Immobilization mechanism of antimony by applying zirconium-manganese oxide in soil.

Antimony (Sb) accumulation in soil poses great potential risk to ecological environment, and its mobilization, transformation and bioavailability are controlled by its fractions and species. Hence, it is important to develop functional materials with both adsorption and oxidation that achieve detoxification and control the mobilization of Sb. In this study, the synthesized zirconium‑manganese oxide (ZrMn) could extremely promoted the transformation of antimonite [Sb(III)] to antimonate [Sb(V)], induced the bioavailable Sb shift to well-crystallized (hydr)oxides of Mn and residual fractions, and further reduced mobility and bioavailability Sb in soil.

Sb(III) resistance mechanism and oxidation characteristics of Klebsiella aerogenes X.

Resistant bacteria are potential natural materials for the bioremediation of soil metalloid pollution. A strain isolated from farmland soil chronically exposed to Sb was identified as K. aerogenes X with high antimonite [Sb(III)] tolerance and oxidation ability.