An on-site inspection system for explosives in a container using dust collection through a vent cover and ion mobility spectrometric detection.

Rapid and accurate cargo-inspection systems are required for shipping containers, because illegal and hazardous items, such as explosives and drugs, can be easily concealed in large containers. Dust in a container is suspended in the air and deposited in vent covers. The vapor and particulate matter of explosives can be adsorbed onto the dust.

Ionization behaviors of nitrotoluenes and dinitrotoluenes by reactions with acetone-related reactant ion.

Dinitrotoluenes (DNTs) and nitrotoluenes (NTs) are found in the environment as metabolites of trinitrotoluene (TNT). When acetone is used as the solvent/eluent in atmospheric pressure chemical ionization-mass spectrometry (APCI-MS), the reactant ion is [2Acetone + O ] for the negative ion mode. The reactant ion reacts with an analyte to produce M and/or [M - H] under atmospheric pressure.

Test method for vapor collection and ion mobility detection of explosives with low vapor pressure.

Rationale: Ion mobility spectrometry (IMS) has been widely used for on-site detection of explosives. Air sampling method is applicable only when the concentration of explosive vapor is considerably high in the air, but vapor pressures of common explosives such as 2,4,6-trinitrotoluene (TNT), 1,3,5-trinitro-1,3,5-triazacyclohexane (RDX), and pentaerythritol tetranitrate (PETN) are very low. A test method for analyzing the vapor detection efficiency of explosives with low vapor pressure via IMS was developed using artificial vapor and collection matrices.

Characteristics of ionization behaviors of aminonitrotoluene isomers produced by atmospheric pressure chemical ionization.

Rationale: Six of the isomers of aminonitrotoluene (ANT) are 2-amino-3-nitrotoluene (2A3NT), 2A4NT, 2A5NT, 2A6NT, 4A2NT, and 4A3NT. Some of them can be identified by chromatography and spectroscopy. Biochemical transformation of 2,4,6-trinitrotoluene (TNT) and dinitrotoluenes (DNTs) is very complex and ANTs are decomposition products of TNT and DNTs.