Peroxymonosulfate assisted mechanochemical remediation of high concentration DDTs contaminated soil.

DDTs (DDT and its metabolites) contaminated sites urgently need to be treated efficiently and greenly. In this study, a horizontal planetary mechanochemical method with co-milling additives was developed aiming at efficiently degrading high-concentration DDTs in historical contaminated soil (∼7500 mg/kg). Peroxymonosulfate (PMS) was firstly used to the mechanochemical degradation of DDTs in historical contaminated soil, with a degradation efficiency of over 95% after 1 h of milling under the optimal milling conditions (C = 30:1, r = 500 rpm, R = 1:4).

Mechanochemical remediation of lindane-contaminated soils assisted by CaO: Performance, mechanism and overall assessment.

Soil contamination caused by persistent organic pollutants (POPs) has been a worldwide concern for decades. With lindane-contaminated soil as the target, a mechanochemical method assisted by CaO was comprehensively evaluated in terms of its remediation performance, degradation mechanism and overall assessment. The mechanochemical degradation performance of lindane in cinnamon soil or kaolin was determined under different additives, lindane concentrations and milling conditions.

Horizontal planetary mechanochemical method for rapid and efficient remediation of high-concentration lindane-contaminated soils in an alkaline environment.

Lindane is a persistent organic pollutant that has attracted worldwide attention because of its threat to human health and environmental security. A horizontal planetary mechanochemical method was developed for rapid and efficient degradation of lindane in soil in an alkaline environment. Under the condition of a very low reagent-to-soil ratio (R = 2%), ball-to-powder ratio (C = 6:1), rotation speed (r = 300 rpm) and high soil single treatment capacity (S = 60 g), the lindane in four typical soils (~ 100 mg/kg) can be degraded up to 96.