A Nanofilm-Based Fluorescent Sensor toward Highly Efficient Detection of Ethephon.

Ethephon (ETH) is widely used to promote fruit ripening and improve fruit quality. However, improper use is harmful to human health and to the environmental safety. Therefore, development of the techniques for on-site and at real-time monitoring of ETH is of importance for its safe use.

Conformationally tunable calix[4]pyrrole-based nanofilms for efficient molecular separation.

Preparation of nanofilms which are able to reject water-soluble low molecular weight organic compounds in nanofiltration remains to be a challenge. Herein, we report a new kind of self-standing, defect-free, robust, centimeter-sized and thickness controllable calix[4]pyrrole (C[4]P)-based nanofilms with excellent molecular sieving performance in nanofiltration. The nanofilms were prepared via confined dynamic condensation of the tetra-benzoyl-hydrazine derivative of calix[4]pyrrole (CPTBH) with 1,3,5-benzenetricarboxaldehyde (BTC) at the air/dimethyl sulfoxide (DMSO) interface.

Hydrogen peroxide generation in microbial fuel cells using graphene-based air-cathodes.

Utilization of two-electron oxygen reduction reaction (ORR) in bioelectrochemical systems (BES) is a novel way to generate HO from wastewater, and cathode catalyst is a key factor affecting ORR performance. Here, the catalytic performance of plain graphene, oxidized graphene and graphene oxide (GO) in microbial fuel cells (MFCs) and the influence of oxygen-containing functional groups are reported. Oxidized graphene air-cathode had 78% and 131% higher HO productions than plain graphene cathode respectively in an abiotic reactor and an MFC.

Enhancing Signal Output and Avoiding BOD/Toxicity Combined Shock Interference by Operating a Microbial Fuel Cell Sensor with an Optimized Background Concentration of Organic Matter.

In the monitoring of pollutants in an aquatic environment, it is important to preserve water quality safety. Among the available analysis methods, the microbial fuel cell (MFC) sensor has recently been used as a sustainable and on-line electrochemical microbial biosensor for biochemical oxygen demand (BOD) and toxicity, respectively. However, the effect of the background organic matter concentration on toxicity monitoring when using an MFC sensor is not clear and there is no effective strategy available to avoid the signal interference by the combined shock of BOD and toxicity.

Preparation of novel W/O gel-emulsions and their application in the preparation of low-density materials.

A series of novel and stable water in oil (W/O) gel-emulsions was created by utilizing a new cholesteryl derivative, a low-molecular mass gelator (LMMGs), as a stabilizer. In the emulsions, n-heptane, n-octane, n-nonane, n-decane, tertiary butyl methacrylate (t-BMA), methyl methacrylate (MMA), or styrene can be used as a continuous phase, water as a dispersed phase, and the stabilizer in the continuous phase is only 2% (w/v). Importantly, the gel-emulsions could be prepared by simple agitation of the mixtures at room temperature, while heating, cooling, and addition of a cosolvent or other additional component are unnecessary.

Glucose-based fluorescent low-molecular mass compounds: creation of simple and versatile supramolecular gelators.

Five novel glucose-based naphthalene derivatives with linkers containing hydrazine, ethylenediamine, 1,3-propanediamine, 1,4-butanediamine, and 1,6-hexanediamine, respectively (1, 2, 3, 4, and 5) were designed and prepared. The gelation test revealed the following points: (1) within the 30 solvents tested, 1 gels water only; (2) in contrast, 2 gels not only water, but also 11 of the organic solvents tested, a typical "ambidextrous gelator"; (3) 3, 4, and 5, however, gel organic solvents only, and the numbers of solvents gelled are 11, 11 and 13, respectively. Clearly, these compounds are effective low-molecular mass gelators, and show transitions from a low-molecular mass hydrogelator to an ambidextrous gelator and then to low-molecular mass organogelators with a slight increase in the length of the spacers.