair density wave state (PDW) could coexist with cuprate superconductivity [D. F.

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Bogoliubov Fermi surfaces are contours of zero-energy excitations that are protected in the superconducting state. Here we show that multiband superconductors with dominant spin singlet, intraband pairing of spin-1/2 electrons can undergo a transition to a state with Bogoliubov Fermi surfaces if spin-orbit coupling, interband pairing and time reversal symmetry breaking are also present. These latter effects may be small, but drive the transition to the topological state for appropriate nodal structure of the intra-band pair.

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Recent nuclear magnetic resonance studies [A. Pustogow et al., Nature 574, 72 (2019)] have challenged the prevalent chiral triplet pairing scenario proposed for Sr_{2}RuO_{4}.

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The emergence in recent years of DNA editing technologies-Zinc finger nucleases (ZFNs), transcription activator-like effector (TALE) guided nucleases (TALENs), clustered regularly interspaced short palindromic repeats (CRISPR)/Cas family enzymes, and Base-Editors-have greatly increased our ability to generate hundreds of edited cells carrying an array of alleles, including single-nucleotide substitutions. However, the infrequency of homology-dependent repair (HDR) in generating these substitutions in general requires the screening of large numbers of edited cells to isolate the sequence change of interest. Here we present a high-throughput method for the amplification and barcoding of edited loci in a 96-well plate format.

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Article Synopsis
  • Superconductivity in FeSe arises from a nematic phase that disrupts the four-fold rotational symmetry of the iron plane, potentially due to various magnetic and orbital influences.
  • Inelastic neutron scattering reveals strong spin excitations at specific wave vectors in the normal state, showing a change in anisotropy at different energy levels.
  • The study underscores the significant electronic anisotropy in FeSe's nematic phase and suggests that spin fluctuations contribute to a highly anisotropic superconducting gap.
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Article Synopsis
  • Strong electronic correlations play a crucial role in copper-based high-temperature superconductors, derived from their Mott insulator parent phase, while iron-based superconductors have a different parent phase that isn't correlated.
  • Iron has five active d orbitals, unlike copper's single one, potentially leading to a Hund's metal state where the alignment of spins creates strong orbital-specific correlations.
  • Research on FeSe shows significant orbital-selective differences in quasiparticle spectral weights across various bands, indicating that these strong correlations are key to understanding the superconductivity mechanism in iron-based materials.
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We propose a mechanism whereby disorder can enhance the transition temperature T_{c} of an unconventional superconductor with pairing driven by exchange of spin fluctuations. The theory is based on a self-consistent real space treatment of pairing in the disordered one-band Hubbard model. It has been demonstrated before that impurities can enhance pairing by softening the spin fluctuations locally; here, we consider the competing effect of pair breaking by the screened Coulomb potential also present.

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The interplay between superconductivity and charge-density wave (CDW) in 2H-NbSe is not fully understood despite decades of study. Artificially introduced disorder can tip the delicate balance between two competing long-range orders, and reveal the underlying interactions that give rise to them. Here we introduce disorder by electron irradiation and measure in-plane resistivity, Hall resistivity, X-ray scattering, and London penetration depth.

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G-protein-coupled receptors (GPCRs) form the largest receptor family, relay environmental stimuli to changes in cell behavior and represent prime drug targets. Many GPCRs are classified as orphan receptors because of the limited knowledge on their ligands and coupling to cellular signaling machineries. Here, we engineer a library of 63 chimeric receptors that contain the signaling domains of human orphan and understudied GPCRs functionally linked to the light-sensing domain of rhodopsin.

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The superconductor iron selenide (FeSe) is of intense interest owing to its unusual nonmagnetic nematic state and potential for high-temperature superconductivity. But its Cooper pairing mechanism has not been determined. We used Bogoliubov quasiparticle interference imaging to determine the Fermi surface geometry of the electronic bands surrounding the Γ = (0, 0) and = (π/, 0) points of FeSe and to measure the corresponding superconducting energy gaps.

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In unconventional superconductors, understanding the form of the pairing interaction is the primary goal. In this regard, Raman spectroscopy is a very useful tool, as it identifies the ground state and also the subleading pairing channels by probing collective modes. Here, we propose a general theory for a multiband Raman response and identify new features in the spectrum that can provide a robust test for a pairing theory.

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At ambient pressure, BiTeI exhibits a giant Rashba splitting of the bulk electronic bands. At low pressures, BiTeI undergoes a transition from trivial insulator to topological insulator. At still higher pressures, two structural transitions are known to occur.

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The mechanism of unconventional superconductivity in iron-based superconductors (IBSs) is one of the most intriguing questions in current materials research. Among non-oxide IBSs, (Ba K )FeAs has been intensively studied because of its high superconducting transition temperature and fascinating evolution of the superconducting gap structure from being fully isotropic at optimal doping ( ≈ 0.4) to becoming nodal at > 0.

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We investigate superconductivity in a two-band system with an electronlike and a holelike band, where one of the bands is away from the Fermi level (or "incipient"). We argue that the incipient band contributes significantly to spin-fluctuation pairing in the strong coupling limit where the system is close to a magnetic instability and can lead to a large T_{c}. In this case, T_{c} is limited by a competition between the frequency range of the coupling (set by an isolated paramagnon) and the coupling strength itself, such that a domelike T_{c} dependence on the incipient band position is obtained.

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We provide a band structure with low-energy properties consistent with recent photoemission and quantum oscillation measurements on FeSe, assuming mean-field-like site- and/or bond-centered ferro-orbital ordering at the structural transition. We show how the resulting model provides a consistent explanation of the temperature dependence of the measured Knight shift and the spin-relaxation rate. Furthermore, the superconducting gap structure obtained from spin-fluctuation theory exhibits nodes on the electron pockets, consistent with the V-shaped density of states obtained by tunneling spectroscopy on this material, and the temperature dependence of the London penetration depth.

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