Additive manufacturing of LiNiMnCoO battery electrode material via vat photopolymerization precursor approach.

Additive manufacturing, also called 3D printing, has the potential to enable the development of flexible, wearable and customizable batteries of any shape, maximizing energy storage while also reducing dead-weight and volume. In this work, for the first time, three-dimensional complex electrode structures of high-energy density LiNiMnCoO (NMC 111) material are developed by means of a vat photopolymerization (VPP) process combined with an innovative precursor approach. This innovative approach involves the solubilization of metal precursor salts into a UV-photopolymerizable resin, so that detrimental light scattering and increased viscosity are minimized, followed by the in-situ synthesis of NMC 111 during thermal post-processing of the printed item.

Lewis Acid Site Assisted Bifunctional Activity of Tin Doped Gallium Oxide and Its Application in Rechargeable Zn-Air Batteries.

The enhanced safety, superior energy, and power density of rechargeable metal-air batteries make them ideal energy storage systems for application in energy grids and electric vehicles. However, the absence of a cost-effective and stable bifunctional catalyst that can replace expensive platinum (Pt)-based catalyst to promote oxygen reduction reaction (ORR) and oxygen evolution reaction (OER) at the air cathode hinders their broader adaptation. Here, it is demonstrated that Tin (Sn) doped β-gallium oxide (β-Ga O ) in the bulk form can efficiently catalyze ORR and OER and, hence, be applied as the cathode in Zn-air batteries.

Tomato Fruit Nutritional Quality Is Altered by the Foliar Application of Various Metal Oxide Nanomaterials.

Carbohydrates and phytonutrients play important roles in tomato fruit's nutritional quality. In the current study, FeO, MnFeO, ZnFeO, ZnMnFeO, MnO, and ZnO nanomaterials (NMs) were synthesized, characterized, and applied at 250 mg/L to tomato plants via foliar application to investigate their effects on the nutritional quality of tomato fruits. The plant growth cycle was conducted for a total of 135 days in a greenhouse and the tomato fruits were harvested as they ripened.

A double-edged effect of manganese-doped graphene quantum dots on salt-stressed Capsicum annuum L.

The objective of the current study is to evaluate both the positive and negative effects of manganese-doped graphene quantum dots (GQD-Mn) on Capsicum annuum L. grown under salt stress. GQD-Mn was synthesized, characterized, and foliar-applied (250 mg/L, 120 mg/L, 60 mg/L) to C.

Copper oxide (CuO) nanoparticles affect yield, nutritional quality, and auxin associated gene expression in weedy and cultivated rice (Oryza sativa L.) grains.

Weedy rice grows competitively with cultivated rice and significantly diminishes rice grain production worldwide. The different effects of Cu-based nanomaterials on the production of weedy and cultivated rice, especially the grain qualities are not known. Grains were collected from weedy and cultivated rice grown for four months in field soil amended with nanoscale CuO (nCuO), bulk CuO (bCuO), and copper sulfate (CuSO) at 0, 75, 150, 300, and 600 mg Cu/kg soil.

Soil-aged nano titanium dioxide effects on full-grown carrot: Dose and surface-coating dependent improvements on growth and nutrient quality.

Rutile titanium dioxide nanoparticles (nTiO) were weathered in field soil at 0, 100, 200, and 400 mg Ti/kg soil for four months. Two types of nTiO with different surface coatings (hydrophilic and hydrophobic), uncoated nTiO (pristine), and the untreated control were included. Thereafter, carrot seeds (Daucus carota L.

Soil-Weathered CuO Nanoparticles Compromise Foliar Health and Pigment Production in Spinach ().

In this study, spinach plants exposed to fresh/unweathered (UW) or weathered (W) copper compounds in soil were analyzed for growth and nutritional composition. Plants were exposed for 45 days to freshly prepared or soil-aged (35 days) nanoparticulate CuO (nCuO), bulk-scale CuO (bCuO), or CuSO at 0 (control), 400, 400, and 40 mg/kg of soil, respectively. Foliar health, gas exchange, pigment content (chlorophyll and carotenoid), catalase and ascorbate peroxidase enzymes, gene expression, and Cu bioaccumulation were evaluated along with SEM imagery for select samples.

Effects of different surface-coated nTiO on full-grown carrot plants: Impacts on root splitting, essential elements, and Ti uptake.

The production and environmental release of surface-modified titanium dioxide nanoparticles (nTiO) have increased. Hence, crops may be directly exposed to the nTiO in soil. In this study, we grew carrots in soils amended with pristine, hydrophilic and hydrophobic surface-coated nTiO at 100, 200, and 400 mg kg until full-plant maturity.

Antioxidant and defense genetic expressions in corn at early-developmental stage are differentially modulated by copper form exposure (nano, bulk, ionic): Nutrient and physiological effects.

In the present study, Zea mays seedlings grown under nano Cu(OH) (nCu), bulk Cu(OH) (bCu), and ionic CuSO (iCu) compound exposure were harvested after six days. The nutritional profile was determined to be significantly disrupted in the roots by 1000 ppm bCu treatment, resulting in a 58.7% reduction in potassium compared to the control.

Copper nanowires as nanofertilizers for alfalfa plants: Understanding nano-bio systems interactions from microbial genomics, plant molecular responses and spectroscopic studies.

The recent application of nano copper (Cu) compounds in the agrosystem has shown potential to improve the physiological performance and agronomical parameters of crops. We grew alfalfa (Medicago sativa) in potting mix amended with bulk, nano, and ionic Cu compounds at 80 and 280 mg Cu/kg; then, we evaluated plant performance at physiological and molecular levels. Plants treated with bulk/nano Cu presented better agronomical responses.

Effect of copper oxide nanoparticles on two varieties of sweetpotato plants.

Little information is available on the interaction of CuO nanoparticles (nCuO) with tuberous roots. In this study, Beauregard-14 (B-14, low lignin) and Covington (COV, high lignin) sweetpotato varieties were cultivated until maturity in soil amended with nCuO, bulk copper oxide (bCuO) and CuCl2 at 25-125 mg/kg. The Cu treatments had no significant influence on chlorophyll content.

Bok choy (Brassica rapa) grown in copper oxide nanoparticles-amended soils exhibits toxicity in a phenotype-dependent manner: Translocation, biodistribution and nutritional disturbance.

The comparative toxicity of nano/bulk cupric oxide (CuO) and ionic copper (Cu) in Rosie and Green bok choy (Brassica rapa) varieties, with higher and lower anthocyanin contents, respectively, was investigated. Both phenotypes were cultivated for 70 days in natural soil amended with nano CuO (nCuO), bulk CuO (bCuO), and Cu chloride (CuCl) at 75, 150, 300, and 600 mg Cu/kg soil. Essential elements in tissues, agronomical parameters, chlorophyll content, and Cu distribution in leaf were determined.

Improvement of nutrient elements and allicin content in green onion (Allium fistulosum) plants exposed to CuO nanoparticles.

With the exponential growth of nanomaterial production in the last years, nano copper (Cu)-based compounds are gaining more consideration in agriculture since they can work as pesticides or fertilizers. Chinese scallions (Allium fistulosum), which are characterized by their high content of the antioxidant allicin, were the chosen plants for this study. Spectroscopic and microscopic techniques were used to evaluate the nutrient element, allicin content, and enzyme antioxidant properties of scallion plants.

Insights into the Biogeochemical Cycling of Cobalt: Precipitation and Transformation of Cobalt Sulfide Nanoparticles under Low-Temperature Aqueous Conditions.

Cobalt sulfide precipitates, key phases in the natural biogeochemistry of cobalt and in relevant remediation and resource recovery processes, are poorly defined under low-temperature aqueous conditions. Here, we systematically studied Co (Fe) sulfides precipitated and aged in environmentally relevant solutions, defined by different combinations of pH, initial cobalt to iron ratios ([Co]/[Fe]), with/without S, and the presence/absence of sulfate-reducing bacteria. The initial abiogenic precipitates were composed exclusively of amorphous Co sulfide nanoparticles (CoS·HO) that were stable in anoxic solution for 2 months, with estimated log values 1-5 orders of magnitude higher than that previously reported for Co sulfides.

Long-term assessment of nano and bulk copper compound exposure in sugarcane (Saccharum officinarum).

As interest in the use of copper-based nanomaterials in agriculture continue to increase, research into their exposure effects must expand from short-term, high exposure studies to long-term studies at realistic concentrations. Long-term studies can better elucidate the implications of copper nanomaterial exposure by allowing plants to mature and adapt to higher copper concentrations. In this study, sugarcane plants were grown to maturity in large nursery pots using soils amended with one of the following treatments: Kocide 3000 (Cu(OH)), a nano-sized CuO (nCuO), a bulk-sized CuO (bCuO), copper metal nanoparticles (Cu NP), or CuCl at 20, 40, and 60 mg kg.

Nutritional Status of Tomato () Fruit Grown in -Infested Soil: Impact of Cerium Oxide Nanoparticles.

In this study, the impact of cerium oxide nanoparticles on the nutritional value of tomato () fruit grown in soil infested with f. sp. was investigated in a greenhouse pot study.

Sustainable synthesis and remarkable adsorption capacity of MOF/graphene oxide and MOF/CNT based hybrid nanocomposites for the removal of Bisphenol A from water.

A series of novel absorbents based on Cu-BDC MOFs decorated over graphene oxide (GrO) and carbon nanotubes (CNTs) hybrid nanocomposites, namely Cu-BDC@GrO and Cu-BDC@CNT, are synthesized via a facile and one-pot green solvothermal method for water remediation. The nanocomposites were characterized by XRD, TEM, SEM, EDS, Raman, FTIR, TGA, XPS, Zetasizer and ICP-OES instruments. XRD results confirmed the high crystalline structure of the synthesized hybrid nanocomposites.

Uptake, transport, and effects of nano-copper exposure in zucchini (Cucurbita pepo).

Numerous studies on short term effects of copper-based nanomaterials on plants have been published, however investigations with plants grown in a complex soil medium are lacking. In this study Grey Zucchini (Cucurbita pepo) was grown in an environmental growth chamber using a 1:1 (v/v) potting mix native soil mixture amended with Kocide 3000, nCuO, bCuO, or Cu NPs. After 3 weeks Cu concentrations in the root, stem, and leaves of treated plants were significantly higher than control plants.

A comparative metagenomic and spectroscopic analysis of soils from an international point of entry between the US and Mexico.

The Paso del Norte region is characterized by its dynamic industries and active agriculture. Throughout the years, urban and agricultural soils from this region have been exposed to xenobiotics, heavy metals, and excess of hydrocarbons. In this study, samples of urban [domestic workshops (DW)] and agricultural-intended (AI) soils from different sites of Ciudad Juárez, Mexico were evaluated for their fertility, element content, and microbial diversity.

Toxicity of copper hydroxide nanoparticles, bulk copper hydroxide, and ionic copper to alfalfa plants: A spectroscopic and gene expression study.

Bulk Cu compounds such as Cu(OH) are extensively used as pesticides in agriculture. Recent investigations suggest that Cu-based nanomaterials can replace bulk materials reducing the environmental impacts of Cu. In this study, stress responses of alfalfa (Medicago sativa L.

ZnO nanoparticles increase photosynthetic pigments and decrease lipid peroxidation in soil grown cilantro (Coriandrum sativum).

The growth of the nanotechnology industry has raised concerns about its environmental impacts. In particular, the effect on terrestrial plants, which are the primary producers of the global food chain, is widely debated. In this study, cilantro plants (Coriandrum sativum) were cultivated for 35 days in soil amended with ZnO nanoparticles (N ZnO), bulk ZnO (B ZnO) and ZnCl (ionic/I Zn) at 0-400 mg/kg.

Biochemical and physiological effects of copper compounds/nanoparticles on sugarcane (Saccharum officinarum).

The widespread use of copper based nanomaterials has been accompanied by an increasing interest in understanding their potential risks. It is essential to understand the effects of these nanoparticles on edible crops by performing long-term experiments at relevant exposure concentrations. Sugarcane is the source of 70% of the world's sugar supply and the widespread use of refined sugar and the consumption of raw sugarcane can provide a route for nanoparticles to enter the food supply.

Two-Photon Microscopy and Spectroscopy Studies to Determine the Mechanism of Copper Oxide Nanoparticle Uptake by Sweetpotato Roots during Postharvest Treatment.

The interaction of engineered nanoparticles with plant tissues is still not well understood. There is a lack of information about the effects of curing (postharvest treatment) and lignin content on copper uptake by sweetpotato roots exposed to copper-based nanopesticides. In this study, Beauregard-14 (lower lignin) and Covington (higher lignin) varieties were exposed to CuO nanoparticles (nCuO), bulk CuO (bCuO), and CuCl at 0, 25, 75, and 125 mg/L.

Finding the conditions for the beneficial use of ZnO nanoparticles towards plants-A review.

Zinc oxide nanoparticles (ZnO NPs) have a wide range of applications in cosmetics, electrical, and optical industries. The wide range of applications of ZnO NPs, especially in personal care products, suggest they can reach major environmental matrices causing unforeseen effects. Recent literature has shown conflicting findings regarding the beneficial or detrimental effects of ZnO NPs towards terrestrial biota.