An in-situ polymer-solution-processing approach enables the efficient production of uniform graphene-reinforced polylactic acid (G-PLA) nanocomposites with notable physical and biomedical properties. The approach effectively enhances the interfacial bonding between graphene and PLA by creating graphene dangling bonds and defects during exfoliation. As a result, an 182 % increase in Young's modulus and an 85 % increase in tensile strength can be achieved in G-PLA.
View Article and Find Full Text PDFAs the capacity of individual offshore wind turbines increases, prolonged downtime (due to maintenance or faults) will result in significant economic losses. This necessitates enhancing the efficiency of vessel operation and maintenance (O&M) to reduce O&M costs. Existing research mostly focuses on planning O&M schemes for individual vessels.
View Article and Find Full Text PDFIntroduction: Dementia is marked by a steady decline or worsening in cognitive abilities, affecting memory, logic, and social competencies. While many studies suggest a potential link between the amount of sleep and dementia risk, the outcomes are not yet consistent. This research delved into the relationship between sleep length and bedtime on cognitive abilities using an extensive dataset from the China Family Panel Studies (CFPS) from 2014 to 2020.
View Article and Find Full Text PDFCalcium peroxide nanoparticles (nCP) as a versatile and safe solid source of hydrogen peroxide (HO) receive substantial attention from researchers as a potential groundwater remediation reagent. In this study, we synthesized polyvinylpyrrolidone-coated calcium peroxide nanoparticles (PVP@nCP-PVP) to control the release rate of HO and modulate pH fluctuation simultaneously. The PVP@nCP-PVP is fully characterized and the HO releasing kinetics and mechanisms are investigated.
View Article and Find Full Text PDFThe development of portable electronic devices has created greater demands for multifunctional energy integration systems. Self-powered systems have gained widespread interest because they can collect and storage renewable environmental energy and provide stable electricity to electronic devices. Herein, we developed a flexible self-charging energy system, involving textile-based zinc-ion hybrid (ZIHC) and triboelectric nanogenerator (TENG), which demonstrates wearable, compatibility, lightweight and can quickly harvest and store energy.
View Article and Find Full Text PDFCr(VI) is difficult to remove from wastewater via a one-step method because it is a type of oxyanion. Developing ARPs to selectively remove total Cr is critical for Cr(VI) remediation, including Cr(VI) adsorption-reduction and Cr(III) complexation. Hereon, chitosan and biochar modified-FeS (CTS-FeS@BC) was prepared to apply in the selective removal of total Cr from wastewaters.
View Article and Find Full Text PDFIn wastewater treatment by persulfate-based advanced oxidation processes (PS-AOPs), electron-deficient aromatic pollutants (EDAPs) are refractory to nonradical pathway. To explore an efficient degradation pathway for EDAPs, MgCu-biochar (BC) (x = 0.5, 1, 1.
View Article and Find Full Text PDFPolychlorinated biphenyls (PCBs) degradation by peroxymonosulfate (PMS) activation through •OH and SO radical oxidation process was the effective technology in the last decades; however, there were few research focusing on removing PCBs by O and O induced by PMS activation. In this work, 90.86% of 2,4,4-trichlorodiphenyl (PCB 28) was degraded by 0.
View Article and Find Full Text PDFBackground And Objective: Alzheimer's disease (AD) is the most common type of dementia, with its pathology like beta-amyloid and phosphorylated tau beginning several years before the clinical onset. The aim is to identify genetic risk factors associated with the onset of AD.
Methods: We collected three microarray data of post-mortem brains of AD patients and the healthy from the GEO database and screened differentially expressed genes between AD and healthy control.
Peroxisome proliferator-activated receptor γ (PPARγ) is the master regulator of adipogenesis and is expressed as two isoforms, PPARγ1 and PPARγ2. Our previous lentiviral overexpression study showed that PPARγ1 and PPARγ2 differentially regulated proliferation, differentiation, and apoptosis of the immortalized chicken preadipocyte cell line (ICP2). However, we cannot rule out the possibility that the endogenous expression of PPARγ isoforms may compromise our findings.
View Article and Find Full Text PDFThe combined pollution of heavy metals is ubiquitous worldwide. Mn/Al-layered double oxide-loaded crab shells biochar (LDO/BC) was prepared, so as to remediate the combined pollution of Cd and Cu in soil and water. The pristine and used LDO/BC were characterized and the results revealed that the layered double oxide was successfully loaded on crab shells biochar (BC) and metal element Ca in crab shells was beneficial to the formation of more regular layered and flake structure.
View Article and Find Full Text PDFSimultaneous elimination of As(III) and Pb(II) from wastewater is still a great challenge. In this work, an iron-sulfur codoped biochar (Fe/S-BC) was successfully fabricated in a simplified way and was applied to the remediate the co-pollution of As(III) and Pb(II). The positive enthalpy indicated that the adsorption in As-Pb co-pollution was an endothermic reaction.
View Article and Find Full Text PDFα-FeO modified biochar (FeO/BC) was prepared to remove Cu(II), Pb(II) and As(V). By adjusting the calcination temperature, the morphology and exposed crystal facets of α-FeO on the biochar were changed which further affected the adsorption performance. The kinetics and isotherms were investigated systematically to reveal adsorption effect of the adsorbent on Cu(II), Pb(II) and As(V).
View Article and Find Full Text PDFThe mechanisms and influencing factors for electron transfer complex need to be further studied by comparing radical and nonradical pathways. Herein, metal-biochar (BC) nanocomposites including CuO/BC, FeO/BC and ZnO/BC were prepared to activate peroxydisulfate (PDS) for bisphenol A (BPA) degradation. The existence of electron transfer complex in CuO/BC-PDS system were directly demonstrated.
View Article and Find Full Text PDFThe adsorption of hydrophobic organic compounds (HOCs) by microplastics (MPs) has attracted great attention in recent years. However, the ultimate environmental fate of the HOCs sorbed on MPs (HOCs-MPs) is poorly understood. In this work, we investigated the potential influence of the biotransformation process on the environmental fate of phenanthrene (PHE, a model HOC) sorbed on MPs (PHE-MPs) under the existence of humic acid (HA, the main ingredient of dissolved organic matter (DOM)) in the aquatic environment.
View Article and Find Full Text PDFMany researchers have paid more attention to the progress of carbon materials owing to their advantages, such as high activity, low cost, large surface area, high conductivity and high stability. Carbon materials have been widely used in persulfate-based advanced oxidation processes (PS-AOPs), especially for graphene (G), carbon nanotubes (CNTs) and biochar (BC). Various strategies are applied to promote their activity, however, up to now, the relationship between the structures of carbon materials and their activities in PS-AOPs has not been specifically reviewed.
View Article and Find Full Text PDFThe effects of organic acids on hexavalent chromium (Cr(VI)) removal by reduced iron-based materials have been extensively studied. Nevertheless, the promotion mechanism from the perspective of the electron transfer process is still unclear. Herein, sulfidated nanoscale zero-valent iron (S-nZVI) and the selected organic acids, citric acid (containing both -OH and -COOH groups) and oxalic acid (containing only -COOH groups), showed significant synergistic promotion effects in Cr(VI) removal.
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