Interfacial Dynamics and Its Relations with ?Negative? Surface Viscosities Measured at Water?Air Interfaces Covered with a Cationic Surfactant.

We studied the dynamics of a cationic surfactant monolayer, Gemini 12-2-12, at the air?water interface for surfactant aqueous solutions at concentrations below the critical micelle concentration. We present surface rheology experiments performed in a Langmuir trough by the oscillatory barrier technique. From these, we found negative surface viscosities at certain frequencies.