Publications by authors named "Herman Smit"

The ozonesonde is a small balloon-borne instrument that is attached to a standard radiosonde to measure profiles of ozone from the surface to 35 km with ~100-m vertical resolution. Ozonesonde data constitute a mainstay of satellite calibration and are used for climatologies and analysis of trends, especially in the lower stratosphere where satellites are most uncertain. The electrochemical-concentration cell (ECC) ozonesonde has been deployed at ~100 stations worldwide since the 1960s, with changes over time in manufacture and procedures, including details of the cell chemical solution and data processing.

View Article and Find Full Text PDF

Reprocessed ozonesonde data from eight SHADOZ (Southern Hemisphere ADditional OZonesondes) sites have been used to derive the first analysis of uncertainty estimates for both profile and total column ozone (TCO). The ozone uncertainty is a composite of the uncertainties of the individual terms in the ozone partial pressure (P) equation, those being the ozone sensor current, background current, internal pump temperature, pump efficiency factors, conversion efficiency, and flow-rate. Overall, P uncertainties (ΔP) are within 15% and peak around the tropopause (15±3km) where ozone is a minimum and ΔP approaches the measured signal.

View Article and Find Full Text PDF

IAGOS (In-service Aircraft for a Global Observing System) performs long-term routine in situ observations of atmospheric chemical composition (O, CO, NO, NO, CO, CH), water vapour, aerosols, clouds, and temperature on a global scale by operating compact instruments on board of passenger aircraft. The unique characteristics of the IAGOS data set originate from the global scale sampling on air traffic routes with similar instrumentation such that the observations are truly comparable and well suited for atmospheric research on a statistical basis. Here, we present the analysis of 15 months of simultaneous observations of relative humidity with respect to ice (RH) and ice crystal number concentration in cirrus (N) from July 2014 to October 2015.

View Article and Find Full Text PDF

Charge transport rate at open-circuit potential (V(oc)) is proposed as a new characterization method for dye-sensitized (DS) and other nanostructured solar cells. At V(oc), charge density is flat and measurable, which simplifies quantitative comparison of transport and charge density. Transport measured at V(oc) also allows meaningful comparison of charge transport rates between different treatments, temperatures, and types of cells.

View Article and Find Full Text PDF