Ultimate resolution in scanning transmission electron microscopy (STEM) with state-of-the-art aberration correctors requires careful tuning of the experimental parameters. The optimum aperture semi-angle depends on the chosen high tension, the chromatic aberration and the energy width of the source as well as on potentially limiting intrinsic residual aberrations. In this paper we derive simple expressions and criteria for choosing the aperture semi-angle and for counterbalancing the intrinsic sixth-order three-lobe aberration of two-hexapole aberration correctors by means of the fourth-order three-lobe aberration.
View Article and Find Full Text PDFThe chemical synthesis of monoatomic metallic copper is unfavorable and requires inert or reductive conditions and the use of toxic reagents. Here, we report the environmental extraction and conversion of CuSO ions into single-atom zero-valent copper (Cu) by a copper-resistant bacterium isolated from a copper mine in Brazil. Furthermore, the biosynthetic mechanism of Cu production is proposed via proteomics analysis.
View Article and Find Full Text PDFThe modification of galactose with α1,2-fucose is involved in symbiosis with intestinal bacteria and elimination of pathogenic bacteria. It is postulated that α1,2-fucosylated mucin secreted from goblet cells is involved in defending an organism against infections, but the detailed molecular mechanisms are yet to be elucidated. It was previously reported that Paneth cells of the small intestine were positive for UEA-1 lectin staining.
View Article and Find Full Text PDFIonic liquids show characteristic properties derived from them being composed of only molecular ions, and have recently been used as solvents for chemical reactions and as electrolytes for electrochemical devices. The liquid structures, , ionic distributions, form when solutes are dissolved in ionic liquids and fundamentally affect the reactions and transfer efficiency in such solutions. In this study, we directly observe the liquid structure in a solution of the long-chain ionic liquid 1-octyl-3-methylimidazolium bromide (Cmim Br) and barium stearate (Ba(CHCOO)) using the annular dark-field method of scanning transmission electron microscopy (ADF-STEM).
View Article and Find Full Text PDFEstimating the Jacobian matrix of a nonlinear dynamical system through observed time-series data is one of the important steps in predicting future states of the time series. The Jacobian matrix is estimated using local information about divergences of nearby trajectories. Although the basic algorithm for estimating the Jacobian matrix generally works well, it often fails for short or noisy data series.
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