Understanding the nature of grain boundaries is a prerequisite for fabricating high-performance superconducting bulks and wires. For iron-based superconductors [e.g.
View Article and Find Full Text PDFIn the European Mediterranean Region, palm trees are a common element in cities and semi-urban landscapes and have become important habitat structures for local fauna. This study aimed to monitor the invertebrate and vertebrate fauna occurring on and associated with ornamental palms of the genus , over the course of one year. Five study sites were used in southern Spain, with varying levels of management.
View Article and Find Full Text PDFThe small G-protein CDC42 is an evolutionary conserved polarity protein and a key regulator of polarized cell functions, including directed cell migration. In vertebrates, alternative splicing gives rise to two CDC42 proteins: the ubiquitously expressed isoform (CDC42u) and the brain isoform (CDC42b), which only differ in their carboxy-terminal sequence, including the CAAX motif essential for their association with membranes. We show that these divergent sequences do not directly affect the range of CDC42's potential binding partners but indirectly influence CDC42-driven signaling by controlling the subcellular localization of the two isoforms.
View Article and Find Full Text PDFAdditive and antisolvent engineering strategies are outstandingly efficient in enhancing perovskite quality, photovoltaic performance, and stability of perovskite solar cells (PSCs). In this work, an effective approach is applied by coupling the antisolvent mixture and multi-functional additive procedures, which is recognized as antisolvent additive engineering (AAE). The graphene quantum dots functionalized with amide (AGQDs), which consists of carbonyl, amine, and long hydrophobic alkyl chain functional groups, are added to the antisolvent mixture of toluene (T) and hexane (H) as an efficient additive to form the CHNHPbI (MAPI):AGQDs graded heterojunction structure.
View Article and Find Full Text PDFHigh-entropy oxide (HEO) superconductors have been developed since very recently. Different superconductors can be produced in the form of a high-entropy compound, including REBaCuO (REBCO). However, until now, mainly bulk samples (mostly in polycrystalline form) have been reported.
View Article and Find Full Text PDFThe recent realisations of hydrogen doped LnFeAsO (Ln = Nd and Sm) superconducting epitaxial thin films call for further investigation of their structural and electrical transport properties. Here, we report on the microstructure of a NdFeAs(O,H) epitaxial thin film and its temperature, field, and orientation dependencies of the resistivity and the critical current density J. The superconducting transition temperature T is comparable to NdFeAs(O,F).
View Article and Find Full Text PDFA low-cost chemical solution deposition technique was employed to prepare YBaCuO (YBCO) nanocomposite films starting from a colloidal solution containing preformed ZrO nanocrystals. As previous publications revealed, an increase in the amount of nanocrystals results in a progressive deterioration of the film properties. The parameters that control this process and their interplay are still unknown in detail.
View Article and Find Full Text PDFThe main objective of this work was to study the superconducting properties of BCO films with a mixture of rare-earth () ions with large difference in ion size, in particular Sm and Yb. These Yb Sm BaCuO films have been successfully prepared for the first time by chemical solution deposition following the extremely low-fluorine route, which allows reducing the fluorine content by 93% with respect to standard full trifluoroacetate solutions. On the one hand, critical temperature remains stable at approximately 90 K with Sm content up to = 0.
View Article and Find Full Text PDFREBaCuO (REBCO, RE: rare earth, such as Y and Gd) compounds have been extensively studied as a superconducting layer in coated conductors. Although ErBCO potentially has better superconducting properties than YBCO and GdBCO, little research has been made on it, especially in chemical solution deposition (CSD). In this work, ErBCO films were deposited on IBAD (ion-beam-assisted-deposition) substrates by CSD with low-fluorine solutions.
View Article and Find Full Text PDFACS Appl Mater Interfaces
November 2020
Lab-scale perovskite solar cells (PSCs) have recently reached power conversion efficiencies (PCEs) of up to 25.2%. However, a reliable transfer of solution processing from spin coating to scalable printing techniques and a homogeneous deposition on large substrate sizes is challenging also caused by dewetting of the perovskite precursor solution on highly hydrophobic subjacent materials.
View Article and Find Full Text PDFFor the first time, GdBaCuO nanocomposites were prepared by chemical solution deposition following the ex-situ approach. In particular, ~ 220 nm GdBaCuO-HfO (GdBCO-HfO) nanocomposite films were fabricated starting from a colloidal solution of 5 mol% HfO nanoparticles. Hereby, one of the main challenges is to avoid the accumulation of the nanoparticles at the substrate interface during the pyrolysis, which would later prevent the epitaxial nucleation of the GdBCO grains.
View Article and Find Full Text PDFBackground Interruptions in chest compressions contribute to poor outcomes in out-of-hospital cardiac arrest. The objective of this retrospective observational cohort study was to characterize the frequency, reasons, and duration of interruptions in chest compressions and to determine if interruptions changed over time. Methods and Results All out-of-hospital cardiac arrests treated by the Seattle Fire Department (Seattle, WA, United States) from 2007 to 2016 with capture of recordings from automated external defibrillators and manual defibrillators were included.
View Article and Find Full Text PDFNanomaterials (Basel)
December 2019
Chemical solution deposition (CSD) was used to grow YGdBaCuO-BaHfO (YGBCO-BHO) nanocomposite films containing 12 mol% BHO nanoparticles and various amounts of Gd, , on two kinds of buffered metallic tapes: Ni5W and IBAD. The influence of the rare-earth stoichiometry on structure, morphology and superconducting properties of these films was studied. The growth process was carefully studied in order to find the most appropriate growth conditions for each composition and substrate.
View Article and Find Full Text PDFACS Appl Mater Interfaces
August 2019
Usually hydroxyl groups present on top of oxidized silicon served as binding centers for a silanization reaction toward surface functionalization. In this study, we developed a novel surface functionalization strategy where hydroxyl functionalization on nonoxidized silicon surfaces are obtained. These surfaces were stable for several weeks even in ambient air at room temperature.
View Article and Find Full Text PDFArterioscler Thromb Vasc Biol
April 2019
Objective- Arteriovenous fistulae (AVF) are the most common access created for hemodialysis; however, many AVF fail to mature and require repeated intervention, suggesting a need to improve AVF maturation. Eph-B4 (ephrin type-B receptor 4) is the embryonic venous determinant that is functional in adult veins and can regulate AVF maturation. Cav-1 (caveolin-1) is the major scaffolding protein of caveolae-a distinct microdomain that serves as a mechanosensor at the endothelial cell membrane.
View Article and Find Full Text PDFA new state-of-the-art electrical transport measurement system was developed for the characterization of industrially produced coated conductors (CCs). The current leads are rated to a conduct current of up to 1000 A, which opens up the possibility of measuring the critical current I of tapes at a wide range of temperatures. The setup operates in a He-gas flow cryostat that provides stable temperatures between 1.
View Article and Find Full Text PDFY Gd BaCuO -BaHfO (YGBCO-BHO) nanocomposite films containing 12 mol% BHO nanoparticles and different amounts of Gd were prepared by chemical solution deposition following the trifluoroacetic route on SrTiO single crystals in order to study the influence of the rare earth stoichiometry on structure, morphology and superconducting properties of these films. We optimized the growth process for each of several Gd contents of the 220 nm thick YGBCO-BHO films by varying crystallization temperature and oxygen partial pressure. This optimization process led to the conclusion that mixing the rare earths in YGBCO-BHO films leads to wider growth parameter windows compared to YBCO-BHO and GdBCO-BHO films giving larger freedom for selecting the most convenient processing parameters in order to adapt to different substrates or applications which is very important for the industrial production of coated conductors.
View Article and Find Full Text PDFObjectives: To determine injury risk-workload associations in collegiate American Football.
Design: Retrospective analysis.
Methods: Workload and injury data was recorded from 52 players during a full NCAA football season.
An outstanding current carrying performance (namely critical current density, Jc) over a broad temperature range of 10-77 K for magnetic fields up to 12 T is reported for films of YBa2Cu3O7-x with Ba2Y(Nb,Ta)O6 inclusion pinning centres (YBCO-BYNTO) and thicknesses in the range of 220-500 nm. Jc values of 10 MA cm-2 were measured at 30 K - 5 T and 10 K - 9 T with a corresponding maximum of the pinning force density at 10 K close to 1 TN m-3. The system is very flexible regarding properties and microstructure tuning, and the growth window for achieving a particular microstructure is wide, which is very important for industrial processing.
View Article and Find Full Text PDFWith the increasing prevalence of end-stage renal disease, there is a growing need for hemodialysis. Arteriovenous fistulae (AVF) are the preferred type of vascular access for hemodialysis, but maturation and failure continue to present significant barriers to successful fistula use. AVF maturation integrates outward remodeling with vessel wall thickening in response to drastic hemodynamic changes in the setting of uremia, systemic inflammation, oxidative stress, and pre-existent vascular pathology.
View Article and Find Full Text PDFA quantum critical point (QCP) is currently being conjectured for the BaFe(As P ) system at the critical value x ≈ 0.3. In the proximity of a QCP, all thermodynamic and transport properties are expected to scale with a single characteristic energy, given by the quantum fluctuations.
View Article and Find Full Text PDFArterioscler Thromb Vasc Biol
June 2017
Objective: Arteriovenous fistulae (AVF) remain the optimal conduit for hemodialysis access but continue to demonstrate poor patency and poor rates of maturation. We hypothesized that CD44, a widely expressed cellular adhesion molecule that serves as a major receptor for extracellular matrix components, promotes wall thickening and extracellular matrix deposition during AVF maturation.
Approach And Results: AVF were created via needle puncture in wild-type C57BL/6J and CD44 knockout mice.