Polymers (Basel)
March 2023
In this study, the quantum chemical method was used to investigate the microscopic characteristics of α-poly viny difluoride (PVDF) molecules under the influence of an electric field, and the impact of mechanical stress and electric field polarization on the insulation performance of PVDF was analyzed through the material's structural and space charge characteristics. The findings reveal that long-term polarization of an electric field leads to a gradual decline in stability and a reduction in the energy gap of the front orbital, resulting in the improved conductivity of PVDF molecules and a change in the reactive active site of the molecular chain. When the energy gap reaches a certain value, a chemical bond fracture occurs, with the C-H and C-F bonds at the ends of the backbone breaking first to form free radicals.
View Article and Find Full Text PDFThe method using ethanol to evaluate the cellulose insulation aging condition of oil-immersed transformers has been proposed. At present, the dominating method for detecting ethanol in insulating oil is to use headspace-gas-chromatography-mass-spectrometry (HS-GC-MS). However, the problem of quantitative inaccuracy will be sometimes encountered in the actual detection process due to improper instrument parameter setting and improper manual operation.
View Article and Find Full Text PDFDepending on the study of the master curve technique, a temperature correction model for the polarization current of transformer polymer (cellulose) insulation, considering the effects of both moisture content (%) and temperature is proposed. In the current work, the shift factors of polarization current curves of samples with various moisture contents are extracted at different temperatures. Then, the variation law among the shift factor, test temperature, and moisture content are studied so as to establish the corresponding functional relationship.
View Article and Find Full Text PDFThe aging kinetics model is of great interest to scholars since it is capable of describing the variation law between the degree of polymerization () and the aging duration of transformer polymer (cellulose) insulation. However, it is difficult to determine the moisture content inside the transformer polymer insulation without destroying it, so that the model parameters cannot be confirmed. Such limitation greatly restricts its application.
View Article and Find Full Text PDFIt is a fact that the frequency domain spectroscopy (FDS) curve at different temperatures can be corrected by the shift factor () extracted from the master curve. However, the and master curve reported by previous works are distinctive due to the difference in the construction algorithm. Therefore, it is of great significance to report a universal approach for extracting .
View Article and Find Full Text PDFDissolved gas analysis (DGA) has been widely used in various scenarios of power transformers' online monitoring and diagnoses. However, the diagnostic accuracy of traditional DGA methods still leaves much room for improvement. In this context, numerous new DGA diagnostic models that combine artificial intelligence with traditional methods have emerged.
View Article and Find Full Text PDFA solution for forecasting the dissolved gases in oil-immersed transformers has been proposed based on the wavelet technique and least squares support vector machine. In order to optimize the hyper-parameters of the constructed wavelet LS-SVM regression, the imperialist competition algorithm was then applied. In this study, the assessment of prediction performance is based on the squared correlation coefficient and mean absolute percentage error methods.
View Article and Find Full Text PDFThe life expectancy of a transformer is largely depended on the service life of transformer polymer insulation materials. Nowadays, several papers have reported that the traditional system poles obtained from polarization and depolarization current (PDC) data can be used to assess the condition of transformer insulation systems. However, the traditional system poles technique only provides limited ageing information for transformer polymer insulation.
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