Pristine NASICON Electrolyte: A High Ionic Conductivity and Enhanced Dendrite Resistance Through Zirconia (ZrO) Impurity-free Solid-Electrolyte Design.

Sodium batteries are considered a promising candidate for large-scale grid storage at tropical climate zone, and solid-state sodium metal batteries have a strong proposition as high energy density battery. The main challenge is to develop ultra-pure solid-state ceramic electrolyte and compatible metal interface. Here, a scalable and energy-efficient synthesis strategy of sodium (Na) Super Ionic CONductor, NaZrSiPO (x = 2, NZSP) solid electrolyte, has been introduced with the complete removal of unreacted zirconium oxide (ZrO) impurities.

Fluorine Rich Borate Salt Anion Based Electrolyte for High Voltage Sodium Metal Battery Development.

This study demonstrates the enhanced performance in high-voltage sodium full cells using a novel electrolyte composition featuring a highly fluorinated borate ester anion (1 M Na[B(hfip)].3DME) in a binary carbonate mixture (EC:EMC), compared to a conventional electrolyte (1 M Na[PF] EC:EMC). The prolonged cycling performance of sodium metal battery employing high voltage cathodes (NVPF@C@CNT and NFMO) is attributed to uniform and dense sodium deposition along with the formation of fluorine and boron-rich solid electrolyte interphase (SEI) on the sodium metal anode.

Lower Diffusion-Induced Stress in Nano-Crystallites of P2-Na Ni Mn Ti O Novel Cathode for High Energy Na-ion Batteries.

P2-type Na Ni Mn Ti O (NMTNO) cathode is a preeminent electrode material for Na-ion batteries owing to its open prismatic framework, air-moisture stability, inexpensiveness, appealing capacity, environmental benignity, and Co-free composition. However, the poor cycling stability, sluggish Na-ion kinetics induced in bulk-sized cathode particles, cracking, and exfoliation in the crystallites remain a setback. To outmaneuver these, a designing strategy of a mechanically robust, hexagonal nano-crystallites of P2-type Na Ni Mn Ti O (NMTNO ) electrode via quick, energy-efficient, and low-cost microwave-irradiated synthesis is proposed.

Artificial Organo-Fluoro-Rich Anode Electrolyte Interface and Partially Sodiated Hard Carbon Anode for Improved Cycle Life and Practical Sodium-Ion Batteries.

In this work, a strategy is introduced wherein without keeping any excess cathode, a practical full-cell sodium-ion battery has been demonstrated by utilizing a hard carbon (HC) anode and sodium vanadium fluorophosphate and carbon nanotube composite (NVPF@C@CNT) cathode. A thin, robust, and durable solid electrolyte interface (SEI) is created on the surface of HC through its incubation wetted with a fluoroethylene carbonate (FEC)-rich warm electrolyte in direct contact with Na metal. During the incubation, the HC anode is partially sodiated and passivated with a thin SEI layer.