Publications by authors named "Henri Spanjers"

Article Synopsis
  • This study focuses on extracting structural extracellular polymeric substances (SEPS) from waste activated sludge (WAS) to increase their yield, which is typically low.
  • Using an optimized heating-NaCO extraction process, a maximum yield of 209 mg g volatile solid was achieved under specific conditions like temperature and pH.
  • Proteomic analysis revealed that the proteins in SEPS are linked to nitrogen-fixing and organic matter-degrading microorganisms, which not only enhanced volatile fatty acid production but also improved the overall treatment of residual sludge.
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While air stripping combined with acid scrubbing remains a competitive technology for the removal and recovery of ammonia from wastewater streams, its use of strong acids is concerning. Organic acids offer promising alternatives to strong acids like sulphuric acid, but their application remains limited due to high cost. This study proposes an integration of air stripping and organic acid scrubbing with bipolar membrane electrodialysis (BPMED) to regenerate the organic acids.

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Treating protein-rich wastewater using cost-effective and simple-structured single-stage reactors presents several challenges. In this study, we applied an anaerobic sequencing batch reactor (AnSBR) to treat protein-rich wastewater from a slaughterhouse. We focused on identifying the key factors influencing the removal of chemical oxygen demand (COD) and the settling performance of the sludge.

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The presence of organic micro-pollutants (OMPs) in wastewater treatment effluents is becoming a major threat to the water safety for aquatic and human health. Photo-electrocatalytic based advanced oxidation process (AOP) is one of the emerging and effective techniques to degrade OMPs through oxidative mechanism. This study investigated the application of heterojunction based BiVO/BiOI photoanode for acetaminophen (40 μg L) removal in demineralized water.

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Bitumen fume condensate (BFC) is a hazardous wastewater generated at asphalt reclamation and production sites. BFC contains a wide variety of potentially toxic organic pollutants that negatively affect anaerobic processes. In this study, we chemically characterized BFC produced at an industrial site and evaluated its degradation under anaerobic conditions.

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Protein-rich agro-industrial waste streams are high in organic load and represent a major environmental problem. Anaerobic digestion is an established technology to treat these streams; however, retardation of protein degradation is frequently observed when carbohydrates are present. This study investigated the mechanism of the retardation by manipulating the carbon source fed to a complex anaerobic microbiota and linking the reactor performance to the variation of the microbial community.

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Flux enhancers (FEs) have been successfully applied for fouling mitigation in membrane bioreactors. However, more research is needed to compare and optimise different dosing strategies to improve the filtration performance, while minimising the use of FEs and preventing overdosing. Therefore, the goal of this research is to develop an optimised control strategy for FE dosing into an AnMBR by developing a comprehensive integrated mathematical model.

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Total ammoniacal nitrogen (TAN) is considered to be a pollutant, but is also a versatile resource. This review presents an overview of the TAN recovery potentials from nitrogen (N)-loaded residual streams by discussing the sources, recovery technologies and potential applications. The first section of the review addresses the fate of TAN after its production.

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Phenolic industrial wastewater, such as those from coal gasification, are considered a challenge for conventional anaerobic wastewater treatment systems because of its extreme characteristics such as presence of recalcitrant compounds, high toxicity, and salinity. However, anaerobic membrane bioreactors (AnMBRs) are considered of potential interest since they retain all micro-organism that are required for conversion of the complex organics. In this study, the degradation of phenol as main carbon and energy source (CES) in AnMBRs at high salinity (8.

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Closing water loops in chemical industries result in hot and highly saline residual streams, often characterized by high strength and the presence of refractory or toxic compounds. These streams are attractive for anaerobic technologies, provided the chemical compounds are biodegradable. However, under such harsh conditions, effective biomass immobilization is difficult, limiting the use of the commonly applied sludge bed reactors.

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Cationic polymers have proven to be suitable flux enhancers (FEs) in large-scale aerobic membrane bioreactors (MBRs), whereas in anaerobic membrane bioreactors (AnMBRs) research is scarce, and so far, only done at lab-scale. Results from MBRs cannot be directly translated to AnMBRs because the extent and nature of membrane fouling under anaerobic and aerobic conditions are different. Our research focused on the long-term effect of dosing the cationic polymer Adifloc KD451 to a pilot AnMBR, fed with source-separated domestic blackwater.

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Life cycle assessment (LCA) has proven to be a useful tool in assessing environmental technologies in a retrospective manner. To fully uncover the environmental improvement potential while advancing technologies under technical and environmental constraints, this study recommended approaching the LCA proactively to assess the progress of parameter optimization before determining critical parameters. To that end, the present work introduced a multimethod eight-step (MMES) analysis scheme, which included an integration of LCA with Plackett-Burman multifactorial design, central composite design, and multi-objective optimization.

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White rot fungi using P. sajor-caju and T. versicolor was examined to pretreat raw champost (lignin-rich) and oyster champost (cellulose-rich) for enhancement of fermentative volatile fatty acid (VFA) production.

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Ammonium (NH) can be recovered from water for fertiliser production or even energy production purposes. Because NH recovery is more effective at increased concentrations, electrodialysis (ED) can be used to concentrate NH from side streams, such as sludge reject water, and simultaneously achieve high NH removal efficiencies. However, the effect of osmosis and back-diffusion increases when the NH concentration gradient between the diluate and the concentrate stream increases, resulting in a limitation of the concentration factor and an increase in energy consumption for NH removal.

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To guarantee drinking water security, removal of bromate (BrO) has garnered plenty of attention in water treatment. In current study, we have developed a novel conjugated donor-acceptor (D-A) photocatalyst (4,4''-bis(diphenylamino)-[1,1':4',1''-terphenyl]-2',5'-dicarbaldehyde, BDTD) with supramolecule architecture assembling via intermolecular CH···O hydrogen bonds and CH···π interactions. Both diffuse reflectance spectrum (DRS) and density functional theoretical (DFT) calculations gave the bandgap of E = 2.

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The application of cationic polymers to enhance membrane fluxes in anaerobic membrane bioreactors has been proposed by several authors. However, literature shows contradictory results on the influence of those chemicals on the biological activity. In this research, we studied the effect of a cationic polymer on the production of methane from acetate by acetoclastic methanogens.

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Background: This study investigated the effect of organic loading rate (OLR) and NaCl concentration on biohydrogen production by preheated anaerobic sludge in a lab scale anaerobic sequencing batch reactor (ASBR) fed with glucose during long time operation.

Methods: During ASBR operation, the OLR was increased in steps from 0.5 to 5 g glucose/L.

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This study aimed to characterise the gas-liquid flow and mixing behaviour in a gas-mixed anaerobic digester by improving phase interaction modelling using Computational Fluid Dynamics (CFD). A 2D axisymmetric model validated with experimental data was set up using an Eulerian-Eulerian method. Uncertainty factors, including bubble size, phase interaction forces and liquid rheology were found to significantly influence the flow field.

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This study examined the temperature susceptibility of a continuous-flow lab-scale anaerobic membrane bioreactor (AnMBR) to temperature shifts from 35 °C to 55 °C and its bioconversion robustness treating synthetic phenolic wastewater at 16 gNaL. During the experiment, the mesophilic reactor was subjected to stepwise temperature increases by 5 °C. The phenol conversion rates of the AnMBR decreased from 3.

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Industrial wastewaters are becoming increasingly associated with extreme conditions such as the presence of refractory compounds and high salinity that adversely affect biomass retention or reduce biological activity. Hence, this study evaluated the impact of long-term salinity increase to 20 gNa.L on the bioconversion performance and microbial community composition in anaerobic membrane bioreactors treating phenolic wastewater.

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In this study, we tested a new approach to facilitate the application of white rot fungi (WRF) under non-sterile conditions, by introducing grain sorghum as carrier and sole carbon and nutrient source for WRF. To this end, Trametes versicolor was immobilized on sorghum, and its ability to remove humic acid (HA) from synthetic and real industrial wastewater was studied. HA removal was measured as colour reduction and also analysed via size exclusion chromatography (SEC).

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In this work, we investigated the effects of flocculation aid (FA) addition to an anaerobic dynamic membrane bioreactor (AnDMBR) (7 L, 35 °C) treating waste-activated sludge (WAS). The experiment consisted of three distinct periods. In period 1 (day 1-86), the reactor was operated as a conventional anaerobic digester with a solids retention time (SRT) and hydraulic retention time (HRT) of 24 days.

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Biomass requires trace metals (TM) for maintaining its growth and activity. This study aimed to determine the effect of TM supplementation and partitioning on the specific methanogenic activity (SMA), with a focus on cobalt and tungsten, during the start-up of two lab-scale Anaerobic Membrane Bioreactors (AnMBRs) treating saline phenolic wastewater. The TM partitioning revealed a strong accumulation of sodium in the biomass matrix and a wash-out of the majority of TM in the reactors, which led to an SMA decrease and a low COD removal of about 30%.

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This paper presents the results of fungal treatment of a real industrial wastewater (WW), providing insight into the main mechanisms involved and clarifying some ambiguities and uncertainties in the previous reports. In this regard, the mycoremediation potentials of four strains of white rot fungi (WRF): Phanerochaete chrysosporium, Trametes versicolor, Pleurotus ostreatus and Pleurotus pulmonarius were tested to remove humic acids (HA) from a real humic-rich industrial treated WW of a food-processing plant. The HA removal was assessed by color measurement and size-exclusion chromatography (SEC) analysis.

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The results in this study show that struvite was formed in the digester at pH 7.7 due to the magnesium naturally present and the released ammonia and phosphate, resulting in low phosphate concentration in the digester. Apparently the digester already provided proper conditions for struvite formation.

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