The low cost of biomass has made it an important option for providing carbon sources in the treatment of low carbon to nitrogen ratio (C/N) wastewater constructed wetland (CW). However, the unstable release of biomass carbon source reduces utilization and operation efficiency of CW. In this study, aged corn straw was used as raw material, and modification treatments with acid, alkali and oxidant were to optimize the conditions for stable carbon source release.
View Article and Find Full Text PDFDue to global population growth and increased healthcare accessibility, pharmaceuticals and personal care products (PPCPs) are closely linked with human activities and have become new pollutants alongside some legacy priority pollutants, such as polycyclic aromatic hydrocarbons (PAHs). Although PPCPs have been detected in numerous river basins in recent years, a few researches have been carried out on their association with human activities. In this paper, the concentrations of PPCPs and toxicological data were compiled for over 25 representative watersheds in China in the past two decades from various sources, including PubMed, Elsevier and Springer.
View Article and Find Full Text PDFNeonicotinoids are widely used pesticides around the world, but the photolysis of neonicotinoids in cold agricultural region are still in blank. This paper aimed to study the influence of cold temperature over photolysis of neonicotinoids. To this end, the photolysis rates and photoproducts of dinotefuran and nitenpyram in water, ice and freeze-thawing condition were determined.
View Article and Find Full Text PDFThe changes of medical solid waste (MSW) output in recent years have had a significant impact on the spread of the virus. There is a high-risk transmission of MSW in various stages such as storage, transportation, and treatment during the COVID-19. To cope with the risks brought by the epidemic, normalized prevention consumes a large amount of protective clothing, medical masks, goggles, packaging bags, and other related medical supplies.
View Article and Find Full Text PDFThe emission reduction of atmospheric pollutants during the COVID-19 caused the change in aerosol concentration. However, there is a lack of research on the impact of changes in aerosol concentration on carbon sequestration potential. To reveal the impact mechanism of aerosols on rice carbon sequestration, the spatial differentiation characteristics of aerosol optical depth (AOD), gross primary productivity (GPP), net primary productivity (NPP), leaf area index (LAI), fraction of absorbed photosynthetically active radiation (FPAR), and meteorological factors were compared in the Sanjiang Plain.
View Article and Find Full Text PDFEnviron Sci Pollut Res Int
November 2023
The high value resource utilization of corn straw is a long-term problem at present and in the future. Biochar preparation is an important utilization way of corn straw. The research on city tail water treated by constructed wetland (CW) with biochar was carried out to further increase the wastewater treatment capacity of the CW.
View Article and Find Full Text PDFEnviron Sci Pollut Res Int
October 2023
Constructed wetland (CW) is an important method of ecological water treatment, and CW has obvious advantage in treating low-pollution water. In order to improve the treatment efficiency of CW, the first-order and second-order kinetics simulations of pollutant removal in CW were carried out to optimize operating conditions. The experimental study of city tail water treatment under unmodified biochar (different additions) or different modified biochar conditions showed that the first-order kinetic equation relatively accurately reflect the removal of pollutants by substrate.
View Article and Find Full Text PDFThree novel neonicotinoids (cycloxaprid, flupyradifurone and sulfoxaflor) were designed to reduce the biotoxicity for non-target organisms. These neonicotinoids were photolyzed under light radiation, but it was unclear for the photo-enhanced toxicity and influences of the novel modifying group of the three neonicotinoids. The photolysis and photo-enhanced toxicity experiments were performed for the three neonicotinoids, coupled with quantum chemistry calculation, the mechanisms of photolysis, photo-enhanced toxicity and the influences of novel modifying groups were analyzed.
View Article and Find Full Text PDFThe Schottky barrier (SB) in the ultraclean van der Waals contact between two-dimensional (2D) MoS and three-dimensional (3D) indium (In) strikingly deviates from the Schottky-Mott limit (SML). Herein, on the basis of first-principles calculation, the origin of the SB deviation is brought to bear, as well as a strategy for mitigating the SB deviation. In light of the good agreement between the SB and the corrected SB by interface potential difference (Δ) and Fermi -level shift (Δ) based on the SML, the SB deviation is attributed to the combined effects of Δ and Δ.
View Article and Find Full Text PDFBiochar prepared from straw as constructed wetland (CW) substrate reduces straw pollution and simultaneously promotes the wastewater treatment efficiency of CW. In order to further analyze the pollutant removal mechanism of KMnO-modified biochar substrate, the KMnO-modified biochar was characterized. The experiment on city tail water treatment by CW with biochar was analyzed.
View Article and Find Full Text PDFNeuropathic pain is a growing concern in the medical community, and studies on new analgesic targets for neuropathic pain have become a new hot spot. Whether Connexin43 (Cx43) has a key role in neuropathic pain mediated by the purinergic 2X4 (P2X4) receptor in rats with chronic constriction injury (CCI) was explored in this study. Our experimental results show that blockade of Cx43 could attenuate neuropathic pain in rats suffering from CCI via the P2X4, p38, ERK, and NF-kB signalling pathways.
View Article and Find Full Text PDFBackground: This paper introduces a case of recurrent keratoacanthoma (KA). KA is a self-healing disease. Recurrence after surgical resection is rare.
View Article and Find Full Text PDFOwing to their wide distribution, easy production, and resistance to degradation, microplastics (MPs) represent a globally emerging group of pollutants of concern. Furthermore, their decomposition can result in the generation of nanoplastics (NPs), which cause further environmental issues. Currently, the impact of the combination of these plastics with other organic pollutants on crop growth remains poorly investigated.
View Article and Find Full Text PDFThe pollution of corn straw to the environment had attracted much attention. The preparation and alkali modification of corn straw biochar as the constructed wetland (CW) substrate was conducive to solving the environment pollution caused by straw and improving the purification effect of CW. The NaOH modification mechanism of corn straw biochar was analyzed by measuring the surface morphology, element content, specific surface area (SSA), pore volume, crystal structure, surface functional groups and CO adsorption.
View Article and Find Full Text PDFPermafrost peatlands, as large soil carbon pools, are sensitive to global warming. However, the effects of temperature, moisture, and their interactions on carbon emissions in the permafrost peatlands remain unclear, when considering the availability of soil matrixes. The permafrost peatland (0-50 cm soil) in the Great Xing'an Mountains was selected to explore the deficiency.
View Article and Find Full Text PDFThe combined effects and respective advantages of using pyrite and alkali-modified rice husk (RH) were studied as substrates for nitrogen and phosphorus removal from constructed wetlands, and the effects of the carbon to nitrogen (C/N) ratio and the tidal flow mode on system performance were explored. The results showed that alkali-modified RH, which enhances heterotrophic denitrification, had far more advantages than pyrite, which enhances autotrophic denitrification, and alkali-modified RH can be used for the treatment of sewage containing low C/N ratios. At a C/N ratio of 1.
View Article and Find Full Text PDFCorn straw is rich in resources, and the preparation of biochar as the constructed wetland (CW) substrate is an effective measure to realize high-value resource utilization. The objective of this paper was to improve the treatment effect of CW on city tail water, the freeze-thaw cycles (FTCs) modification and chemical modification (KMnO, NaOH and HSO) of straw biochar and the utilization of modified straw biochar in CW were studied. The modification characteristics of straw biochar were discussed through scanning electron microscope, element determination, pore structure determination, X-ray diffraction analysis, Fourier transform infrared reflection analysis, CO adsorption and desorption experiment and application experiment of CW (no plants and plants).
View Article and Find Full Text PDFClimate warming has intensified changes of permafrost freeze-thaw process and postponed the starting period of soil freezing, which significantly affected the processes of NO production and emission from the soils. However, responses of soil NO fluxes to freeze-thaw cycles (FTC) during autumn freezing period in permafrost peatlands in field remain unclear. Therefore, the static chamber-GC techniques were used to explore the effects of autumn FTC on NO fluxes in the three permafrost peatlands [Calamagrostis angustifolia peatland (CA), Larix gmelini-Sphagnum swamp (LS), and Eriophorum vaginatum peatland (EV)] in Da Xing'an Mountains, Northeast China, from September to November 2019.
View Article and Find Full Text PDFCascade catalysis that combines chemical catalysis and biocatalysis has received extensive attention in recent years, especially the integration of metal nanoparticles (MNPs) with enzymes. However, the compatibility between MNPs and enzymes, and the stability of the integrated nanocatalyst should be improved to promote the application. Therefore, in this study, we proposed a strategy to space-separately co-immobilize MNPs and enzymes to the pores and surface of a highly stable covalent organic framework (COF), respectively.
View Article and Find Full Text PDFGeological disasters seriously threaten the safety of human life, property, ecological resources, and the environment. Effective control of geological disasters is the focus of achieving sustainable social development. The Helong City (Jilin Province, China) was selected as the case study.
View Article and Find Full Text PDFThe co-combustion characteristics and kinetics of Fenton/CaO conditioned MSS, and biomass rice husk (RH) are studied by thermogravimetry, and the condition optimization was carried out by response surface methodology (RSM). The results show that the mixed fuel with RH is helpful to decrease T and T values and increase combustion characteristic index (CCI). The CCI of MSS after conditioning is 0.
View Article and Find Full Text PDFEnviron Sci Pollut Res Int
November 2021
Water pollution control is the focus of environmental pollution control. Ecological water treatment is widely used because of its low cost and landscape effect, and has no pollution. Aquatic plants have attracted wide attention because of their low cost and high level of resource utilization.
View Article and Find Full Text PDFConstructed wetland (CW) has obvious advantages in wastewater treatment of medium and small towns. However, there is a lack of health monitoring research on CW system clogging. The electrical conductivity (EC) of wastewater purified by CW is related to the concentration of pollutants, which can reflect the CW clogging.
View Article and Find Full Text PDFEnviron Sci Pollut Res Int
September 2021
Composting is an effective method for utilizing agricultural straw waste and livestock manure resources. Using deer manure and corn straw as raw materials, the changes in various indexes were studied during composting under different initial C/N ratios, initial moisture contents, and particle sizes of corn straw, and compost maturity was evaluated. Moisture content, total organic carbon content, and C/N ratio all declined during composting, while total nitrogen, total phosphorus, total potassium, pH, germination index, and electrical conductivity increased.
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