CeO nanoparticles exhibit potential as solid adsorbents for carbon dioxide (CO) capture and storage (CCS), offering precise control over various facets and enhancing their efficiency. This study investigated the adsorption and desorption behaviors of two types of CeO nanoparticles: cubic CeO with primarily {001} facets and polyhedral CeO with mainly {111} facets. The results showed that despite polyhedral CeO's lower quantity, it demonstrated successful adsorption-desorption cycles in both oxidized and reduced states.
View Article and Find Full Text PDFA bioinspired alkylation dearomatization reaction was developed to construct the 5/6/6 fused-spiro tricyclic core framework and spiro-quaternary carbon chiral center. The usage of this approach for assembling these natural products of spirocyclic polycyclic polyprenylated acylphloroglucinols with an octahydrospiro-[cyclohexan-1,5'-indene] core is demonstrated by the first asymmetric total synthesis of highly oxidized hyperbeanol A.
View Article and Find Full Text PDFEcotoxicol Environ Saf
December 2024
The global-scale production of plastics has led to a significant accumulation in the environment, and it has become a major stressor to environmental sustainability, agricultural crops, and human health. Here we report the particle size effect of polystyrene (PS, typically microplastic) on the impact on rice suspension cells. This study used PS of different particle sizes (30 nm, 200 nm, and 2 μm) in a three-day co-culture experiment, the results showed that 30 nm, 200 nm, and 2 μm PS at the same concentration (100 μg/mL) caused 4.
View Article and Find Full Text PDFMulti-group data, which include the same set of variables on separate groups of samples, are commonly seen in practice. Such data structure consists of data from multiple groups and can be challenging to analyze due to data heterogeneity. We propose a novel Joint and Individual Component Regression (JICO) model to analyze multi-group data.
View Article and Find Full Text PDFBackground: More and more patients with pancreatic cancer (PC) received neoadjuvant therapy (NAT) and then underwent radical pancreatectomy. However, the benefit of adjuvant chemotherapy (AC) for these patients is still controversial. This study is designed to determine the benefits of postoperative AC for patients with PC undergoing NAT and radical resection.
View Article and Find Full Text PDFInt J Biol Macromol
November 2024
Bacterial infection and free radical oxidative stress at the wound site could easily cause cascade inflammation and hinder the healing process of the wound. In this study, chitosan-cysteine-gallic acid (CCG) hydrogel with antibacterial and antioxidant properties was synthesized by chitosan (CS), cysteine (Cys), and gallic acid (GA) for a preliminary evaluation of its therapeutic efficacy in a mouse model of full-layer skin defect. In vitro analysis showed that the CCG hydrogel had good antibacterial activity and blood compatibility.
View Article and Find Full Text PDFThe discharge arc of a high-current gas spark switch has a strong mechanical effect on the electrode and adjacent objects. The measurement of this mechanical effect on the electrode plays a very important role in switch design and the theoretical study of spark discharge. However, in traditional stress measurement systems, the spatial electromagnetic interference caused by the discharge and the high electrode voltage affects the measurement accuracy and can even damage the experimental instrument.
View Article and Find Full Text PDFMaterials (Basel)
July 2024
High-performance concrete (HPC) experiences significant degradation in its mechanical properties after fire exposure. While various post-fire curing methods have been proposed to rehabilitate thermally damaged concrete (TDC), the physical and chemical changes occurring during these processes are not well-understood. This study examines the strength and microstructure restoration of HPC through water and water-CO cyclic recuring.
View Article and Find Full Text PDFCargo translocation across membranes is a crucial aspect of secretion. In conventional secretion signal peptide-equipped proteins enter the endoplasmic reticulum (ER), whereas a subset of cargo lacking signal peptides translocate into the ER-Golgi intermediate compartment (ERGIC) in a process called unconventional protein secretion (UcPS). The regulatory events at the ERGIC in UcPS are unclear.
View Article and Find Full Text PDFBiodegradation was considered a promising and environmentally friendly method for treating environmental pollution caused by diuron. However, the mechanisms of biodegradation of diuron required further research. In this study, the degradation process of diuron by SL-6 was systematically investigated.
View Article and Find Full Text PDFAlthough the function and stability of catalysts are known to significantly depend on their dispersion state and support interactions, the mechanism of catalyst loading has not yet been elucidated. To address this gap in knowledge, this study elucidates the mechanism of Pt loading based on a detailed investigation of the interaction between Pt species and localized polarons (Ce) associated with oxygen vacancies on CeO(100) facets. Furthermore, an effective Pt loading method was proposed for achieving high catalytic activity while maintaining the stability.
View Article and Find Full Text PDFAdvanced hepatocellular carcinoma (HCC) is one of the most challenging cancers because of its heterogeneous and aggressive nature, precluding the use of curative treatments. Sorafenib (SOR) is the first approved molecular targeting agent against the mitogen-activated protein kinase (MAPK) pathway for the noncurative therapy of advanced HCC; yet, any clinically meaningful benefits from the treatment remain modest, and are accompanied by significant side effects. Here, we hypothesized that using a nanomedicine platform to co-deliver SOR with another molecular targeting drug, metformin (MET), could tackle these issues.
View Article and Find Full Text PDFThe mechanical properties and microstructure of the cemented paste backfill (CPB) in dry-wet cycle environments are particularly critical in backfill mining. In this study, coal gangue, fly ash, cement, glass fiber, and nano-SiO were used to prepare CPB, and dry-wet cycle tests on CPB specimens with different curing ages were conducted. The compressive, tensile, and shear strength of CPB specimens with different curing ages under different dry-wet cycles were analyzed, and the microstructural damage of the specimens was observed by scanning electron microscopy (SEM).
View Article and Find Full Text PDFDomesticated herbivores are an important agricultural resource that play a critical role in global food security, particularly as they can adapt to varied environments, including marginal lands. An understanding of the molecular basis of their biology would contribute to better management and sustainable production. Thus, we conducted transcriptome sequencing of 100 to 105 tissues from two females of each of seven species of herbivore (cattle, sheep, goats, sika deer, horses, donkeys, and rabbits) including two breeds of sheep.
View Article and Find Full Text PDFAccurate detection of multiple cardiovascular biomarkers is crucial for the timely screening of acute coronary syndrome (ACS) and differential diagnosis from acute aortic syndrome (AAS). Herein, an antibody microarray-based metal-enhanced fluorescence assay (AMMEFA) has been developed to quantitatively detect 7 cardiovascular biomarkers through the formation of a sandwich immunoassay on the poly(glycidyl methacrylate--2-hydroxyethyl methacrylate)-decorated GNR-modified slide (GNR@P(GMA-HEMA) slide). The AMMEFA exhibits high specificity and sensitivity, the linear ranges span 5 orders of magnitude, and the limits of detection (LODs) of cardiac troponin I (cTnI), heart-type fatty acid binding protein (H-FABP), C-reactive protein (CRP), copeptin, myoglobin, D-Dimer, and N-terminal pro-brain natriuretic peptide (NT-proBNP) reach 0.
View Article and Find Full Text PDFHard carbon as a negative electrode material for sodium-ion batteries (SIBs) has great commercial potential and has been widely studied. The sodium-ion intercalation in graphite domains and the filling of closed pores in the low voltage platform region still remain a subject of controversy. We have successfully constructed hard carbon materials with a pseudo-graphitic structure by using polymerizable p-phenylenediamine and dichloromethane as carbon sources.
View Article and Find Full Text PDFThe deployment of Li-S batteries in the commercial sector faces obstacles due to their low electrical conductivity, slow redox reactions, quick fading of capacity, and reduced coulombic efficiency. These issues stem from the "shuttle effect" associated with lithium polysulfides (LiPSs). In this work, a haystack-like CeO derived from a cerium-based metal-organic framework (Ce-MOF) is obtained for the modification of a polypropylene separator.
View Article and Find Full Text PDFMulti-modal data are prevalent in many scientific fields. In this study, we consider the parameter estimation and variable selection for a multi-response regression using block-missing multi-modal data. Our method allows the dimensions of both the responses and the predictors to be large, and the responses to be incomplete and correlated, a common practical problem in high-dimensional settings.
View Article and Find Full Text PDFFish Shellfish Immunol
June 2024
Histones and their N-terminal or C-terminal derived peptides have been studied in vertebrates and presented as potential antimicrobial agents playing important roles in the innate immune defenses. Although histones and their derived peptides had been reported as components of innate immunity in invertebrates, the knowledge about the histone derived antimicrobial peptides (HDAPs) in invertebrates are still limited. Using a peptidomic technique, a set of peptide fragments derived from the histones was identified in this study from the serum of microbes challenged Mytilus coruscus.
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