Phosphine-Catalyzed Chemoselective Reduction/Elimination/Wittig Sequence for Synthesis of Functionalized 3-Alkenyl Benzofurans.

An efficient protocol for the construction of functionalized 3-alkenyl benzofurans is demonstrated under metal-free conditions using catalytic amount of phosphine proceeding an intramolecular Wittig reaction. This one-pot reaction initiated by the phospha-Michael addition of phosphine to -acylated nitrostyrene, in which phosphine was in-situ-generated from the chemoselective reduction of phosphine oxide with PhSiH, would provide the phosphorus ylide to result in the aforementioned multifunctionalized benzofuran via -acylation/nitrous acid elimination/Wittig reaction.

Bibliometric review of visual computing in the construction industry.

In the construction area, visuals such as drawings, photos, videos, and 3D models, play a significant role in the design, build and maintenance of a facility, bringing efficiency to generate, transfer, and store information. Advanced visual computing techniques facilitate the understanding of design contents, work plans, and other types of information shared in the construction industry. Automatic visual data collection and analysis provide many possibilities to the construction industry and a large number of works have investigated how visual computing can improve construction management processes and other problems in the construction area.