Photoionization of propargyl and bromopropargyl radicals: a threshold photoelectron spectroscopic study.

In this Article, we present mass-selected threshold photoelectron spectra of propargyl as well as the 1- and 3-bromopropargyl radicals. The reactive intermediates were produced by flash pyrolysis of suitable precursors and ionized by VUV synchrotron radiation. The TPES of the propargyl radical was simulated using data from a recent high-level computational study.

Photoionization of epichlorohydrin enantiomers and clusters studied with circularly polarized vacuum ultraviolet radiation.

The photoionization of enantiomerically pure epichlorohydrin (C(3)H(5)OCl) has been studied using linearly and circularly polarized vacuum ultraviolet synchrotron radiation. The threshold photoelectron spectrum was recorded and the first three bands assigned using molecular orbital calculations for the expected conformers, although uncertain experimental conformer populations and an anticipated breakdown in Koopmans' theorem leave some ambiguity. Measurements of the photoelectron circular dichroism (PECD) were obtained across a range of photon energies for each of these bands, using electron velocity map imaging to record the angular distributions, during which a record PECD chiral asymmetry factor of 32% was observed.

Threshold photoelectron spectroscopy of cyclopropenylidene, chlorocyclopropenylidene, and their deuterated isotopomeres.

Cyclopropenylidene (c-C(3)H(2)), chlorocyclopropenylidene (c-C(3)HCl), and their deuterated isotopomers were studied by the threshold photoelectron-photoion coincidence (TPEPICO) technique using VUV synchrotron radiation. The carbenes were generated via flash pyrolysis. In all species a change in geometry is visible upon ionization, with significant activity in the C═C, C-C-stretching mode and, in the case of c-C(3)H(2)/D(2), the C-H-bending mode.

Threshold photoelectron spectroscopy of the methyl radical isotopomers, CH3, CH2D, CHD2 and CD3: synergy between VUV synchrotron radiation experiments and explicitly correlated coupled cluster calculations.

Threshold photoelectron spectra (TPES) of the isotopomers of the methyl radical (CH(3), CH(2)D, CHD(2), and CD(3)) have been recorded in the 9.5-10.5 eV VUV photon energy range using third generation synchrotron radiation to investigate the vibrational spectroscopy of the corresponding cations at a 7-11 meV resolution.

Photoelectron circular dichroism spectroscopy in an orbitally congested system: the terpene endoborneol.

We have measured the photoelectron circular dichroism (PECD) of single enantiomers of endoborneol in the photon region from 9.9 to 23.6 eV by combining circularly polarized synchrotron radiation and a velocity map imaging technique.

Determination of the absolute photoionization cross sections of CH3 and I produced from a pyrolysis source, by combined synchrotron and vacuum ultraviolet laser studies.

A pyrolysis source coupled to a supersonic expansion has been used to produce the CH3 radical from two precursors, iodomethane CH3I and nitromethane CH3NO2. The relative ionization yield of CH3 has been recorded at the SOLEIL Synchrotron Radiation source in the range 9.0-11.

The photoionisation of two phenylcarbenes and their diazirine precursors investigated using synchrotron radiation.

Two phenylcarbenes, chlorophenylcarbene (CPC) and trifluoromethylphenylcarbene (TFPC), were generated by jet flash pyrolysis of diazirine precursors. Their photoionisation was studied by photoelectron-photoion coincidence spectroscopy using synchrotron radiation. For CPC we determined an adiabatic ionisation energy (IE) of 8.

A versatile electron-ion coincidence spectrometer for photoelectron momentum imaging and threshold spectroscopy on mass selected ions using synchrotron radiation.

We present a photoelectron-photoion coincidence (PEPICO) spectrometer named DELICIOUS II which combines a velocity map imaging apparatus with a Wiley-McLaren time of flight analyzer for the study of gas phase samples in interaction with the synchrotron radiation (SR). This versatile system is capable of providing photoelectron images on mass-selected compounds with kinetic energy resolutions of DeltaE/E=5% and a 17 eV bandwidth, as well as threshold photoelectron spectra with a measured resolution of 0.8 meV, as demonstrated on the 3p(-1) ionization of argon.