Among the conglomeration of hydrogen bond donors, the C-H group is prevalent in chemistry and biology. In the present work, CHCl has been selected as the hydrogen bond donor and are X(CH ) are the hydrogen bond acceptors. Formation of C-H⋅⋅⋅X hydrogen bond under the matrix isolation condition is confirmed by the observation of red-shift in the C-H stretching frequency of CHCl and comparison with the simulated spectra.
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