Divergent drivers of the spatial variation in greenhouse gas concentrations and fluxes along the Rhine River and the Mittelland Canal in Germany.

Lotic ecosystems are sources of greenhouse gases (GHGs) to the atmosphere, but their emissions are uncertain due to longitudinal GHG heterogeneities associated with point source pollution from anthropogenic activities. In this study, we quantified summer concentrations and fluxes of carbon dioxide (CO), methane (CH), nitrous oxide (NO), and dinitrogen (N), as well as several water quality parameters along the Rhine River and the Mittelland Canal, two critical inland waterways in Germany. Our main objectives were to compare GHG concentrations and fluxes along the two ecosystems and to determine the main driving factors responsible for their longitudinal GHG heterogeneities.

Microplastic sample purification methods - Assessing detrimental effects of purification procedures on specific plastic types.

In search of effective, fast, and cheap methods to purify environmental samples for microplastic analysis, scientific literature provides various purification protocols. However, while most of these protocols effectively purify the samples, some may also degrade the targeted polymers. This study was conducted to systematically compare the effects of purification protocols based on acidic, alkaline, oxidative, and enzymatic digestion and extraction via density separation on eight of the most relevant plastic types.

Moving Toward Standardized Toxicity Testing Procedures with Particulates by Dietary Exposure of Gammarids.

Ecotoxicological effect assessment of particulate materials and sparingly soluble substances is an emerging field. Current standard toxicity tests of aquatic organisms are based on soluble substances which are added to the aqueous phase. Although soluble substances distribute homogeneously, particles can form aggregates, resulting in inhomogeneous distribution and unpredictable exposure.

Analysis of microplastics of a broad size range in commercially important mussels by combining FTIR and Raman spectroscopy approaches.

Microplastic (MP) contamination is present in the entire marine environment from the sediment to the water surface and down to the deep sea. This ubiquitous presence of MP particles opens the possibility for their ingestion by nearly all species in the marine ecosystem. Reports have shown that MP particles are present in local commercial seafood species leading to the possible human ingestion of these particles.

Invasive zebra mussel () threatens an exceptionally large population of the depressed river mussel () in a postglacial lake.

Freshwater mussels are in decline worldwide, with the depressed river mussel being one of the rarest and most endangered species in Europe. Invasive mussels are suspected to be an important factor of decline, but there is little information on their interaction with native species.This study analyzed densities, depth distribution, and individual sizes and weights in one of the largest known populations of in Europe in relation to the co-occurring invasive zebra mussel and other mussel species using a systematic transect analysis.

Modulation of PAH toxicity on the freshwater organism G. roeseli by microparticles.

Polycyclic aromatic hydrocarbons are widespread and environmentally persistent chemicals that readily bind to particles in air, soil and sediment. Plastic particles, which are also an ubiquitous global contamination problem, may thus modulate their environmental fate and ecotoxicity. First, the acute aqueous toxicity of phenanthrene in adult Gammarus roeseli was determined with a LC of 471 μg/L after 24 h and 441 μg/L after 48 h.

Multi-temporal surveys for microplastic particles enabled by a novel and fast application of SWIR imaging spectroscopy - Study of an urban watercourse traversing the city of Berlin, Germany.

Following the widespread assumption that a majority of ubiquitous marine microplastic particles originate from land-based sources, recent studies identify rivers as important pathways for microplastic particles (MPP) to the oceans. Yet a detailed understanding of the underlying processes and dominant sources is difficult to obtain with the existing accurate but extremely time-consuming methods available for the identification of MPP. Thus in the presented study, a novel approach applying short-wave infrared imaging spectroscopy for the quick and semi-automated identification of MPP is applied in combination with a multitemporal survey concept.

Do microplastic particles affect Daphnia magna at the morphological, life history and molecular level?

Microplastic particles are ubiquitous not only in marine but also in freshwater ecosystems. However, the impacts of microplastics, consisting of a large variety of synthetic polymers, on freshwater organisms remains poorly understood. We examined the effects of two polymer mixtures on the morphology, life history and on the molecular level of the waterflea Daphnia magna (three different clones).

Enzymatic Purification of Microplastics in Environmental Samples.

Micro-Fourier transform infrared (micro-FTIR) spectroscopy and Raman spectroscopy enable the reliable identification and quantification of microplastics (MPs) in the lower micron range. Since concentrations of MPs in the environment are usually low, the large sample volumes required for these techniques lead to an excess of coenriched organic or inorganic materials. While inorganic materials can be separated from MPs using density separation, the organic fraction impedes the ability to conduct reliable analyses.

Variation in plastic abundance at different lake beach zones - A case study.

Plastic particles in marine and freshwater environments span from macroscopic to microscopic size classes. Each may have a different impact on individuals, populations and ecosystems, but still the wide variety of methods used in beach sediment sampling inhibit comparisons among studies and therefore hampers a risk assessment. A large portion of the uncertainties is due to differing sampling strategies.

Spatial and temporal variation of macro-, meso- and microplastic abundance on a remote coral island of the Maldives, Indian Ocean.

Plastic debris is ubiquitous in the marine environment and the world's shores represent a major sink. However, knowledge about plastic abundance in remote areas is scarce. Therefore, plastic abundance was investigated on a small island of the Maldives.

Hazardous or not - Are adult and juvenile individuals of Potamopyrgus antipodarum affected by non-buoyant microplastic particles?

Microplastic has been ubiquitously detected in freshwater ecosystems. A variety of freshwater organisms were shown to ingest microplastic particles, while a high potential for adverse effects are expected. However, studies addressing the effect of microplastic in freshwater species are still scarce compared to studies on marine organisms.

Pigments and plastic in limnetic ecosystems: A qualitative and quantitative study on microparticles of different size classes.

Recently, macroplastic (>5 mm) and especially microplastic (<5 mm) particles have been reported as emerging contaminants in marine and limnetic ecosystems. Their coloration is gained by the addition of pigments to the polymer blend which is the major component of the respective product. However, color is also a feature of paint and coatings whereby the pigment is the major component.