Investigation on the near-field evolution of industrial plumes from metalworking activities.

In a context where a significant fraction of the population lives near industrial areas, the main objectives of this study are to provide (a) new data on PM chemical compositions, heavy-metal concentrations and trace gases released by metalworking activities and (b) new information on the near-field evolution (up to about a thousand meters) of such industrial plumes in terms of particle chemical composition and size distribution. For that purpose, a one-month field campaign was performed in an industrial area near the city of Dunkirk (Northern France), combining measurements of atmospheric dynamics and physico-chemical characterization of air masses. Comparisons between several elemental ratios (mainly Mn/Fe), particle size distributions and volatile organic compound (VOC) concentrations at the stacks and at a near-field site suggest that plumes of a ferromanganese alloy plant were quickly mixed with pollutants emitted by other sources (mainly other industries, possibly traffic and sea spray), in particular a neighboring steelworks, before reaching the sampling site.

Fe and Mn oxidation states by TEM-EELS in fine-particle emissions from a Fe-Mn alloy making plant.

Fine particles were sampled both inside the chimneys and in the near-field of an Fe-Mn-alloy manufacturing plant. The transfer from one point to another point in the environment, as well as the bioavailability and toxicity of these two metals, depend above all on their speciation. The oxidation states of iron and manganese in the collected particles were determined by using transmission electron microscopy coupled with electron energy-loss spectroscopy (TEM-EELS).

Fast changes in chemical composition and size distribution of fine particles during the near-field transport of industrial plumes.

Aerosol sampling was performed inside the chimneys and in the close environment of a FeMn alloys manufacturing plant. The number size distributions show a higher abundance of ultrafine aerosols (10-100 nm) inside the plume than upwind of the plant, indicating the emissions of nanoparticles by the industrial process. Individual analysis of particles collected inside the plume shows a high proportion of metal bearing particles (Mn-/Fe-) consisting essentially of internally mixed aluminosilicate and metallic compounds.