Acid rain and air pollution: 50 years of progress in environmental science and policy.

Because of its serious large-scale effects on ecosystems and its transboundary nature, acid rain received for a few decades at the end of the last century wide scientific and public interest, leading to coordinated policy actions in Europe and North America. Through these actions, in particular those under the UNECE Convention on Long-range Transboundary Air Pollution, air emissions were substantially reduced, and ecosystem impacts decreased. Widespread scientific research, long-term monitoring, and integrated assessment modelling formed the basis for the policy agreements.

Brown clouds over South Asia: biomass or fossil fuel combustion?

Carbonaceous aerosols cause strong atmospheric heating and large surface cooling that is as important to South Asian climate forcing as greenhouse gases, yet the aerosol sources are poorly understood. Emission inventory models suggest that biofuel burning accounts for 50 to 90% of emissions, whereas the elemental composition of ambient aerosols points to fossil fuel combustion. We used radiocarbon measurements of winter monsoon aerosols from western India and the Indian Ocean to determine that biomass combustion produced two-thirds of the bulk carbonaceous aerosols, as well as one-half and two-thirds of two black carbon subfractions, respectively.

Soil sensitivity to acidification in Asia: status and prospects.

Exceedance of steady-state critical loads for soil acidification is consistently found in southern China and parts of SE Asia, but there is no evidence of impacts outside of China. This study describes a methodology for calculating the time to effects for soils sensitive to acidic deposition in Asia under potential future sulfur (S), nitrogen (N), and calcium (Ca) emission scenarios. The calculations are matched to data availability in Asia to produce regional-scale maps that provide estimates of the time (y) it will take for soil base saturation to reach a critical limit of 20% in response to acidic inputs.

The global distribution of acidifying wet deposition.

The acid-base status of precipitation is a result of a balance between acidifying compounds--mainly oxides of sulfur and nitrogen--and alkaline compounds--mainly ammonia and alkaline material in windblown soil dust. We use current models of the global atmospheric distribution of such compounds to estimate the geographical distribution of pH in precipitation and of the rate of deposition of hydrogen ion or bicarbonate ion. The lowest pH values--mainly due to high concentration of sulfuric acid--occur in eastern parts of North America, Europe, and China.