Composting is one of the primary methods for organic waste recycling in China. This study aims to analyze the product quality of organic fertilizer enterprises from the perspective of actual production and the relationship between production process variations and organic matter content in organic fertilizers based on 348 samples from 229 organic fertilizer companies across 22 provinces. Results showed that fertilizers produced through composting processes contain higher organic matter, averaging 45.
View Article and Find Full Text PDFAeration is an important factor to regulate composting efficiency and nitrogen loss. This study is aimed to compare the effects of different aeration modes (continuous and intermittent) and aeration rate on nitrogen conversion and bacterial community in composting from dehydrated sludge and corn straw. Results showed that the intermittent aeration mode at same aeration volume was superior to the continuous aeration mode in terms of NH emission reduction, nitrogen conversion and germination index (GI) improvement.
View Article and Find Full Text PDFUnder the twin pressures of global food security and dual‑carbon strategies, improving farm eco-efficiency is critical for achieving China's goal of a 50 Pg increase in grain production, meeting the ambitious climate mitigation targets set by the Paris Agreement, and meeting seven of the seventeen Sustainable Development Goals (SDGs) set by the United Nations. However, there is limited research on eco-efficiency measures supported by localised fine-scale data and coupling mechanisms for the structure, production process, efficiency improvement, and carbon reduction synergies of integrated farming systems in China. This study used the Life Cycle Assessment (LCA) and Data Envelopment Analysis (DEA) methods to assess eco-efficiency at the farm level in northern China, included in the National Coupling Crop and Livestock Production Pilot Programs, to improve the eco-efficiency of farms to achieve increased production and emission reductions.
View Article and Find Full Text PDFAdditives could improve composting performance and reduce gaseous emission, but few studies have explored the synergistic of additives on HS emission and compost maturity. This research aims to make an investigation about the effects of chemical additives and mature compost on HS emission and compost maturity of kitchen waste composting. The results showed that additives increased the germination index value and HS emission reduction over 15 days and the treatment with both chemical additives and mature compost achieved highest germination index value and HS emission reduction (85%).
View Article and Find Full Text PDFIn this Letter, beveled mesas for 30 × 30 µm GaN-based micro-light-emitting diodes (µLEDs) with different inclination angles are designed, fabricated, and measured. We find that µLED with a mesa inclination angle of 28° has the lowest internal quantum efficiency (IQE) and the highest injection current density at which the peak IQE is obtained. This is due to the increased quantum confined Stark effect (QCSE) at the mesa edge.
View Article and Find Full Text PDFIn this paper, by using advanced numerical models, we investigate the impact of the AlN/GaN distributed Bragg reflector (DBR) and AlInN/GaN DBR on stimulated radiative recombination for GaN-based vertical-cavity-surface-emitting lasers (VCSELs). According to our results, when compared with the VCSEL with AlN/GaN DBR, we find that the VCSEL with AlInN/GaN DBR decreases the polarization-induced electric field in the active region, and this helps to increase the electron-hole radiative recombination. However, we also find that the AlInN/GaN DBR has a reduced reflectivity when compared with the AlN/GaN DBR with the same number of pairs.
View Article and Find Full Text PDFLayered transition metal oxide cathodes have been one of the dominant cathodes for lithium-ion batteries with efficient Li intercalation chemistry. However, limited by the weak layered interaction and unstable surface, mechanical and chemical failure plagues their electrochemical performance, especially for Ni-rich cathodes. Here, adopting a simultaneous elemental-structural atomic arrangement control based on the intrinsic Ni-Co-Mn system, the surface role is intensively investigated.
View Article and Find Full Text PDFA single-crystalline Ni-rich (SCNR) cathode with a large particle size can achieve higher energy density, and is safer, than polycrystalline counterparts. However, synthesizing large SCNR cathodes (>5 μm) without compromising electrochemical performance is very challenging due to the incompatibility between Ni-rich cathodes and high temperature calcination. Herein, we introduce Vegard's Slope as a guide for rationally selecting sintering aids, and we successfully synthesize size-controlled SCNR cathodes, the largest of which can be up to 10 μm.
View Article and Find Full Text PDFIn this work, by using three-dimensional finite-difference time-domain (3D FDTD) method, the effect of conventional nano-patterned sapphire substrate (NPSS) on the optical crosstalk and the light extraction efficiency (LEE) for InGaN/GaN-based flip-chip micro light-emitting diodes (µ-LEDs) are systematically studied. We find that the conventional NPSS is not suitable for µ-LEDs. It is because the inclined mesa sidewall for µ-LEDs possesses a good scattering effect for µ-LEDs, but the introduced conventional NPSS causes part of the light be off escape cone between sapphire and air and become the guided light.
View Article and Find Full Text PDFIn this report, the impact of different mesa designs on the optical and electrical characteristics for GaN-based micro-light emitting diodes (µLEDs) has been systematically and numerically investigated by using TCAD simulation tools. Our results show that an enhanced light extraction efficiency can be obtained by using beveled mesas. The inclined mesa angles can more effectively reflect the photons to the substrate, and this helps to extract the photons to free air for flip-chip µLEDs.
View Article and Find Full Text PDFSingle-crystalline Ni-rich cathodes with high capacity have drawn much attention for mitigating cycling and safety crisis of their polycrystalline analogues. However, planar gliding and intragranular cracking tend to occur in single crystals with cycling, which undermine cathode integrity and therefore cause capacity degradation. Herein, we intensively investigate the origin and evolution of the gliding phenomenon in single-crystalline Ni-rich cathodes.
View Article and Find Full Text PDFEcological pig-raising systems (EPRSs) differ from conventional breeding systems, focusing more on environmental consequences, human health, and food safety during production processes. Thus productions from EPRSs have undergone significant development in China. Thus far, adding plant fiber sources (e.
View Article and Find Full Text PDFHigh-nickel (Ni ≥ 90%) cathodes with high specific capacity hold great potential for next-generation lithium-ion batteries (LIBs). However, their practical application is restricted by the high interfacial reactivity under continuous air erosion and electrolyte assault. Herein, a stable high-nickel cathode is rationally designed via in situ induction of a dense amorphous Li CO on the particle surface by a preemptive atmosphere control.
View Article and Find Full Text PDFDue to the increased surface-to-volume ratio, the surface recombination caused by sidewall defects is a key obstacle that limits the external quantum efficiency (EQE) for GaN-based micro-light-emitting diodes (µLEDs). In this work, we propose selectively removing the periphery p-GaN layer so that the an artificially formed resistive ITO/p-GaN junction can be formed at the mesa edge. Three types of LEDs with different device dimensions of 30 × 30 µm, 60 × 60 µm and 100 × 100 µm are investigated, respectively.
View Article and Find Full Text PDFIn this report, we investigate the impact of a thin p-GaN layer on the efficiency for AlGaN-based deep-ultraviolet light-emitting diodes (DUV LEDs). According to our results, the light extraction efficiency (LEE) becomes higher with the decrease of the p-GaN layer thickness, which can be ascribed to the decreased absorption of DUV emission by the thin p-GaN layer. Moreover, we also find that the variation trend of external quantum efficiency (EQE) is consistent with that of LEE.
View Article and Find Full Text PDFSingle-crystalline Ni-rich cathodes are promising candidates for the next-generation high-energy Li-ion batteries. However, they still suffer from poor rate capability and low specific capacity due to the severe kinetic hindrance at the nondilute state during Li intercalation. Herein, combining experiments with density functional theory (DFT) calculations, we demonstrate that this obstacle can be tackled by regulating the oxidation state of nickel via injecting high-valence foreign Ta .
View Article and Find Full Text PDFIn this work, we propose adopting step-type quantum wells to improve the external quantum efficiency for GaN-based yellow micro light-emitting diodes. The step-type quantum well is separated into two parts with slightly different InN compositions. The proposed quantum well structure can partially reduce the polarization mismatch between quantum barriers and quantum wells, which increases the overlap for electron and hole wave functions without affecting the emission wavelength.
View Article and Find Full Text PDFLi-conductive ceramic oxide electrolytes, such as garnet-structured LiLaZrO have been considered as promising candidates for realizing the next-generation solid-state Li-metal batteries with high energy density. Practically, the ceramic pellets sintered at elevated temperatures are often provided with high stiffness yet low fracture toughness, making them too brittle for the manufacture of thin-film electrolytes and strain-involved operation of solid-state batteries. The ceramic powder, though provided with ductility, does not yield satisfactorily high Li conductivity due to poor ion conduction at the boundaries of ceramic particles.
View Article and Find Full Text PDFOwing to high surface-to-volume ratio, InGaN-based micro-light-emitting diodes (μLEDs) strongly suffer from surface recombination that is induced by sidewall defects. Moreover, as the chip size decreases, the current spreading will be correspondingly enhanced, which therefore further limits the carrier injection and the external quantum efficiency (EQE). In this work, we suggest reducing the nonradiative recombination rate at sidewall defects by managing the current spreading effect.
View Article and Find Full Text PDFIn this report, we propose GaN-based vertical cavity surface emitting lasers with a p-GaN/n-GaN/p-GaN (PNP-GaN) structured current spreading layer. The PNP-GaN current spreading layer can generate the energy band barrier in the valence band because of the modulated doping type, which is able to favor the current spreading into the aperture. By using the PNP-GaN current spreading layer, the thickness for the optically absorptive ITO current spreading layer can be reduced to decrease internal loss and then enhance the lasing power.
View Article and Find Full Text PDFA better lateral current confinement is essentially important for GaN-based vertical-cavity-surface-emitting lasers (VCSELs) to achieve lasing condition. Therefore, a buried insulator aperture is adopted. However, according to our results, we find that the current cannot be effectively laterally confined if the insulator layer is not properly selected, and this is because of the unique feature for GaN-based VCSELs grown on insulating substrates with both p-electrode and n-electrode on the same side.
View Article and Find Full Text PDFThe intensification and industrialization of agricultural production leads to more and more serious separation of crop and livestock, which causes serious contradiction between livestock excrement and environment, and major challenges for agricultural sustainable development. Here, we quantitatively investigated the spatial pattern and evolutionary trend of the sustainable development index (ESI) of the crop-livestock system using the emergy analysis and the input/output data in Shandong Province (1999-2015). The results showed that the sustainability of the crop-livestock system in Shandong Province decreased from 1999 to 2015 by 22.
View Article and Find Full Text PDFACS Appl Mater Interfaces
November 2018
Catalytic efficiency is a crucial index for electrodes in flow batteries, and tremendous efforts have been devoted to exploring catalysts with as many reaction zones as possible. Nevertheless, the space between the reaction sites, especially for interstitial space utilization, is usually ignored and challengeable to exploit owing to the balance between the catalytic efficiency and structural stability. Herein, a three-dimensional conducting network was constructed via a nitrogen-rich carbon film-bridged graphite felt framework (GF@N-C) to maximize its electrocatalytic effectiveness toward redox species.
View Article and Find Full Text PDFACS Appl Mater Interfaces
January 2017
The development of a three-dimensionally flexible, large-surface area, high-conductivity electrode is important to improve the low conductivity and utilization of active materials and restrict the shuttle of long-chain polysulfides in Li-polysulfide batteries. Herein, we constructed an integrated three-dimensional carbon nanotube forest/carbon cloth electrode with heteroatom doping and high electrical conductivity. The as-constructed electrode provides strong trapping on the polysulfide species and fast charge transfer.
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