This study aimed to develop a cementitious repair material that can be constructed in cold weather conditions. The addition of nitrite/nitrate-based antifreezing agents has been shown to increase the initial strength of cementitious repair materials in cold weather. However, increasing the amount of these agents may lead to an increase in deformation behavior and shrinkage cracking.
View Article and Find Full Text PDFRecently, there has been increased use of calcium-nitrite and calcium-nitrate as the main components of chloride- and alkali-free anti-freezing agents to promote concrete hydration in cold weather concreting. As the amount of nitrite/nitrate-based accelerators increases, the hydration of tricalcium aluminate (CA phase) and tricalcium silicate (CS phase) in cement is accelerated, thereby improving the early strength of cement and effectively preventing initial frost damage. Nitrite/nitrate-based accelerators are used in larger amounts than usual in low temperature areas below -10 °C.
View Article and Find Full Text PDFMaterials (Basel)
September 2020
Various methods for repairing and modifying concrete surfaces have been proposed and applied to improve the durability of existing concrete structures. Surface modification through forced carbonation is a method of densification that forms calcium carbonate in the pores on the surface of concrete to improve its durability. In this study, to evaluate the applicability of this surface modification method to existing buildings, a series of experiments was conducted in which mortar specimens were repeatedly immersed in a carbon dioxide nanobubble aqueous solution.
View Article and Find Full Text PDFThis study investigated the physical properties of section-restoration mortar with calcium nitrite (Ca(NO)) and carbon dioxide (CO) nanobubble mixing water to develop materials and methods for the repair and reinforcement of cracks in reinforced concrete (RC) structures. As the calcium nitrite content increased, the generation rate and generated amount of nitrite-based hydration products also increased, owing to the rapid reaction between NO ions in calcium nitrite and CA(AlO). Further, the reaction with CS and CS was accelerated, thereby increasing the generation rates of Ca(OH) and C-S-H.
View Article and Find Full Text PDFRecently, calcium nitrite (Ca(NO)) and calcium nitrate (Ca(NO)) have been increasingly used as the main components of salt- and alkali-free anti-freezing agents, for promoting concrete hydration in cold-weather concreting. With an increase in the amount of nitrite-based accelerator, the hydration of CA, CS, and βCS in the cement is accelerated, thereby improving its early strength and effectively preventing the initial frost damage. Meanwhile, with an increase in the amount of nitrite-based accelerator, the expansion and shrinkage of the concrete-and, therefore, the crack occurrence-are expected to increase.
View Article and Find Full Text PDFWhen concrete is used for construction in cold-temperature regions, cold-resistant accelerators based on calcium nitrite (Ca(NO)) and calcium nitrate (Ca(NO)) are added to prevent early freezing damage. Although cold-resistant accelerators increase the early compressive strength and prevent early freezing damage by promoting cement hydration, the strength enhancement effect owing to the formation of such hydrates has not been evaluated quantitatively thus far. This study covers various types of analysis to understand the relationship between cement hydrate formation behavior and strength development upon the addition of varying amounts of nitrite-based accelerator.
View Article and Find Full Text PDFThere has recently been an increased use of anti-freezing agents that are primarily composed of salt- and alkali-free calcium nitrite (Ca(NO)) and calcium nitrate (Ca(NO)) to promote the hydration reaction of concrete in cold weather concreting. Nitrite-nitrate based accelerators accelerate the hydration of CA and CS in cement more quickly when their quantities are increased, thereby boosting the concrete's early strength and effectively preventing early frost damage. However, the connection between the hydrate formation behavior and the strength development characteristic over time has yet to be clearly identified.
View Article and Find Full Text PDFConcrete has a remarkably low ratio of tensile strength to compressive strength, and is widely used in construction. However, the occurrence of cracks in a concrete structure is inevitable. Nevertheless, in the presence of adequate moisture, small cracks in the concrete structure exhibit a propensity to self-heal by getting filled due to the rehydration of cement particles and the subsequent precipitation of calcium carbonate (CaCO).
View Article and Find Full Text PDFIn this study, the shrinkage and durability of environmental load-reducing fiber-reinforced polymer cement mortar (FRPCM) were examined by using silicone oil. The results indicated that the shrinkage can be greatly reduced by adding silicone oil. However, when the silicone oil is added in excess, it affects the strength and durability.
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April 2019
The purpose of this study is to evaluate the temperature distribution, strength development, porosity, scanning electron microscopy observation, shrinkage, and surface properties of concrete in order to apply microwave heat curing to the precast method and to analyze the CO₂ emissions and economic feasibility of microwave heat curing. The heating of a steel form by microwave heating enabled concrete to be efficiently cured at a temperature within a range of ±5 °C. After the curing, demolding strength could be cleared through the densification of the concrete by decreasing the porosity of the concrete.
View Article and Find Full Text PDFAlthough concrete is one of the most widely used construction materials, it is characterized by substantially low tensile strength in comparison to its compression strength, and the occurrence of cracks is unavoidable. In addition, cracks progress due to environmental conditions including damage by freezing, neutralization, and salt, Moreover, detrimental damage can occur in concrete structures due to the permeation of deteriorating elements such as Cl and CO₂. Meanwhile, under an environment in which moisture is being supplied and if the width of the crack is small, a phenomenon of self-healing, in which a portion of the crack is filled in due to the rehydration of the cement particles and precipitation of CaCO₃, is been confirmed.
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