Tungsten doped FeCoP nanoparticles embedded into carbon for highly efficient oxygen evolution reaction.

Designing active and stable electrocatalysts with economic efficiency for oxygen evolution reaction (OER) is essential for developing water splitting process at an industrial scale. Herein, we rationally designed a tungsten doped iron cobalt phosphide incorporated with carbon (W-FeCoP/C), prepared by a mechanochemical approach. X-ray photoelectron spectroscopy (XPS) revealed that the doping of W led to an increasing of Co/Co and Fe/Fe molar ratios, which contributed to the enhanced OER performance.

Two aquaporins, PIP1;1 and PIP2;1, mediate the uptake of neonicotinoid pesticides in plants.

Neonicotinoids (NEOs), a large class of organic compounds, are a type of commonly used pesticide for crop protection. Their uptake and accumulation in plants are prerequisites for their intra- and intercellular movements, transformation, and function. Understanding the molecular mechanisms that underpin NEO uptake by plants is crucial for effective application, which remains elusive.

Insights into the volatile flavor and quality profiles of loquat ( Lindl.) during shelf-life via HS-GC-IMS, E-nose, and E-tongue.

Loquat fruits are among the most popular Chinese fruits because of their unique taste and aroma. The quality profiles of these fruits during 18 days of shelf-life at 20 °C were elucidated by headspace gas chromatography-ion mobility spectrometry (HS-GC-IMS), E-nose, and E-tongue. During shelf-life period, the properties and variations of 43 (20 aldehydes, 7 esters, 6 ketones, 1 alcohol, and 1 furan) volatile flavored compounds were determined by GC-IMS, which showed that the contents of methyl 3-methyl butanoate, ethyl acetate, and dimethyl ketone gradually decrease with prolonged shelf-life time, while (E)-2-heptenal, heptanal, (E)-2-pentenal, 1-penten-3-one 3-pentanone and 2-pentylfuran increase.

Visible-Light-Promoted Intermolecular β-Acyl Difunctionalization of Alkenes via Oxidative Radical-Polar Crossover.

A visible-light-induced β-acyl difunctionalization of alkenes with acyl oxime esters and various nucleophiles was developed to achieve molecular complexity from readily available raw materials via oxidative radical-polar crossover. A variety of nucleophiles, including H-sulfoximines, indoles, indazole, and trimethoxybenzene, were all effectively applicable to the sustainable reaction system. The novel synthetic strategy features mild reaction conditions, a broad substrate scope (39 examples), easy scale-up, and excellent regioselectivity.

Visible-Light-Induced Decarboxylation of Dioxazolones to Phosphinimidic Amides and Ureas.

A visible-light-induced external catalyst-free decarboxylation of dioxazolones was realized for the bond formation of N=P and N-C bonds to access phosphinimidic amides and ureas. Various phosphinimidic amides and ureas (47 examples) were synthesized with high yields (up to 98%) by this practical strategy in the presence of the system's ppm Fe.

CuCl-photocatalyzed C-H amination of benzoxazoles.

The direct coupling of benzoxazoles and amines was realized by visible light irradiation and CuCl catalysis. Various aminated benzoxazoles were successfully synthesized under mild conditions with air as an oxidant.

Effects of tebuconazole application at different growth stages on rice grain quality of rice-based untargeted metabolomics.

Tebuconazole (TEB) is a pesticide widely used in crops and has a strong control effect on fungal pathogens. TEB abuse has caused many food safety problems. In this study, the TEB residue in rice and the effect of TEB on white rice quality were investigated.

Impact of substrate digestibility on microbial community stability in methanogenic digestors: The mechanism and solution.

This study investigated the temporal dynamics of digestion efficiency and community stability in digesters fed with waste activated sludge (WAS), straw (STR-AD), food waste (FW-AD) and mixture of straw-and-food waste (STR-FW-AD). Results showed that carbon removals of recalcitrant substrates (i.e.

Ce(III)/Photoassisted Synthesis of Amides from Carboxylic Acids and Isocyanates.

The Ce(III)-photocatalyzed synthesis of amides from carboxylic acids and aryl isocyanates was developed. The reaction includes the formation of alkyl radicals from carboxylic acids followed by radical addition to the electron-deficient carbon of isocyanate.

Uptake, translocation, and subcellular distribution of three triazole pesticides in rice.

Triazole pesticides are widely used for the control of pathogenic fungi in crops, which were frequently detected in edible parts. Its extensive use has caused many environmental pollution and food safety problems. In this study, the uptake, translocation, and subcellular distribution of three triazole pesticides (triadimefon, tebuconazole, and epoxiconazole) in rice were investigated.

Metal-Free Photosynthesis of Alkylated Benzimidazo[2,1-]isoquinoline-6(5)-ones and Indolo[2,1-]isoquinolin-6(5)-ones in PEG-200.

A visible-light-induced decarboxylation reaction was developed for the synthesis of alkylated benzimidazo[2,1-]isoquinoline-6(5)-ones and indolo[2,1-]isoquinolin-6(5)-ones under metal-free conditions. Impressively, metal catalysts and traditionally volatile organic solvents could be effectively avoided.

Acyl Radicals from α-Keto Acids: Metal-Free Visible-Light-Promoted Acylation of Heterocycles.

A general and metal-free visible-light-induced decarboxylative arylation procedure at room temperature was described for the construction of acylated heterocyclic derivatives, such as benzimidazo/indolo[2,1-]isoquinolin-6(5)-ones, aroylazaspiro[4.5]trienones, thioflavones, and so on. This practical arylation procedure was conducted by using 2,4,5,6-tetra(9-carbazol-9-yl)isophthalonitrile (4CzIPN) as a photocatalyst under mild conditions, which avoided the use of an additional base, traditional heating, and metal reagents.

Sludge pre-treatments change performance and microbiome in methanogenic sludge digesters by releasing different sludge organic matter.

In this study, temporal impacts of thermal, alkaline/acid and thermal-alkaline sludge pre-treatments on digestion performance and microbiome were investigated and compared in methanogenic sludge digesters. Results showed that thermal and alkaline/acid pre-treatments were efficient in releasing intracellular and EPS organic matter, respectively. The thermal-alkaline pre-treatment showed synergistic impacts of both thermal and alkaline/acid pre-treatments by releasing the major portion of sludge organic matter from solid- to liquid-phase, which result in 60-65% organic carbon removal in subsequent sludge digestion and further optimizing digestion temperature had negligible improvement.

Development of an alkaline/acid pre-treatment and anaerobic digestion (APAD) process for methane generation from waste activated sludge.

Anaerobic sludge digesters are biorefineries for energy recovery from waste activated sludge (WAS) via methane production, in which disintegration of floc structure and microbial cells is a major challenge in releasing extracellular polymeric substances (EPS) and cytoplasmic macromolecules for subsequent hydrolysis and fermentation. Here, we developed a new process combining alkaline/acid pre-treatments and anaerobic digestion (APAD) to improve sludge digestion. Both alkaline and acid pre-treatments effectively disintegrated the floc structure and microbial cells to release sludge organic contents.

Effect of Imidacloprid Uptake from Contaminated Soils on Vegetable Growth.

In the present study, the effect of imidacloprid uptake from contaminated soils on the growth of leaf vegetable Shanghaiqing was investigated. The result showed that during 35-day exposure, the concentration of imidacloprid (IMI) was in the order of vegetable shoots > vegetable roots > soil, indicating that IMI was more readily concentrated in vegetable shoots than in roots. Moreover, the biomass of IMI-treated vegetable shoots was comparable to that of the controls with early exposure, but was higher than that of the controls after 7-day exposure, showing that the test concentration of IMI could stimulate vegetable growth.

Organic matter rather than salinity as a predominant feature changes performance and microbiome in methanogenic sludge digesters.

Due to low digestibility and long retention time of anaerobic sludge digestion, pre-treatment with alkaline/acid has been widely employed to enhance the rate and extent of sludge digestion. Nonetheless, effects of gradient concentrations of alkaline/acid pre-treatments and resulting salinity on digestion performance and sludge microbiome remain poorly understood. To elucidate these effects, both batch- and reactor-experiments were setup with varied feeding sludge.