Evaluating the Generalization Ability of Super-Resolution Networks.

Performance and generalization ability are two important aspects to evaluate the deep learning models. However, research on the generalization ability of Super-Resolution (SR) networks is currently absent. Assessing the generalization ability of deep models not only helps us to understand their intrinsic mechanisms, but also allows us to quantitatively measure their applicability boundaries, which is important for unrestricted real-world applications.

Divergent Radical Cyclization and Hydroaminoalkylation of -Arylacrylamides Using Photoredox Catalysis.

The ability to selectively synthesize multiple products from the same sets of substrates is a highly appealing and challenging concept in synthetic chemistry. In this manuscript, we describe the visible-light photoredox intermolecular catalysis of -arylacrylamides that are α-C-H functionalized with aryl tertiary amines. The photocatalyst acts as a chemical switch to trigger two different reaction pathways and to obtain two different products from the same starting material.

Umpolung Reactivity of Imine Ester: Visible-Light Mediated Transfer Hydrogenation of α-Aryl Imino Esters by Phenylsilane and Water.

A visible-light mediated chemoselective transfer hydrogenation of α-aryl imino esters was demonstrated. The methodology allowed the efficient and practical preparation of α-amino acid esters. The mechanism of the reaction was probed by DFT calculations, and deuteration experiments indicated deuterium was introduced into amino acid esters efficiently (up to 99 % D ratio), enabling a feasible way to obtain deuterated amino acids using D O as a cheap deuterium source.