3-octanone has been widely identified as a primary biomarker for mold and insect infestation in wheat. Nevertheless, to date, no chemiresistive sensor based on a metal oxide semiconductor with excellent sensing properties for 3-octanone has been developed. In light of the extensively reported superior efficacy of CoO-based sensors for ketone detection, we designed CoO samples with various hierarchical morphologies (hollow sphere, multi-wall sphere, flower-like, and urchin-like), which were determined by regulating solvent and organic ligand.
View Article and Find Full Text PDFThe integration of dual-mesoporous structures, the construction of heterojunctions, and the incorporation of highly concentrated oxygen vacancies are pivotal for advancing metal oxide-based gas sensors. Nonetheless, achieving an optimal design that simultaneously combines mesoporous structures, precise heterojunction modulation, and controlled oxygen vacancies through a one-step process remains challenging. This study proposes an innovative method for fabricating zinc stannate semiconductors featuring dual-mesoporous structures and tunable oxygen vacancies via a direct solution precursor plasma spray technique.
View Article and Find Full Text PDFLow-pressure cold spray (LPCS) has broadened the application field of cold spray owing to its portability and low cost. For additive manufacturing (AM) based on LPCS (LPCSAM), it is important to investigate the effects of parameters such as temperature and pressure of the gas, stand-off distance, gun traverse speed, and the number of scanning passes of the gun on the deposition and properties. This study aims to determine the optimal kinematic spray parameters for spraying Cu+AlO powder onto an aluminum substrate through LPCS, so as to prepare for the next AM work.
View Article and Find Full Text PDFBackground: Blood-brain barrier (BBB) is a crucial but dynamic structure that functions as a gatekeeper for the central nervous system (CNS). Managing sufficient substances across the BBB is a major challenge, especially in the development of therapeutics for CNS disorders.
Methods: To achieve an efficient, fast and safe strategy for BBB opening, an acoustofluidic transwell (AFT) was developed for reversible disruption of the BBB.
This study reports the development of ZnSnO based gas sensors for pyridine detection in rice aging. Pyridine is one of heterocyclic markers formed via Maillard reaction and lipid oxidation. Herein, graphitic carbon nitride (g-CN) decorated ZnSnO microstructures were obtained through a template-free approach.
View Article and Find Full Text PDFJ Therm Spray Technol
February 2022
In thermal spray process, the characteristics of in-flight particles (velocity and temperature) play an important role regarding the microstructure of the deposit and thus the coating performances. The implementation of diagnostic devices is necessary to measure such characteristics. Many imaging systems and algorithms have been developed for identifying and tracking in-flight particles.
View Article and Find Full Text PDFBackground: Animal bites are a major public health problem. The more serious the bite wound is, the higher the risk of developing rabies is. This study aimed to investigate the severity of wounds among animal bite victims and identify the influencing factors in Wuhan, China.
View Article and Find Full Text PDFThis paper systematically investigates the biomedical performance of selective laser melted (SLM) porous Ti6Al4V ELI scaffolds for bone implantation through in vitro and in vivo experiments. Scaffolds with pore sizes of 500 μm, 600 μm and 700 μm and porosities of 60% and 70% were manufactured in order to explore the optimum pore size and porosity. Rat bone marrow mesenchymal stem cells (rBMMSCs) were used in the in vitro experiments.
View Article and Find Full Text PDFMaterials (Basel)
December 2018
In this work, the removal of manganese from nickel melts by Ar and (10%, 20% and 40%) H₂ plasma arc melting under various pressures (0.01⁻0.02, 0.
View Article and Find Full Text PDFHydraulic components are coated by thermal spraying to protect them against cavitation erosion. These coatings are built up by successive deposition of single splats. The behavior of a single splat under mechanical loading is still very vaguely understood.
View Article and Find Full Text PDFBinary spinel-type metal oxides (ABO) related materials, including ferrites (AFeO), are attractive photocatalysts thanks to their excellent visible light response for the photodegradation of organic pollutants. Currently, these materials are synthesized via conventional chemical routes suffering from long preparation duration and multistep. Moreover, the photocatalysts are obtained as nano-powders from conventional chemical routes would introduce another drawback for their recycling and reuse.
View Article and Find Full Text PDFThe deposition of oxygen-defective ZnO films exhibiting varied nanostructures via Solution Precursor Plasma Spray (SPPS) route, a one-step, minute-scaled duration and large scale method, is reported. The in situ formation of oxygen vacancies in ZnO films was confirmed by UV-Visible, Raman and photoluminescence (PL) spectroscopy and the as-prepared samples exhibit a bandgap as low as 3.02 eV.
View Article and Find Full Text PDFTo obtain hydroxyapatite (HA) coatings with high crystallinity which have long-term stability in clinical applications, coarse powders were usually injected to less energetic plasma. However, the HA coatings accumulated by partly melted particles usually have high porosity and poor mechanical properties, especially poor bonding strength. In this work, by profiting its quenching and mechanical impact, dry-ice blasting was in-situ employed during plasma spray process to improve the microstructure characterization and bonding strength of HA coatings.
View Article and Find Full Text PDFTensile strength and ductility of Selective Laser Melting (SLM) processed commercially pure Ti (CP-Ti) were simultaneous enhanced by preforming the melting/solidification processes under Static Magnetic Field (SMF). The effects of SMF on microstructure and tensile properties were examined. The SMF-SLMed CP-Ti sample presents a microstructure of fine acicular martensitic α'-Ti and lath-shaped α-Ti.
View Article and Find Full Text PDFBenzene is an established leukotoxin and leukemogen in humans. We have previously reported that exposure of workers to benzene and to benzene metabolite hydroquinone in cultured cells induced DNA-dependent protein kinase catalytic subunit (DNA-PKcs) to mediate the cellular response to DNA double strand break (DSB) caused by DNA-damaging metabolites. In this study, we used a new, small molecule, a selective inhibitor of DNA-PKcs, 2-(morpholin-4-yl)-benzo[h]chomen-4-one (NU7026), as a probe to analyze the molecular events and pathways in hydroquinone-induced DNA DSB repair and apoptosis.
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