Mode Conversion Behavior of Guided Wave in a Pipe Inspection System Based on a Long Waveguide.

To make clear the mode conversion behavior of S0-mode lamb wave and SH0-plate wave converting to the longitudinal mode guided wave and torsional mode guided wave in a pipe, respectively, the experiments were performed based on a previous built pipe inspection system. The pipe was wound with an L-shaped plate or a T-shaped plate as the waveguide, and the S0-wave and SH0-wave were excited separately in the waveguide. To carry out the objective, a meander-line coil electromagnetic acoustic transducer (EMAT) for S0-wave and a periodic permanent magnet (PPM) EMAT for SH0-wave were developed and optimized.

Photoreaction of rac-leucine in ice by circularly polarized synchrotron radiation: temperature-induced mechanism switching from Norrish Type II to deamination.

The delivery of extraterrestrial organics to primitive Earth is considered to have triggered the origin and subsequent evolution of life. Indeed, enantiomerically enriched amino acids of nonterrestrial origin have been found in carbonaceous meteorites, and enantioselective photodecomposition by circularly polarized light (CPL) in outer space has been proposed to have played some role in the initial enantiomeric bias. To experimentally examine this possibility and elucidate the photoreaction mechanisms, we have studied the photolysis of racemic leucine (rac-Leu) in acidic and neutral ice/water media at 21-298 K with left- and right-CPL in an attempt to detect enantiomerically enriched D- and L-Leu, respectively.

Simultaneous measurement of the phase and group velocities of Lamb waves in a laser-generation based imaging method.

This paper describes a novel approach to the simultaneous measurement of the phase and group velocities of Lamb waves based on images of their propagation. The laser-generation based imaging method was first introduced to obtain images of Lamb wave propagation. The time series of snapshot images is used to make a position-time diagram, and the velocities can be estimated based on the slopes of the position curves.

Propagation phenomena of wideband guided waves in a bended pipe.

Ultrasonic guided waves in pipes have been anticipated as a rapid screening technique for pipe inspection because of their long-range propagation due to low energy leakage. In this paper, the propagation phenomena of guided waves in a bended pipe were investigated using a wideband laser ultrasonic system. The laser ultrasonic system, together with wavelet transformation, is a powerful tool for observing the dispersive phenomena intrinsic to guided waves.

Enantioselective synthesis of near enantiopure compound by asymmetric autocatalysis triggered by asymmetric photolysis with circularly polarized light.

Right- and left-handed circularly polarized light (CPL) has been proposed as one of the origins of homochirality of biomolecules. However, the enantiomeric excess induced by CPL has been only very low (<2% ee). We found the unprecedented example of asymmetric autocatalysis triggered directly by a chiral physical factor, that is, right- and left-handed CPL, leading to a near enantiopure compound.

Absolute asymmetric photoreactions of aliphatic amino acids by circularly polarized synchrotron radiation: critically pH-dependent photobehavior.

The absolute asymmetric photoreaction (AAP) of racemic aliphatic amino acids, such as alanine (Ala) and leucine (Leu), by left- and right-handed circularly polarized light (l- and r-CPL) irradiation was investigated in aqueous solutions at various pHs, by using the Onuki-type polarizing undulator installed in an electron storage ring. The magnitude of the optical purity (op) generated and the enantiomer-enriching mechanism operative in the AAP were found to be entirely dependent on the ionic state (and thus pH) of the amino/carboxylic acid moieties. At pH 1, the op of Ala and Leu determined by circular dichroism (CD) spectral measurement gradually developed with CPL irradiation, according to Kagan's equation.