Engineering Hygroscopic MOF-Based Silk Via Bioinspired Interfacial Assembly for Fast Moisture Manipulation.

Metal-organic frameworks (MOFs) have emerged as exceptional moisture sorbents in low humidity conditions. However, their typical powdered form often results in agglomeration, impeding water diffusion kinetics and practical handling. To enhance the accessibility and diversify the integration of MOFs, a universal and scalable bionic interfacial assembly method is introduced for fabricating MOF-based silk.

Prediction of postoperative complications following transanal total mesorectal excision in middle and low rectal cancer: development and internal validation of a clinical prediction model.

Purpose: The objective of this study is to develop a nomogram for the personalized prediction of postoperative complication risks in patients with middle and low rectal cancer who are undergoing transanal total mesorectal excision (taTME). This tool aims to assist clinicians in early identification of high-risk patients and in addressing preoperative risk factors to enhance surgical safety.

Methods: In this case-control study, 207 patients diagnosed with middle and low rectal cancer and undergoing taTME between February 2018 and November 2023 at The First Affiliated Hospital of Xiamen University were included.

The Short-Term and Long-Term Outcomes of Laparoscopy-Assisted Proximal Gastrectomy with Double-Tract Reconstruction versus Laparoscopy-Assisted Total Gastrectomy with Roux-en-Y Reconstruction for Adenocarcinoma of the Esophagogastric Junction: A Multicenter Study Based on Propensity Score Matching Analysis.

Purpose: To compare the antireflux effect, long-term nutritional levels, and quality of life (QoL) between laparoscopy-assisted proximal gastrectomy with double-tract reconstruction (LPG-DTR) and laparoscopy-assisted total gastrectomy with Roux-en-Y reconstruction (LTG-RY) for adenocarcinoma of the esophagogastric junction (AEG).

Methods: This multicenter retrospective cohort study collected clinicopathological and follow-up data of AEG patients from January 2016 to January 2021 at five high-volume surgery centers. The study included patients who underwent digestive tract reconstruction with LPG-DTR or LTG-RY after tumor resection.

Clinical efficacy and pathological outcomes of transanal endoscopic intersphincteric resection for low rectal cancer.

Background: Transanal endoscopic intersphincteric resection (ISR) surgery currently lacks sufficient clinical research and reporting.

Aim: To investigate the clinical effectiveness of transanal endoscopic ISR, in order to promote the clinical application and development of this technique.

Methods: This study utilized a retrospective case series design.

Transanal total mesorectal excision: single center study on risk factors for major complications.

Purpose: Transanal total mesorectal excision (TaTME) as a novel surgical approach for mid and low rectal cancer has gained significant research interest in recent years. The main objective of this study is to identify the risk factors associated with major complications after TaTME and evaluate the perioperative clinical outcomes.

Methods: A retrospective analysis was performed on the clinical data of patients with mid-to-low rectal cancer who underwent TaTME surgery and were admitted to the First Affiliated Hospital of Xiamen University from January 2018 to May 2023.

Spontaneous Separation of Immiscible Organic Droplets on Asymmetric Wedge Channels with Hierarchical Microchannels.

Spontaneous separation of immiscible organic droplets has substantial research implications for environmental protection and resource regeneration. Compared to the widely explored separation of oil-water mixtures, there are fewer reports on separating mixed organic droplets on open surfaces due to the low surface tension differences. Efficient separation of mixed organic liquids by exploiting the rapid spontaneous transport of droplets on open surfaces remains a challenge.

Designing a slippery/superaerophobic hierarchical open channel for reliable and versatile underwater gas delivery.

Achieving long-term and stable gas manipulation in an aqueous environment is necessary to improve multiphase systems relating to gas/liquid interaction. Inspired by the Pitcher plant and the hummingbird beak, we report a slippery/superaerophobic (SLSO) hierarchical fluid channel for continuous, durable, and flexible gas transport. The immiscible lubricant layer inside the SLSO channel promotes one-year stability of gas transport, and the maximum flux of this open channel can reach 3000 mL h.

Designing Versatile Superhydrophilic Structures via an Alginate-Based Hydrophilic Plasticene.

The rational design of superhydrophilic materials with a controllable structure is a critical component in various applications, including solar steam generation, liquid spontaneous transport, etc. The arbitrary manipulation of the 2D, 3D, and hierarchical structures of superhydrophilic substrates is highly desirable for smart liquid manipulation in both research and application fields. To design versatile superhydrophilic interfaces with various structures, here we introduce a hydrophilic plasticene that possesses high flexibility, deformability, water absorption, and crosslinking capabilities.

Unidirectional Moisture Delivery via a Janus Photothermal Interface for Indoor Dehumidification: A Smart Roof.

Rational control of the humidity in specific environments plays an important role in green building, equipment protection, etc. A smart apparatus that can actively expel inner moisture and largely prevent outer liquid penetration can be highly desirable. Through the integration of the Janus interface with unidirectional liquid manipulation and the solar evaporating layer, here, a Janus solar dehumidifying interface (JSDI) is designed for the switchable moisture management of an indoor environment.

On-Chip Liquid Manipulation via a Flexible Dual-Layered Channel Possessing Hydrophilic/Hydrophobic Dichotomy.

The hydrophilic/hydrophobic cooperative interface provides a smart platform to control liquid distribution and delivery. Through the fusion of flexibility and complex structure, we present a manipulable, open, and dual-layered liquid channel (MODLC) for on-demand mechanical control of fluid delivery. Driven by anisotropic Laplace pressure, the mechano-controllable asymmetric channel of MODLC can propel the directional slipping of liquid located between the paired tracks.

Improved Liquid Collection on a Dual-Asymmetric Superhydrophilic Origami.

Manipulating fluid with an open channel provides a promising strategy to simplify the current systems. Nevertheless, spontaneous on-surface fluid transport with large flux, high speed, and long distance remains challenging. Inspired by scallop shells, here a shell-like superhydrophilic origami (S-SLO) with multiple-paratactic and dual-asymmetric channels is presented to improve fluid collection.

Advances in Bioinspired Superhydrophobic Surfaces Made from Silicones: Fabrication and Application.

As research on superhydrophobic materials inspired by the self-cleaning and water-repellent properties of plants and animals in nature continues, the superhydrophobic preparation methods and the applications of superhydrophobic surfaces are widely reported. Silicones are preferred for the preparation of superhydrophobic materials because of their inherent hydrophobicity and strong processing ability. In the preparation of superhydrophobic materials, silicones can both form micro-/nano-structures with dehydration condensation and reduce the surface energy of the material surface because of their intrinsic hydrophobicity.

Fluid manipulation multifunctional lubricant infused slippery surfaces: principle, design and applications.

Water-repellent interfaces with high performance have emerged as an indispensable platform for developing advanced materials and devices. Inspired by the pitcher plant, slippery liquid-infused porous surfaces (SLIPSs) with reliable hydrophobicity have proven to possess great potential for various applications in droplet and bubble manipulation, droplet energy harvesting, condensation, fog collection, anti-icing, and anti-biofouling due to their excellent properties such as persistent surface hydrophobicity, molecular smoothness, and fluidity. This review aims to introduce the development history of interaction between SLIPSs and fluids as well as the design principles, preparation methods, and various applications of some of the more typical SLIPSs.

Synthesis of mono- and few-layered n-type WSe from solid state inorganic precursors.

Tuning the charge transport properties of two-dimensional transition metal dichalcogenides (TMDs) is pivotal to their future device integration in post-silicon technologies. To date, co-doping of TMDs during growth still proves to be challenging, and the synthesis of doped WSe, an otherwise ambipolar material, has been mainly limited to p-doping. Here, we demonstrate the synthesis of high-quality n-type monolayered WSe flakes using a solid-state precursor for Se, zinc selenide.

An interfacial floating tumbler with a penetrable structure and Janus wettability inspired by .

Designing advanced interfacial materials is decisive to the improvement of multiphase systems. Inspired by the superior floatability of , here we present a superhydrophobic/hydrophilic 3D Janus floater with a water managing ability. Its self-regulated floatation mechanism, as well as its water removal logic, should provide insight into the development of multifunctional interfacial carriers in the fields of micro-devices, solar evaporation,

Nanoprodrug ratiometrically integrating autophagy inhibitor and genotoxic agent for treatment of triple-negative breast cancer.

Effective combination therapies are urgently needed to treat triple-negative breast cancer (TNBC), which is insensitive to the existing treatment regimens. However, the synergistic potency of traditional small-molecule combinations is limited in TNBC mainly due to mismatched molar ratios, inconsistent pharmacokinetics, and intratumoral accumulation of individual drugs. Here, we find that the autophagy inhibitor hydroxychloroquine (HCQ) and the topoisomerase I inhibitor 7-ethyl-10-hydroxycamptothecin (SN38) exhibit synergistic effects when the molar ratio reaches 5:1.

Precise Cation Recognition in Two-Dimensional Nanofluidic Channels of Clay Membranes Imparted from Intrinsic Selectivity of Clays.

Various kinds of clays occur naturally and are accompanied by particular cations in their interlayer domains. Here we report the reassembled membranes with nanofluidic channel arrays by using the natural clays montmorillonite, mica, and vermiculite, which were imparted with the natural selectivity for realizing precise recognition and directional regulation of the naturally occurring interlayer cations. A typical surface-governed ionic transport behavior was observed in the clay nanofluidic channels.

Designing Flexible but Tough Slippery Track for Underwater Gas Manipulation.

Lubricant-infused slippery surface exhibits a series of superior properties such as pressure tolerance, self-healing, oil-repellence, etc. Especially when being applied in an aqueous environment, the reliable bubble manipulating ability of slippery surface offers great opportunities to develop advanced systems in the field of gas transport, water splitting, etc. To improve the strength and the functionality of slippery surfaces, a sliced lubricant-infused slippery (SLIS) track is presented here, possessing both flexibility and toughness for underwater bubble manipulation.

Eco-friendly geopolymer prepared from solid wastes: A critical review.

Solid wastes are generated from human activities which could cause damage to the ecological environment and human beings. In recent years, there has been extensive research on solid wastes utilized as precursors, aggregates, fibers, etc. to prepare the geopolymers, which has invariably been a research hotspot.

Adsorption toward Cu(II) and inhibitory effect on bacterial growth occurring on molybdenum disulfide-montmorillonite hydrogel surface.

Novel molybdenum disulfide-montmorillonite (MoS@2DMMT) hydrogels for Cu(II) removal and inhibition on bacterial growth were successfully prepared. MoS was first in-situ growth onto 2DMMT platelet through hydrothermal method and then cross-linked with organic reagents to form hydrogels. The flower-like structure of synthesized MoS could be clearly observed in MoS@2DMMT by SEM.

High-performance two-dimensional montmorillonite supported-poly(acrylamide-co-acrylic acid) hydrogel for dye removal.

High-performance two-dimensional montmorillonite supported-poly (acrylamide-co-acrylic acid) hydrogel for dye removal was investigated. Montmorillonite cooperated with acrylamide and acrylic acid via polymerization, hydrogen-bond, amidation and electrostatic interactions to form the three-dimensional reticular-structured hydrogel with the free entrance for macromolecules. Adsorption tests revealed that the efficient removal (97%) for methylene blue at high concentration (200 mg/L) could be achieved via a small dose of hydrogel (0.

Synthesis of chitosan cross-linked 3D network-structured hydrogel for methylene blue removal.

TiO loaded 2D montmorillonite (2DMMT)-chitosan-poly (acrylic acid) hydrogel with 3D network structure as a novel adsorbent for methylene blue (MB) removal was investigated. The hydrogel was formed via the polymerization and molecular forces between 2DMMT and polysaccharide. Physicochemical analysis and factor experiments were implemented on hydrogel.

Beetle-Inspired Hierarchical Antibacterial Interface for Reliable Fog Harvesting.

The microdroplets in fog flow have been considered as an important resource for supplying fresh drinking water. Most of the reported works of fog collection focus on the water-collecting ability rather than the environmental reliability of selected materials. In this work, a beetle-inspired hierarchical fog-collecting interface based on the antibacterial needle-array (ABN) and hydrophilic/hydrophobic cooperative structure is displayed.