Publications by authors named "Hiroki Akasaka"

Hydrogenated amorphous carbon (-C:H) films have optical and electrical properties that vary widely depending on deposition conditions; however, the electrical conduction mechanism, which is dependent on the film structure, has not yet been fully revealed. To understand the relationship between the film structure and electrical conduction mechanism, three types of C:H films were prepared and their film structures and electrical properties were evaluated. The /( + ) ratios were measured by a near-edge X-ray absorption fine structure technique.

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Diamond-like carbon (DLC) films have attracted considerable interest for application as protective films in diverse industrial parts. This is attributed to their desirable characteristics, such as high hardness, low coefficient of friction, gas-barrier properties, and corrosion resistance. Antiseizure properties, in addition to wear resistance, are required during the die molding of polymer and polymer-matrix composite parts.

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The effect of soft X-ray irradiation on hydrogenated silicon-containing diamond-like carbon (Si-DLC) films intended for outer space applications was investigated by using synchrotron radiation (SR). We found that the reduction in film thickness was about 60 nm after 1600 mA·h SR exposure, whereas there was little change in their elemental composition. The reduction in volume was attributable to photoetching caused by SR, unlike the desorption of hydrogen in the case of exposure of hydrogenated DLC (H-DLC) film to soft X-rays.

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Amorphous boron carbon nitride (a-BCN) films exhibit excellent properties such as high hardness and high wear resistance. However, the correlation between the film structure and its mechanical properties is not fully understood. In this study, a-BCN films were prepared by an arc-sputtering hybrid process under various coating conditions, and the correlations between the film's structure and mechanical properties were clarified.

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Diamond-like carbon (DLC) films have been extensively applied in industries owing to their excellent characteristics such as high hardness. In particular, there is a growing demand for their use as protective films for mechanical parts owing to their excellent wear resistance and low friction coefficient. DLC films have been deposited by various methods and many deviate from the DLC regions present in the ternary diagrams proposed for sp covalent carbon, sp covalent carbon, and hydrogen.

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An amendment to this paper has been published and can be accessed via a link at the top of the paper.

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We have successfully conceived and demonstrated a simple, scalable process for improving the fracture energy of epoxy resins. The process is based on the combined application of high pressures (in the order of GPa) and shear rates (in the order of 10 m) in the pre-cured polymer, obtaining mechanical forces sufficiently high to increase the reactivity of the monomers due to the scission of the epoxy groups. To achieve these high values of pressure and shear rate, we take advantage of the elastohydrodynamic phenomena occurring at lubricated higher kinematic pairs as, for example, the rolling element - track pair in ball bearings.

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Diamond-like carbon (DLC) material is used in blood contacting devices as the surface coating material because of the antithrombogenicity behavior which helps to inhibit platelet adhesion and activation. In this study, DLC films were doped with boron during pulsed plasma chemical vapor deposition (CVD) to improve the blood compatibility. The ratio of boron to carbon (B/C) was varied from 0 to 0.

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Article Synopsis
  • This study examines the thermal stability, oxidation, and wear resistance of nanoporous -BC:H films compared to traditional diamond-like carbon (DLC) films.
  • The -BC:H films demonstrated superior thermal stability, remaining intact after heating to 500 °C, while the DLC films failed under the same conditions.
  • Despite having lower hardness, -BC:H films exhibited excellent lubrication properties, reducing friction and wear when tested, suggesting they could be a better option for challenging operational environments.
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