J Colloid Interface Sci
February 2025
Developing efficient and environmentally benign heterogeneous catalysts that activate peroxymonosulfate (PMS) for the degradation of persistent organic contaminants remains a challenge. Metal-organic frameworks (MOFs)-derived metal oxide catalysts in advanced oxidation processes (AOPs) have received considerable attention research fraternity. Herein, we report an innovative magnetic trimetallic MOF-derived Fe-Mn-Sn oxide heterostructure (FeMnO@Sn) with adjustable morphology, size and Sn content, prepared through an impregnation-calcination strategy.
View Article and Find Full Text PDFTo overcome the limitations imposed by Sn-Sb electrodes, the titanium foam (PMT)-TiO-NTs@NiO-C/Sn-Sb composite electrodes with cubic crystal structure are synthesized by introducing NiO@C nanosheet arrays interlayer on the TiO-NTs/PMT matrix through hydrothermal and carbonization process. Then a two-step pulsed electrodeposition method is used to prepare the Sn-Sb coating. Benefiting from the advantages of stacked 2D layer-sheet structure, the obtained electrodes exhibit enhanced stability and conductivity.
View Article and Find Full Text PDFStable and efficient SnO electrodes are very promising for effectively degrading refractory organic pollutants in wastewater treatment. In this regard, we firstly prepared Ti self-doped urchin-like rutile TiO nanoclusters (TiO NCs) on a Ti mesh substrate by hydrothermal and electroreduction to serve as an interlayer for the deposition of Sb-SnO . The TiO NCs/Sb-SnO anode exhibited a high oxygen evolution potential (2.
View Article and Find Full Text PDFStable electrode materials with high catalytic activity are urgently required for electrochemical degradation of refractory organic pollutants in wastewater treatment. Herein, high conductive MXene (TiCT) was firstly fabricated by electrophoretic deposition (EPD) as an interlayer for preparing a novel PbO electrode. The well-conducted TiCT interlayer significantly improved the electrochemical performance of the EPD-2.
View Article and Find Full Text PDFSolar water evaporation is a promising and environment-friendly approach to relieve global water scarcity issues. Currently, many reports show that the voids and porous structure are beneficial to the absorption of solar energy to generate water steam. Herein, carbon nanospheres with central cavity structures are rationally designed by the one-step NaN/fluorinated graphite deflagration method.
View Article and Find Full Text PDFCuO@Al nanothermites with Al shell and CuO core were successfully fabricated via a simple self-assembly route. The composition and morphology of CuO@Al nanothermites were analyzed by x-ray diffraction and field-emission scanning electron microscopy in detail. When the equivalence ratio was 1.
View Article and Find Full Text PDFAn effective and biodegradable Ficus tikoua leaves extract was studied as a corrosion inhibitor for carbon steel in hydrochloric acid. Systematic electrochemical experiments and morphological characterization were carried out to investigate the properties of the corrosion inhibitor. Meanwhile, quantum chemical calculations were performed to aid further understanding of the electrochemical mechanism.
View Article and Find Full Text PDFThe biodegradable inhibitors, which could effectively reduce the rate of corrosion of carbon steel, were investigated by potentiodynamic polarization and electrochemical impedance spectroscopy (EIS). The mixed-type inhibitors extracted from Eriobotrya japonica Thunb. leaf exhibited excellent inhibition performance, and the inhibition efficiency for carbon steel reached 90.
View Article and Find Full Text PDFAmmonia is an important indicator among environmental monitoring parameters. In this work, thin-core fiber Mach-Zehnder interferometer deposited with poly (acrylic acid) (PAA), poly (allyamine hydrochloride) (PAH) and single-walled carbon nanotubes (SWCNTs-COOH) sensing film for the detection of ammonia gas has been presented. The thin-core fiber modal interferometer was made by fusion splicing a small section of thin-core fiber (TCF) between two standard single mode fibers (SMF).
View Article and Find Full Text PDFGuang Pu Xue Yu Guang Pu Fen Xi
June 2015
High density polyethylene (HDPE) was widely used as rotational packaging case in the material reserve field. The chemical changes of HDPE, exposed to particular climatic conditions of tropic marine atmosphere for one year-long in Wanning Hainan, were elucidated by the attenuated total reflection infrared spectroscopy (ATR-FTIR). The structural changes were studied qualitatively, mainly from the polymeric chain breaking, branching and oxidation to distinguish the degradation profile.
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