Magnetic Properties of a High-Pressure Torsion Deformed Co-Zr Alloy.

Co-Zr amorphous alloys exhibit soft magnetic properties, whereas the Co-rich crystalline magnetic phases in this alloy system displayed a hard magnetic behavior. In this study, an initial two-phase Co-Zr composite with an overall composition of 75 at.% Co and 25 at.

Exchange Bias Demonstrated in Bulk Nanocomposites Processed by High-Pressure Torsion.

Ferromagnetic (Fe or FeNi) and antiferromagnetic (NiO) phases were deformed by high-pressure torsion, a severe plastic deformation technique, to manufacture bulk-sized nanocomposites and demonstrate an exchange bias, which has been reported predominantly for bilayer thin films. High-pressure torsion deformation at elevated temperatures proved to be the key to obtaining homogeneous bulk nanocomposites. X-ray diffraction investigations detected nanocrystallinity of the ferromagnetic and antiferromagnetic phases.

Manufacturing of Textured Bulk Fe-SmCo Magnets by Severe Plastic Deformation.

Exchange-coupling between soft- and hard-magnetic phases plays an important role in the engineering of novel magnetic materials. To achieve exchange coupling, a two-phase microstructure is necessary. This interface effect is further enhanced if both phase dimensions are reduced to the nanometer scale.

Soft Magnetic Properties of Ultra-Strong and Nanocrystalline Pearlitic Wires.

The paper describes the capability of magnetic softening of a coarse-grained bulk material by a severe deformation technique. Connecting the microstructure with magnetic properties, the coercive field decreases dramatically for grains smaller than the magnetic exchange length. This makes the investigation of soft magnetic properties of severely drawn pearlitic wires very interesting.

Vapochromism and Magnetochemical Switching of a Nickel(II) Paddlewheel Complex by Reversible NH Uptake and Release.

Reaction of [NiCl (PnH) ] (1) (PnH=6-tert-butyl-pyridazine-3-thione) with NiCl affords the binuclear paddlewheel (PW) complex [Ni (Pn) ] (2). Diamagnetic complex 2 is the first example of a PW complex capable of reversibly binding and releasing NH . The NH ligand in [Ni (Pn) (NH )] (2⋅NH ) enforces major spectroscopic and magnetic susceptibility changes, thus displaying vapochromic properties (λ (2)=532 nm, λ (2⋅NH )=518 nm) and magnetochemical switching (2: S=0; 2⋅NH : S=1).

Magneto-Ionic Switching of Superparamagnetism.

Electrochemical reactions represent a promising approach to control magnetization via electric fields. Favorable reaction kinetics have made nanoporous materials particularly interesting for magnetic tuning experiments. A fully reversible ON and OFF switching of magnetism in nanoporous Pd(Co) at room temperature is demonstrated, triggered by electrochemical hydrogen sorption.

Redox processes in sodium vanadium phosphate cathodes - insights from operando magnetometry.

Operando magnetic susceptibility measurements of sodium ion cathode materials during repetitive electrochemical cycling enable a continuous and bulk sensitive monitoring of the transition metal oxidation states. Such measurements on NaxV2(PO4)3 identified vanadium to be the only ion undergoing oxidation/reduction processes upon battery operation. For the initial battery charging-discharging cycle as well as for the first cycle after prolonged room temperature storage, however, peculiarities within the magnetic susceptibility measurements indicate parasitic side reactions, likely on the cathode surface.

Magnetic Binary Supersaturated Solid Solutions Processed by Severe Plastic Deformation.

Samples consisting of one ferromagnetic and one diamagnetic component which are immiscible at the thermodynamic equilibrium (Co-Cu, Fe-Cu, Fe-Ag) are processed by high-pressure torsion at various compositions. The received microstructures are investigated by electron microscopy and synchrotron X-ray diffraction, showing a microstructural saturation. Results gained from microstructural investigations are correlated to magnetometry data.

Using Functionalized Silyl Ligands To Suppress Solvent Coordination to Silyl Lanthanide(II) Complexes.

The reaction of the potassium 1,3-trisilanediide MeSi[Si(MeSi)K] with SmI and YbI was found to give the respective disilylated complexes MeSi[Si(MeSi)]Sm·2THF and MeSi[Si(MeSi)]Yb·2THF. Desolvation of coordinated solvent molecules in these complexes made their handling difficult. However, using a number of functionalized silanide ligands, complexes with a diminished number or even no coordinated solvent molecules were obtained ((RSi)Ln(THF) (x = 0-3)).

Effects of concentration and vendor specific composition of formalin on postmortem MRI of the human brain.

Purpose: Formalin fixation prevents tissue autolysis by crosslinking proteins and changes tissue microstructure and MRI signal characteristics. Previous studies showed high variations in MR relaxation time constants of formalin fixed brain tissue, which has been attributed to the use of different formalin concentrations. Our investigations confirmed the influence of formalin concentration on relaxation times and unexpectedly revealed an influence of vendor specific formalin composition, which has not been investigated so far.

Electrochemical cell for in situ electrodeposition of magnetic thin films in a superconducting quantum interference device magnetometer.

An electrochemical cell is designed and applied for in situ electrodeposition of magnetic thin films in a commercial SQUID magnetometer system. The cell is constructed in such a way that any parasitic contribution of the cell and of the substrate for electrodeposition to the magnetic moment of the deposited film is reduced to a minimum. A remanent minor contribution is readily taken into account by a proper analysis of the detected signal.

Iron mapping using the temperature dependency of the magnetic susceptibility.

Purpose: The assessment of iron content in brain white matter (WM) is of high importance for studying neurodegenerative diseases. While R2 * mapping and quantitative susceptibility mapping is suitable for iron mapping in gray matter, iron mapping in WM still remains an unsolved problem. We propose a new approach for iron mapping, independent of diamagnetic contributions of myelin by assessing the temperature dependency of the paramagnetic susceptibility.

In situ monitoring magnetism and resistance of nanophase platinum upon electrochemical oxidation.

Controlled tuning of material properties by external stimuli represents one of the major topics of current research in the field of functional materials. Electrochemically induced property tuning has recently emerged as a promising pathway in this direction making use of nanophase materials with a high fraction of electrode-electrolyte interfaces. The present letter reports on electrochemical property tuning of porous nanocrystalline Pt.

SQUID magnetometry combined with in situ cyclic voltammetry: A case study of tunable magnetism of [Formula: see text]-FeO nanoparticles.

SQUID magnetometry combined with in situ cyclic voltammetry by means of a three-electrode chemical cell opens up novel potentials for studying correlations between electrochemical processes and magnetic behaviour. The combination of these methods shows that the charge-induced variation of the magnetic moment of nanocrystalline maghemite ([Formula: see text]-FeO) of about 4% strongly depends on the voltage regime of charging. Upon positive charging, the charge-induced variation of the magnetic moment is suppressed due to adsorption layers.

Detection of laser-induced nanosecond ultrasonic pulses in metals using a pancake coil and a piezoelectric sensor.

A piezoelectric sensor and a pancake coil sensor were used for broadband detection of laser-induced ultrasound in single-crystal aluminum and polycrystalline nickel. Pressure pulses with pronounced compression phases were induced by laser pulses of 5 ns duration from one side of the specimens and detected from the opposite side. A coupling layer of water was required for the piezoelectric method, whereas the pancake coil placed in the biasing permanent field of a cylindrical magnet ~0.

Attenuation of ultrasound in severely plastically deformed nickel.

Ultrasound attenuation was measured in nickel specimens of about 30 mm diameter prepared using the high pressure torsion technique. The cold working process produced an equivalent shear strain increasing from zero at the center up to 1000% at the edge of the specimen. The fragmentation of the grains due to multiple dislocations led to an ultrafine microstructure with large angle grain boundaries.