Molecular conformations of dumbbell-shaped polymers in good solvent.

We study conformational properties of diluted dumbbell polymers composed of two rings attached to both ends of a linear spacer segment. Our investigation involves analytical methods of field theory and bead-spring coarse-grained molecular dynamics simulations. We focus on the influence of the relative length of the spacer segment to the length of side rings on the shape and the relative size of dumbbells as compared to linear polymers of equal mass.

Conformational properties of hybrid star-shaped polymers comprised of linear and ring arms.

We study the influence of arm architecture on the conformational properties of hybrid star-shaped macromolecules called rosette polymers containing linear and ring grafts connected to a central branching point in a good solvent regime. We utilize analytical methods and molecular dynamics simulations to determine the estimates for the relative size ratios of these polymers with respect to linear chains and starlike polymers composed of the same number of solely linear arms and equal molecular weights. The results of numerical simulations corroborate our theoretical prediction that rosette polymers undergo conformational compactification with increasing functionality of grafted rings.

Universal size ratios of Gaussian polymers with complex architecture: radius of gyration vs hydrodynamic radius.

We study the impact of arm architecture of polymers with a single branch point on their structure in solvents. Many physical properties of polymer liquids strongly dependent on the size and shape measures of individual macromolecules, which in turn are determined by their topology. Here, we use combination of analytical theory, based on path integration method, and molecular dynamics simulations to study structural properties of complex Gaussian polymers containing [Formula: see text] linear branches and [Formula: see text] closed loops grafted to the central core.

Shape analysis of random polymer networks.

We propose the model of a random polymer network, formed on the base on Erdös-Rényi random graph. In the language of mathematical graphs, the chemical bonds between monomers can be treated as vertices, and their chemical functionalities as degrees of these vertices. We consider graphs with fixed number of vertices= 5 and variable parameter(connectedness), defining the total number of links=(- 1)/2 between vertices.

Universal size properties of a star-ring polymer structure in disordered environments.

We consider the complex polymer system, consisting of a ring polymer connected to the f_{1}-branched starlike structure, in a good solvent in the presence of structural inhomogeneities. In particular cases f_{1}=1 and f_{1}=2, such a system restores the synthesized tadpole-shaped polystyrenes [Doi et al., Macromolecules 46, 1075 (2013)MAMOBX0024-929710.

Loop statistics in polymers in crowded environment.

We analyze the probability to find a single loop in a long flexible polymer chain in disordered environment in d dimensions. The structural defects are considered to be correlated on large distances r according to a power law ∼r(-a). Working within the frames of continuous chain model and applying the direct polymer renormalization scheme, we obtain the values of critical exponents governing the scaling of probabilities to find the loops of various positions along the chain as function of loops' length.

Ring polymers in crowded environment: conformational properties.

We analyze the universal size characteristics of flexible ring polymers in solutions in presence of structural obstacles (impurities) in d dimensions. One encounters such situations when considering polymers in gels, colloidal solutions, intra- and extracellular environments. A special case of extended impurities correlated on large distances r according to a power law ~r(-a) is considered.